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Construction of 3D micro-cellular structure of the metal / ceramic system

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Abstract

3D micro-cellular structure of Al90Mn9Ce1 / Al2O3 (TiO2, SiC, ZrO2), Fe76Si9B10P5 / Zn0.5Ni0.5Fe2O4 (Co0.5Ni0.5Fe2O4) metal / ceramic system were constructed, based on special sintering mechanism of spark plasma sintering (SPS). The SPS micro local-area temperature field and sintering mechanism at lower macro sintering temperature were analyzed. The microstructure of samples, phase analysis and microstructure of interface were investigated via SEM, XRD and TEM. The results indicate that the 3D micro-cellular structure have been found in the samples, the cellular wall which is nano-ceramic sintered body is uniform, and the alloy cellular body is surrounded by nano-ceramic cellular wall. The infiltration transition area between cellular body and cellular wall implies the combination of interface is fine. Apropos micro-nano-discharge air gap provides interface local transient high temperature. The phase of the composites could maintain small metastable state because of low temperature rapid sintering.

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References

  1. Wang S.C., Deng Z.X., and Shen W.D., Sound transmission loss characteristics of unbounded orthotropic sandwich panels in bending vibration considering transverse shear deformation, Compos Struct, 2010, 92(12): 2885.

    Article  Google Scholar 

  2. Chen J.M., Hsu C.H., Lin Y.R, Hsiao M.H., and Fey G.T.K., High-power LiFePO4 cathode materials with a continuous nano carbon network for lithium-ion batteries, J. Power Sources, 2008, 184(2): 498.

    Article  CAS  Google Scholar 

  3. Matteo P., Massimiliano V., and Claudio B., Effect of porosity of cordierite performs on microstructure and mechanical strength of co-continuous ceramic composites, J. Eur. Ceram. Soc., 2007, 27: 131.

    Article  Google Scholar 

  4. Lee S.P., Chen Y.J., Ho C.M., Chang C.P., and Hong Y.S., A study on synthesis and characterization of the core-shell materials of Mn1−x ZnxFe2O4-Polyaniline, Mat Sci Eng. B, 2007, 143(1–3): 1.

    Article  CAS  Google Scholar 

  5. Mamedov V., Spark plasma sintering as advanced PM sintering method, Powd Metall, 2002, 45(4): 322.

    Article  CAS  Google Scholar 

  6. Tamburini U.A., Garay J.E., and Munir Z.A., Fast low-temperature consolidation of bulk nanometric ceramic materials, Scripta Mater, 2006, 54: 823.

    Article  Google Scholar 

  7. Zhao Z.K., Yao K.F., and Li J.F., A bulk metal/ceramic composite materal with a celluar structure, Chinese Sci. Bull., 2006, 51(2): 235.

    Article  CAS  Google Scholar 

  8. Chun C.H., Lin C.P., Wen S.B., and Shen Y.H., Sintering of aluminum nitride by using alumina crucible and MoSi2 heating element at temperature of 1650 and 1700 °C, Ceram Int, 2009, 35(8): 3455.

    Article  Google Scholar 

  9. Jiang Q., and Lu H.M., Size dependent interface energy and its applications, Surf. Sci. Rep., 2008, 63: 427.

    Article  CAS  Google Scholar 

  10. Jiang Q., and Lu H.M., Size-dependent interface energies, J. Mater. Sci. Technol., 2005, 21(suppl. 1): 6.

    CAS  Google Scholar 

  11. Jiang Q., Zhao D.S., and Zhao M., Size-dependent interface energy and related interface stress, Acta Mater., 2001, 49: 3143.

    Article  CAS  Google Scholar 

  12. Lu H.M., and Jiang Q., Size-dependent surface energies of nanocrystals, J. Phys. Chen. B, 2004, 108: 5617.

    Article  CAS  Google Scholar 

  13. Jiang Q., and Shi F.G., Size-dependent initial sintering temperature of ultrafine particles, J. Mater. Sci. Technol., 1998, 14: 171.

    CAS  Google Scholar 

  14. Zhang Z., Li J. C., and Jiang Q., Modelling for size-dependent and dimension-dependent melting of nanocrystals, J. Phys. D, 2000, 33: 2653.

    Article  CAS  Google Scholar 

  15. Zhang Z., Lu X.X., and Jiang Q., Finite size effect on melting enthalpy and melting entropy of nanocrystals, Physica B, 1999, 270: 249.

    Article  CAS  Google Scholar 

  16. Tokita M., Development of large sized ceramic/metal bulk FGM fabricated by spark plasma sintering, Mater Sci. Forum, 1999, 308-311: 83.

    Article  CAS  Google Scholar 

  17. Zhang J.X., Zhang G.Z., Zhao S.X., and Song X.Y., Binder-free WC bulk synthesized by spark plasma sintering. J. Alloy Compd., 2009, 479(1–2): 427.

    Article  CAS  Google Scholar 

  18. Zhao Z.K., Yao K.F., Jin S.Z., and Li J.F., Bulk Al90Mn9Ce1 alloy with ultra-high strength prepared by spark plasma sintering. Acta Metall. Sin., 2005, 41: 1298.

    CAS  Google Scholar 

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Correspondence to Zhankui Zhao.

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Wang, S., Li, S., Wang, M. et al. Construction of 3D micro-cellular structure of the metal / ceramic system. Rare Metals 30 (Suppl 1), 604–609 (2011). https://doi.org/10.1007/s12598-011-0355-z

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  • DOI: https://doi.org/10.1007/s12598-011-0355-z

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