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Self-assembled monolayers for electrochemical migration protection of low-temperature sintered nano-Ag paste

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摘要

室温下利用巯基苯并噻唑钠在低温固化纳米银浆电极表面制备自组装防护膜, 采用水滴实验法研究该自组装防护膜对其电化学迁移失效行为的影响规律, 以平均短路失效时间作为评价电化学迁移行为的指标参数。本工作中采用电化学阻抗法、动电位极化法、局部电化学阻抗谱和扫描开尔文探针等方法原位研究自组装成膜过程。结果表明:电化学迁移过程中形成的树枝状银枝晶可以诱导相邻电极发生短路失效;巯基苯并噻唑钠自组装防护膜可以降低电化学迁移过程中阳极溶解速率进而抑制枝晶的生长;随着巯基苯并噻唑钠预膜液浓度增加, 自组装膜对电化学迁移失效行为的抑制效率提高;最佳自组装时间为60 min;随着外加偏压增大,电化学迁移失效时间越短。基于上述实验结果, 建立巯基苯并噻唑钠自组装膜对低温固化纳米银浆电化学迁移失效的防护机制。

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References

  1. Liao B, Wang H, Wan S, Xiao W, Guo X. Electrochemical migration inhibition of tin by disodium hydrogen phosphate in water drop test. Metals. 2020;10(7):942.

    Article  CAS  Google Scholar 

  2. Liao B, Wang H, Xiao W, Cai Y, Guo X. Recent advances in method of suppressing dendrite formation of tin-based solder alloys. J Mater Sci Mater Electron. 2020;31(8):13001.

    Article  CAS  Google Scholar 

  3. Medgyes B, Illés B, Harsányi G. Electrochemical migration behaviour of Cu, Sn, Ag and Sn63/Pb37. J Mater Sci Mater Electron. 2012;23(2):551.

    Article  CAS  Google Scholar 

  4. Zhong X, Lu W, Liao B, Medgyes B, Hu J, Zheng Y, Zeng D, Zhang Z. Evidence for Ag participating the electrochemical migration of 96.5Sn–3Ag–0.5Cu alloy. Corros Sci. 2019;156:10.

    Article  CAS  Google Scholar 

  5. Wang H, Quan X, Zeng Q, Wu Y, Liao B, Guo X. Electrochemical corrosion and protection of low-temperature sintered silver nanoparticle paste in NH4Cl solution. J Mater Sci Mater Electron. 2021;32:13748.

    Article  CAS  Google Scholar 

  6. Xiang XZ, Gong WY, Kuang MS, Wang L. Progress in application and preparation of silver nanowires. Rare Met. 2016;35(4):289.

    Article  CAS  Google Scholar 

  7. Zhou BY, Fan SJ, Fan YC, Zheng Q, Zhang X, Jiang W, Wang LJ. Recent progress in ceramic matrix composites reinforced with graphene nanoplatelets. Rare Met. 2020;39(5):513.

    Article  CAS  Google Scholar 

  8. Liao B, Wang H, Kang L, Wan S, Guo X. Electrochemical migration behavior of low-temperature-sintered Ag nanoparticle paste using water-drop method. J Mater Sci Mater Electron. 2021;32(5):5680.

    Article  CAS  Google Scholar 

  9. Khazaka R, Mendizabal L, Henry D. Review on joint shear strength of nano-silver paste and its long-term high temperature reliability. J Electron Mater. 2014;43(7):2459.

    Article  CAS  Google Scholar 

  10. Hu JQ, Li R, Liu Y, Su Y. An overview of healthcare monitoring by flexible electronics. Sci China Phys Mech. 2018;61(9):94601.

    Article  Google Scholar 

  11. Al Zoubi W, Ko YG. Self-assembly of hierarchical N-heterocycles-inorganic materials into three-dimensional structure for superior corrosion protection. Chem Eng J. 2019;356:850.

    Article  CAS  Google Scholar 

  12. Zheng H, Chen X, Yang Y, Li L, Feng CQ, Wang SQ. Self-assembled uniform double-shelled Co3V2O8 hollow nanospheres as anodes for high-performance Li-ion batteries. Rare Met. 2021;40(12):3485.

    Article  CAS  Google Scholar 

  13. Kaseem M, Hussain T, Baek SH, Ko YG. Formation of stable coral reef-like structures via self-assembly of functionalized polyvinyl alcohol for superior corrosion performance of AZ31 Mg alloy. Mater Des. 2020;193:108823.

    Article  CAS  Google Scholar 

  14. Korrapati VK, Scharnagl N, Letzig D, Zheludkevich ML. Self-assembled layers for the temporary corrosion protection of magnesium-AZ31 alloy. Corros Sci. 2020;169:108619.

    Article  CAS  Google Scholar 

  15. Mo Q, Qin G, Ling K, Lv X, Wang N, Li W. Layer-by-layer self-assembled polyurea layers onto MAO surface for enhancing corrosion protection to aluminum alloy 6063. Surf Coat Technol. 2021;405:126653.

    Article  CAS  Google Scholar 

  16. Giuseppone N, Lehn J. Constitutional dynamic self-sensing in a zinc II/polyiminofluorenes system. J Am Chem Soc. 2004;126(37):11448.

