Abstract
Magnesium–lithium (Mg–Li) alloy, as the lightest metal structure material, has unparalleled market prospects in aerospace, weapons and equipment, electronic technology, transportation, and many other fields. However, it is hard to balance the superlight and high strength of Mg–Li alloy, and the inferior high-temperature strength and poor high-temperature stability limit the wide application of Mg–Li alloy. At present, the main methods to improve the mechanical properties of Mg–Li alloy are alloying, grain refinement, and compound strengthening. The domestic and overseas research progress in the strengthening and toughening methods and mechanisms of Mg–Li alloy are reviewed, and the future development of the high strength and high toughness Mg–Li alloy is prospected.
摘要
作为最轻的金属结构材料, Mg–Li合金在航空航天、武器装备、电子科技以及交通运输等领域具有广阔的应用前景。然而, Mg–Li合金的超轻和高强度很难兼顾, 较差的高温强度和稳定性限制了该合金的广泛应用。目前, 提高Mg-Li合金力学性能的主要途径是合金化强化、细晶强化和复合强化。本文介绍了国内外学者在镁锂合金强韧化方法与机理方面的研究进展, 并对高强韧镁锂合金的研发趋势进行了展望。
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References
Wang BJ, Xu K, Xu DK, Cai X, Qiao YX, Sheng LY. Anisotropic corrosion behavior of hot-rolled Mg-8 wt.%Li alloy. J Mater Sci Technol. 2020;53(18):102.
Yan YM, Maltseva A, Zhou P, Li XJ, Zeng ZR, Gharbi O, Ogle K, Haye LM, Vaudescal M, Esmaily M, Birbilis N, Volovitch P. On the in-situ aqueous stability of an Mg–Li–(Al–Y–Zr) alloy: role of Li. Corros Sci. 2020;164:108342.
Lentz M, Klaus M, Beyerlein IJ, Zecevic M, Reimers W, Knezevic M. In situ X-ray diffraction and crystal plasticity modeling of the deformation behavior of extruded Mg–Li–(Al) alloys: an uncommon tension–compression asymmetry. Acta Mater. 2015;86:254.
Zhang JH, Zhang L, Leng Z, Liu SJ, Wu RZ, Zhang ML. Experimental study on strengthening of Mg–Li alloy by introducing long-period stacking ordered structure. Scr Mater. 2013;68(9):675.
Peng X, Liu WC, Wu GH, Ji H, Ding WJ. Plastic deformation and heat treatment of Mg–Li alloys: a review. J Mater Sci Technol. 2022;99:193.
Li Z, Xu B, Sun Q, Li QL, Liu W. Stress field interaction during propagation of adjacent tensile twinning nuclei in magnesium. Rare Met. 2019;38(8):721.
Fu H, Ge BC, Xin YC, Wu RZ, Fernandez C, Huang JY, Peng QM. Achieving high strength and ductility in magnesium alloys via densely hierarchical double contraction nanotwins. Nano Lett. 2017;17(10):6117.
Sanschagrin A, Tremblay R, Angers R, Dube D. Mechanical properties and microstructure of new magnesium-lithium base alloys. Mater Sci Eng A. 1996;220(1–2):69.
Le QZ, Cui JZ, Li HB, Zhang XJ. Current research development in Mg–Li alloy and its applications. Mater Rep. 2003;17(12):1.
Wang W. Study of microstructures and mechanical properties on α-based Mg-Li alloys with Cd/Sn alloying. Master Thesis. Harbin: Harbin Engineering University. 2010.1.
Alamo A, Banchik AD. Precipitation phenomena in the Mg-31 at%Li-1at%Al alloy. J Mater Sci. 1980;15(1):222.
Agnew SR, Yoo MH, Tome CN. Application of texture simulation to understanding mechanical behevior of Mg and solid solution alloys containing Li or Y. Acta Mater. 2001;49(20):4277.
Luo GX, Wu GQ, Wang SJ, Li RH, Huang Z. Effects of YAl2 particulates on microstructure and mechanical properties of β-Mg–Li alloy. J Mater Sci. 2006;41(17):5556.
Shen GJ, Duggan BJ. Texture development in a cold-rolled and annealed body-centered-cubic Mg-Li alloy. Metall Mater Trans A. 2007;38(10):2593.
