Abstract
La1−x Sr x Co1−y Fe y O3 cathode materials for solid oxide fuel cells were prepared by the microwave synthesis method. The reaction mechanism was studied using a thermal analysis method. The influences of microwave synthesis conditions were examined and the characteristics of the samples were determined by X-ray diffraction and scanning electron microscopy. It was found that the optimum conditions were the microwave power of 800 W and the reaction time of 40 min. Samples with perosvkite-type crystal structure were obtained. The samples consist of uniformly distributed internal particles and the particle size is less than 1 μm.
Similar content being viewed by others
References
Bao X., Chen Y.H., and Lu X.Y., Preparation and characterization of Ba0.4Sr0.6Co1−x FexO3−δ cathode materials, Chin. J. Inorg. Chem., 2008, 24(3): 363.
Tai L.W., Nasrallah M.M., Anderson H.U., and Sparlin D.M., Structure and electrical properties of La1−x SrxCo1−y FeyO3. Part 1: The system La1−x SrxCo1−y FeyO3, Solid State Ionics, 1995, 76(3–4): 259.
Tai L.W., Nasrallah M.M., Anderson H.U., and Sparlin D.M., Structure and electrical properties of La1−x SrxCo1−y FeyO3. Part 2: The system La1−x SrxCo1−y FeyO3, Solid State Ionics, 1995, 76(3–4): 273.
Lee S.B., Jang I.C., Lim H.H., Aravindan V., Kim H.S., and Lee Y.S., Preparation and electrochemical characterization of LiFePO4 nanoparticles with high rate capability by a sol-gel method, J. Alloys Compd., 2010, 491(1–2): 668.
Guo R.S., Wei Q.T., Li H.L., and Wang F.H., Synthesis and properties of La0.7Sr0.3MnO3 cathode by gel combustion, Mater. Lett., 2006, 60(2): 261.
Zhai X.J., Zhou Y.G., Fu Y., Bai B., and Wang J., Lithium ion battery cathode material LiCoO2 synthesized by microwave method, J. Rare Earths, 2005, 23(Suppl.1): 85.
Zhai X.J., Fu Y., Han Q., and Chu G., Microwave technology synthesized the cathode materials of solid oxide fuel cell La1−x SrxMnO3, Chin. J. Mater. Res., 2008, 22(5): 539.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Zhai, X., Shi, W., Fu, Y. et al. Microwave synthesis of La1−x Sr x Co1−y Fe y O3 cathode materials for solid oxide fuel cells. Rare Metals 29, 576–578 (2010). https://doi.org/10.1007/s12598-010-0172-6
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12598-010-0172-6