    Article  CAS  Google Scholar 

  17. Tauk L, Schröder AP, Decher G, Giuseppone N. Hierarchical functional gradients of pH-responsive self-assembled monolayers using dynamic covalent chemistry on surfaces. Nat Chem. 2009;1(8):649.

    Article  CAS  Google Scholar 

  18. Markevicius G, Chaudhuri S, Bajracharya C, Rastogi R, Xiao J, Burnett C, Chastek T. Polyoligomeric silsesquioxane (POSS)–hydrogenated polybutadiene polyurethane coatings for corrosion inhibition of AA2024. Prog Org Coat. 2012;75(4):319.

    Article  CAS  Google Scholar 

  19. Yang H, Sun Y, Ji J, Wei S, Xuan Z, Yao Y, Zhang Z. 2-Mercaptobenzothiazole monolayers on zinc and silver surfaces for anticorrosion. Corros Sci. 2008;50(11):3160.

    Article  CAS  Google Scholar 

  20. Liu D, Han E, Song Y, Shan D. Enhancing the self-healing property by adding the synergetic corrosion inhibitors of Na3PO4 and 2-mercaptobenzothiazole into the coating of Mg alloy. Eelctrochim Acta. 2019;323:134796.

    Article  CAS  Google Scholar 

  21. Liu X, Yue T, Qi K, Xia B, Chen Z, Qiu Y, Guo X. Probe into metal-organic framework membranes fabricated via versatile polydopamine-assisted approach onto metal surfaces as anticorrosion coatings. Corros Sci. 2014;177:108949.

    Article  Google Scholar 

  22. Salzanodeluna M, Buonocore GG, Giuliani C, Messina E, Dicarlo G, Lavorgna M, Ambrosio L, Ingo G. Long-lasting efficacy of coatings for bronze artwork conservation: the key role of layered double hydroxide nanocarriers in protecting corrosion inhibitors from photodegradation. Angewandte Chemie Int Ed. 2018;130(25):7380.

    Article  Google Scholar 

  23. Goudarzi N, Farahani H. Investigation on 2-mercaptobenzothiazole behavior as corrosion inhibitor for 316-stainless steel in acidic media. Anti-Corros Method Mater. 2014;61(1):20.

    Article  CAS  Google Scholar 

  24. Liao B, Wang H, Kang L, Wan S, Quan X, Zhong X, Guo X. Electrochemical migration behavior of low-temperature-sintered Ag nanoparticle paste using water-drop method. J Mater Sci Mater Electron. 2021;32(5):5680.

    Article  CAS  Google Scholar 

  25. Daoud D, Douadi T, Hamani H, Chafaa S, Al-Noaimi M. Corrosion inhibition of mild steel by two new S-heterocyclic compounds in 1 M HCl: experimental and computational study. Corros Sci. 2015;94:21.

    Article  CAS  Google Scholar 

  26. Guo L, Zhu S, Zhang S, He Q, Li W. Theoretical studies of three triazole derivatives as corrosion inhibitors for mild steel in acidic medium. Corros Sci. 2014;87:366.

    Article  CAS  Google Scholar 

  27. Apachitei I, Fratila-Apachitei LE, Duszczyk J. Microgalvanic activity of an Mg–Al–Ca-based alloy studied by scanning Kelvin probe force microscopy. Scripta Mater. 2007;57(11):1012.

    Article  CAS  Google Scholar 

  28. Liao B, Cen H, Chen Z, Guo X. Corrosion behavior of Sn-30Ag-0.5Cu alloy under chlorine-containing thin electrolyte layers. Corros Sci. 2018;143:347.

    Article  CAS  Google Scholar 

  29. Liao B, Chen Z, Qiu Y, Zhang G, Guo X. Effect of citrate ions on the electrochemical migration of tin in thin electrolyte layer containing chloride ions. Corros Sci. 2016;112:393.

    Article  CAS  Google Scholar 

  30. Zhu X, Liu Y, Long J, Liu X. Electrochemical migration behavior of Ag-plated Cu-filled electrically conductive adhesives. Rare Met. 2012;31(1):64.

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This study was financially supported by the National Natural Science Foundation of China (Nos. 52001080 and 51971067), the Science and Technology Research Project of Guangzhou (Nos. 202102020467 and 202002010007), the Platform Research Capability Enhancement Project of Guangzhou University (No. 69-620939), Guangzhou University’s 2020 Training Program for Talent (No. 69-62091109) and Provincial Innovation Training Program for College Students of Guangzhou University (No. S202011078017).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Guangzhou Key Laboratory for Clean Energy and Materials, Guangzhou University, Guangzhou, 510006, China

    Shan Wan, Hong Wang, Bo-Kai Liao & Xing-Peng Guo

  2. School of Chemistry and Chemical Engineering, Jiangxi Province Engineering Research Center of Ecological Chemical Industry, Jiujiang University, Jiujiang, 332005, China

    Jin-Hang Liu

  3. School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, 430074, China

    Xing-Peng Guo

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  1. Shan Wan
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  2. Hong Wang
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Correspondence to Bo-Kai Liao or Xing-Peng Guo.

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Wan, S., Wang, H., Liu, JH. et al. Self-assembled monolayers for electrochemical migration protection of low-temperature sintered nano-Ag paste. Rare Met. 41, 1239–1244 (2022). https://doi.org/10.1007/s12598-021-01866-2

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  • DOI: https://doi.org/10.1007/s12598-021-01866-2

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