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Phase transformation behavior and mechanical properties of Ti50Ni49−x Fe1Co x shape memory alloys

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Abstract

In this article, the influence of Co addition on phase transformation behavior and mechanical properties of TiNiFe shape memory alloy was investigated extensively. Differential scanning calorimetry (DSC) measurements shows that martensitic start transformation temperatures (M s) decrease drastically with increasing Co content, while the R phase transformation start temperatures (R s) vary slightly. Nevertheless, the substitution of Ni with Co does not exert substantial influence on the two-stage transformation behavior of the TiNiFe alloy. The results from stress–strain curves indicate that higher critical stress for stress-induced martensitic transformation (σ SIM) has been obtained because of Co addition. In such cases, the Ti50Ni48Fe1Co1.0 alloy maintains a good shape memory effect, and a maximum recoverable strain of 7.5 % can be obtained.

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References

  1. Liu FS, Ding Z, Li Y, Xu HB. Phase transformation behaviors and mechanical properties of TiNiMo shape memory alloys. Intermetallics. 2005;13(3–4):357.

    Article  Google Scholar 

  2. Xu HB, Jiang CB, Gong SK, Feng G. Martensitic transformation of the Ti50Ni48Fe2 alloy deformed at different temperatures. Mater Sci Eng A. 2000;28(1–2):234.

    Google Scholar 

  3. Zheng YF, Zhao LC. NiTi Alloys Applied in the Medical Field. Beijing: Science Press; 2004. 57.

  4. Xu Q, Liu FS. Transformation behavior and shape memory effect of Ti50−x Ni48Fe2Nb x alloys by aging treatment. Rare Met. 2012;3(14):311.

    Article  Google Scholar 

  5. Liu Y, Liu FS. Transformation behaviors of Ti48.5Ni48Fe2Nb1.5 dependence of annealing and thermomechanical cycling. Rare Met. 2012;31(3):231.

    Article  CAS  Google Scholar 

  6. Uchil J, Ganesh Kumara K, Mashesh KK. Effect of heat treatment temperature and thermal cycling on phase transformations in Ni–Ti–Cr alloy. J Alloys Compd. 2001;325(5):210.

    Article  CAS  Google Scholar 

  7. Marquina ML, Jiménez M, Marquina V, Aburto S, Ridaura R, Gómez R, Escudero R, Ríos-Jara D. Structural transitions in a TiNiFe shape memory alloy. Mater Charact. 1994;32(3):189.

    Article  CAS  Google Scholar 

  8. Goo E, Duerig T, Melton K, Sinclair R. Mechanical twinning in Ti50Ni47Fe3 and Ti49Ni51 alloys. Acta Met. 1985;33(9):1725.

    Article  CAS  Google Scholar 

  9. Hwang CM, Meichle M, Salamon MB, Wayman CM. Transformation behaviour of a Ti50Ni47Fe3 alloy I. Premartensitic phenomena and the incommensurate phase. Philos Mag A. 1983;47(C4):231.

    Google Scholar 

  10. Moberly WJ, Proft JL, Duerig TW, Sinclair R. Deformation, twinning and thermo-mechanical strengthening of Ti50Ni47Fe3. Acta Met Mater. 1990;38(12):2601.

    Article  CAS  Google Scholar 

  11. Sui JH, Gao ZY, Li YF, Zhang ZG, Cai W. A study on NiTiNbCo shape memory alloy. Mater Sci Eng A. 2009;508(1):33.

    Google Scholar 

  12. Jing RR, Liu FS. The influence of Co addition on phase transformation behavior and mechanical properties of TiNi alloys. Chin J Aeronaut. 2007;20(2):153.

    Article  Google Scholar 

  13. Kishi Y, Yajiba Z, Shimizu K. Relation between tensile deformation behavior and microstructure in a Ti–Ni–Co shape memory alloy. Mater Trans. 2002;43(5):834.

    Article  CAS  Google Scholar 

  14. Hosoda H. Martensite transformation temperatures and mechanical properties of ternary NiTi alloys with off-stoichiometric compositions. Intermetallics. 1998;6(4):291.

    Article  CAS  Google Scholar 

  15. Liu YN, Calvin SP. Criteria for pseudoelasticity in near-equiatomic NiTi shape memory alloys. Acta Mater. 1997;45(11):4431.

    Article  CAS  Google Scholar 

Download references

Acknowledgment

This project was financially supported by the National Natural Science Foundation of China (No. 50921003) and the Industry, Education and Research Projects of the China Aviation Industrial (No.cxy2012BH04).

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Correspondence to Fu-Shun Liu.

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Chen, B., Liu, FS. Phase transformation behavior and mechanical properties of Ti50Ni49−x Fe1Co x shape memory alloys. Rare Met. 32, 225–227 (2013). https://doi.org/10.1007/s12598-013-0073-6

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  • DOI: https://doi.org/10.1007/s12598-013-0073-6

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