Counts WA, Friak M, Raabe D, Neugebauer J. Using ab initio calculations in designing bcc Mg–Li alloys for ultra-lightweight applications. Acta Mater. 2009;57(1):69.
Yang CW, Lui TS, Chen LH, Hung HE. Tensile mechanical properties and failure behaviors with the ductile-to-brittle transition of the α+β-type Mg–Li–Al–Zn alloy. Scr Mater. 2009;61(12):1141.
Cheng CW, Huang JJ, Lee S, Wang J, Ciang C. Microstructure and mechanical behaviors of the new LAZ1151 Mg-Li alloy. Adv Mater Res. 2011;239–242:1326.
Cao FR, Xia F, Hou HL, Ding H, Li ZQ. Effects of high-density pulse current on mechanical properties and microstructure in a rolled Mg–9.3Li–1.79Al–1.61Zn alloy. Mater Sci Eng A. 2015;637:89.
Trojanova Z, Droz Z, Kudela S, Szaraza Z, Lukac P. Strengthening in Mg-Li matrix composites. Compos Sci Technol. 2007;67(9):1965.
Yamamoto A, Ashida T, Kouta Y, Kim KB, Fukumoto S, Tsubakino H. Precipitation in Mg–(4–13)%Li–(4–5)%Zn ternary alloys. Mater Trans. 2003;44(4):619.
Hsu C, Wang J, Lee S. Room temperature aging characteristic of MgLiAlZn alloy. Mater Trans. 2008;49(11):2728.
Xu TC, Peng XD, Jiang JW, Wei GB, Zhang B. Microstructure and mechanical properties of superlight Mg–Li–Al–Zn wrought alloy. Rare Met Mater Eng. 2014;43(8):1815.
Guo XY, Wu RZ, Zhang JH, Liu B, Zhang ML. Influences of solid solution parameters on the microstrucuture and hardness of Mg–9Li–6Al and Mg–9Li–6Al–2Y. Mater Des. 2014;53:528.
Dong HW, Wang LD, Wu YM, Wang LM. Preparation and characterization of Mg–6Li and Mg–6Li–1Y alloys. J Rare Earths. 2011;29(7):645.
Fei PF, Qu ZK, Wu RZ. Microstructure and hardness of Mg–9Li–6Al–xLa (x=0, 2, 5) alloys during solid solution treatment. Mater Sci Eng A. 2015;625:169.
Xu TC, Peng XD, Jiang JW, Xie WD, Chen YF, Wei GB. Effect of Sr content on microstructure and mechanical properties of Mg-Li-Al-Mn alloy. Trans Nonferrous Met Soc China. 2014;24(9):2752.
Li JQ, Qu ZK, Wu RZ, Zhang ML. Effects of Cu addition on the microstructure and hardness of Mg–5Li–3Al–2Zn alloy. Mater Sci Eng A. 2010;527(10–11):2780.
Tang Y, Jia WT, Liu X, Le QC, Zhang YL. Fabrication of high strength α, α+β, β phase containing Mg-Li alloys with 0.2%Y by extruding and annealing process. Mater Sci Eng A. 2016;675:55.
Wj KIM. Explanation for deviations from the Hall-Petch Relation based on the creep behavior of an ultrafine-grained Mg–Li alloy with low diffusivity. Scr Mater. 2009;61(6):652.
Muga CO, Guo H, Xu SS, Zhang ZW. Effects of aging and fast-cooling on the mechanical properties of Mg–14Li–3Al–3Ce alloy. Mater Sci Eng A. 2017;689:195.
Xu TC, Peng XD, Qin J, Chen YF, Yang Y, Wei GB. Dynamic recrystallization behavior of Mg–Li–Al–Nd duplex alloy during hot compression. J Alloy Compd. 2015;639:79.
Torkian A, Faraji G, Pedram MS. Mechanical properties and in vivo biodegradability of Mg–Zr–Y–Nd–La magnesium alloy produced by a combined severe plastic deformation. Rare Met. 2021;40(3):651.
Tan L, Zhang XY, Xia T, Huang GJ, Liu Q. Fracture morphology and crack mechanism in pure polycrystalline magnesium under tension–compression fatigue testing. Rare Met. 2020;39(2):162.
Kim YW, Kim DH, Lee HI, Hong CP. Widmanstatten type solidification in squeeze casting of Mg–Li–Al alloys. Scr Mater. 1998;38(6):923.
Matsuda A, Wan CC, Yang JM, Kao WH. Rapid solidification processing of a Mg–Li–Si–Ag alloy. Metall Mater Trans A. 1996;27:1363.
Zhou YY, Bian LP, Chen G, Wang LP, Liang W. Influence of Ca addition on microstructural evolution and mechanical properties of near-eutectic Mg–Li alloys by copper-mold suction casting. J Alloy Compd. 2016;664:85.
Hu Z, Yin Z, Yin Z, Tang BB, Huang X, Yan H, Song HG, Luo C, Chen XH. Influence of Sm addition on microstructural and mechanical properties of as-extruded Mg–9Li–5Al alloy. J Alloys Compd. 2020;842:155836.
Chiang C, Lee S, Chu C. Rolling route for refining grains of super light Mg–Li alloys containing Sc and Be. Trans Nonferrous Met Soc China. 2010;20(8):1374.
Dong TS, Zheng XD, Wang T, Liu JH, Li GL. Effect of Nd content on microstructure and mechanical properties of as-cast Mg–12Li–3Al alloy. China Foundry. 2018;14(4):279.
Cui CL, Zhu TL, Leng Z, Wu RZ, Zhang JH, Zhang ML. Effect of combined addition of Y and Nd on microstructure and texture after compression of Mg–Li alloy at room temperature. Acta Metall Sin. 2012;48(6):725.
Le QZ, Cui JZ. The effect of Zr on the mechanical properties of Mg–Li alloy. Mater Rep. 1997;11(1):26.
Li HB, Yao GC, Liang CL, Liu YH, Guo ZQ, Jiang HJ. Microstructure and properties of Mg–Li–Zn alloy sheets with Mn addition. J Funct Mater. 2006;37(8):1269.
Nene SS, Kashyap BP, Prabhu N, Estrin Y, Al-Samman T. Microstructure refinement and its effect on specific strength and bio-corrosion resistance in ultralight Mg–4Li–1Ca (LC41) alloy by hot rolling. J Alloy Compd. 2014;615:501.
Li HB, Yao GC, Guo ZQ, Liu YH, Yu HJ, Ji HB. Microstructure and mechanical properties of Mg–Li alloy with Ca addition. Acta Mater. 2006;19(5):355.
Guo F, Liu L, Ma YL, Jiang LY, Zhang DF, Pan FS. Mechanism of phase refinement and its effect on mechanical properties of a severely deformed dual-phase Mg–Li alloy during annealing. Mater Sci Eng A. 2020;772:138792.
Mineta T, Hasegawa K, Sato H. High strength and plastic deformability of Mg–Li–Al alloy with dual BCC phase produced by a combination of heat treatment and multi-directional forging in channel die. Mat Sci Eng A. 2020;773:138867.
Liu T, Wang YD, Wu SD, Lin PR, Huang CX, Jiang CB, Li SX. Textures and mechanical behavior of Mg–3.3%Li alloy after ECAP. Scr Mater. 2004;51(11):1057.
Cao FR, Xue GQ, Xu GM. Superplasticity of a dual-phase-dominated Mg–Li–Al–Zn–Sr alloy processed by multidirectional forging and rolling. Mater Sci Eng A. 2017;704:360.
Saito Y, Utsunomiya H, Tsuji N, Sakai T. Novel ultra-high straining process for bulk materials-development of the accumulative roll-bonding (ARB) process. Acta Mater. 1999;47(2):579.
Lin K, Kang ZX, Fang Q, Zhang JY. Microstructure and mechanical properties of Mg–Li alloy processed by severe plastic deformation and annealing. Chin J Nonferrous Met. 2012;23(12):3267.
Yang HJ, Shao XH, Li SX, Wu SD, Zhang ZF. Enhancing strength and maintaining ductility of Mg–3%Li–1%Sc alloy by equal channel angular pressing. Mater Sci Forum. 2010;667–669:839.
Wang TZ, Zheng HP, Wu RZ, Yang JL, Ma XD, Zhang ML. Preparation of fine-grained and high-strength Mg–8Li–3Al–1Zn alloy by accumulative roll bonding. Adv Eng Mater. 2016;18(2):304.
Xu J, Su Q, Wang CX, Wang XW, Shan DB, Guo B, Landon TG. Micro-embossing formability of a superlight dual-phase Mg–Li alloy processed by high-pressure torsion. Adv Eng Mater. 2019;21(2):1800961.
Sharath PC, Udupa KR, Kumar GVP. Effect of multi directional forging on the microstructure and mechanical properties of Zn–24 wt% Al–2 wt% Cu alloy. Trans Indian Inst Met. 2016;70:89.
Karami M, Mahmudi R. The microstructural, textural, and mechanical properties of extruded and equal channel angularly pressed Mg-Li-Zn alloys. Metall Mater Trans A. 2013;44(8):3934.
Wei GB, Mahmoodkhani Y, Peng XD, Hadadzadeh A, Xu TC, Liu JW, Xie WD, Wells MARYA. Microstructure evolution and simulation study of a duplex Mg–Li alloy during double change channel angular pressing. Mater Des. 2016;90:266.
Rogl G, Sstman D, Schafler E, Horky J, Kerber M, Zehetbauer M, Falmbigl M, Rogl P, Royanian E, Bauer E. High-pressure torsion, a new processing route for thermoelectrics of high ZTs by means of severe plastic deformation. Acta Mater. 2012;60(5):2146.
Matsunoshita H, Edalati K, Furui M, Horita Z. Ultrafine-grained magnesium–lithium alloy processed by high-pressure torsion: low-temperature superplasticity and potential for hydroforming. Mater Sci Eng A. 2015;640:443.
Srinivasarao B, Zhilyaev AP, Gutierrez-Urrutia I, Perez-Prado MT. Stabilization of metastable phases in Mg–Li alloys by high-pressure torsion. Scr Mater. 2013;68(8):583.
Su Q, Xu J, Li Y, Yoon JI, Shan D, Guo B, Kim HS. Microstructural evolution and mechanical properties in superlight Mg–Li alloy processed by high-pressure torsion. Materials. 2018;11(4):598.
Hou LG, Wang TZ, Wu RZ, Zhang JH, Zhang ML, Dong AP, Sun BD, Betsofen S, Krit B. Microstructure and mechanical properties of Mg-5Li-1Al sheets prepared by accumulative roll bonding. J Mater Sci Technol. 2018;34(2):317.
Cao FR, Zhang J, Ding X, Xue GQ, Liu SY, Sun CF, Su RK, Teng XM. Mechanical properties and microstructural evolution in a superlight Mg–6.4Li–3.6Zn–0.37Al–0.36Y alloy processed by multidirectional forging and rolling. Mater Sci Eng A. 2019;760:377.
Kudela S, Gergely V, Jansch E, Hofmann A, Baunack S, Oswald S, Wetzig K. Compatibility between PAN-based carbon fibres and Mg–8Li alloy during the pressure infiltration process. J Mater Sci. 1994;29:5576.
Xiao P, Gao YM, Yang CC, Li YF, Huang XY, Liu QK, Zhao SY, Xu FX, Gupta M. Strengthening and toughening mechanisms of Mg matrix composites reinforced with specific spatial arrangement of in-situ TiB2 nanoparticles. Compos Part B Eng. 2020;198:108174.
Wu LB, Meng XR, Wu RZ, Cui CL, Zhang ML, Zhang JH. Solid-state composite technology for B4Cp reinforced magnesium-lithium alloy. Trans Nonferrous Met Soc China. 2011;21(4):820.
Cui CL, Wu LB, Wu RZ, Zhang JH, Zhang ML. Influence of yttrium on microstructure and mechanical properties of as-cast Mg–5Li–3Al–2Zn alloy. J Alloys Compd. 2011;509(37):9045.
Acknowledgements
This study was financially supported by the National Natural Science Foundation of China (Nos. 51771115, 51775334, 51821001 and U2037601) and the Joint Fund for Space Science and Technology (No. 6141B06310106).
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Peng, X., Liu, WC. & Wu, GH. Strengthening-toughening methods and mechanisms of Mg–Li alloy: a review. Rare Met. 41, 1176–1188 (2022). https://doi.org/10.1007/s12598-021-01874-2
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DOI: https://doi.org/10.1007/s12598-021-01874-2