Skip to main content
Log in

Geochemical processes of groundwater salinization in an arid area, southeastern Tunisia

  • Original Paper
  • Published:
Arabian Journal of Geosciences Aims and scope Submit manuscript

Abstract

Salinization is an environmental issue that affects different regions worldwide. Geochemical approaches and statistical tools are combined to investigate the origin and process of groundwater salinization in Menzel Habib shallow aquifer. The inland aquifer from Menzel Habib area is in the northwest of Gabès, southeastern Tunisia. A total of twenty-five water samples were selected and collected in the study area. Physicochemical parameters (electrical conductivity, pH, total dissolved solids) were measured in situ, and major ions (Na, Mg, Ca, K, Cl, SO4, HCO3, F, and Br) were determined. The obtained results show a Na-Cl groundwater dominant facies (60%), Na-SO4 (36%), and mixed water type (4%). Thus, a correlation between total dissolved solids and major ions shows the contribution of SO4, Cl, Na, Ca, and Mg in groundwater salinization. The salinization of groundwater is due to the dissolution of Triassic evaporites, which are related to the tectonic context of the region, and to the cationic exchange. Furthermore, statistical approaches, especially principal component analysis, reveal that the high groundwater mineralization is due to the evaporite dissolution. Multiple linear regression leads to establish a model linking total dissolved solids to the different chemical elements involved in groundwater salinization.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12

Similar content being viewed by others

References

  • Abdelaziz S, Gad MI, El Tahan AHMH (2020) Groundwater quality index based on PCA: Wadi El-Natrun, Egypt. J Afr Earth Sci 172:103964. https://doi.org/10.1016/j.jafrearsci.2020.103964

    Article  Google Scholar 

  • Abdipour M, Younessi-Hmazekhanlu M, Ramazani SH (2019) Artificial neural networks and multiple linear regression as potential methods for modeling seed yield of safflower (Carthamus tinctorius L.). Ind Crop Prod 127:185–194. https://doi.org/10.1016/j.indcrop.2018.10.050

    Article  Google Scholar 

  • Abid K, Trabelsi R, Zouari K, Abidi B (2009) Caractérisation hydrogéochimique de la nappe du Continental Intercalaire (sud tunisien)/Hydrogeochemical characterization of the Continental Intercalaire aquifer (southern Tunisia). Hydrol Sci J 54(3):526–537. https://doi.org/10.1623/hysj.54.3.526

    Article  Google Scholar 

  • Agoubi B (2018) Assessing hydrothermal groundwater flow path using Kohonen’s SOM, geochemical data, and groundwater temperature cooling trend. Environ Sci Pollut Res 25:13597–13610. https://doi.org/10.1007/s11356-018-1525-1

    Article  Google Scholar 

  • Agoubi B, Kharroubi A, Bouri S, Abida H (2010) Contribution of geostatistical modelling to mapping groundwater level and aquifer geometry, case study of Sfax’s deep aquifer, Tunisia. Middle-East J Sci Res 6/3:305–316

    Google Scholar 

  • Agoubi B, Kharroubi A, Abida H (2012) Saltwater intrusion modelling in Jorf coastal aquifer, South eastern Tunisia: geochemical, geoelectrical and geostatistical application. Hydrol Process 27:1191–1199. https://doi.org/10.1002/hyp.9207

    Article  Google Scholar 

  • Agoubi B, Kharroubi A, Abichou T, Abida H (2013) Hydrochemical and geoelectrical investigation of Marine Jeffara Aquifer, southeastern Tunisia. Appl Water Sci 15:415–429

    Article  Google Scholar 

  • Alassane A, Trabelsi R, Dovonon LF, Odeloui DJ, Boukari M, Zouari K, Mama D (2015) Chemical evolution of the continental terminal shallow aquifer in the south of coastal sedimentary basin of Benin (West-Africa) using multivariate factor analysis. J Water Resour Prot 07(06):496–515. https://doi.org/10.4236/jwarp.2015.76040

    Article  Google Scholar 

  • Argamasilla M, Barberá JA, Andreo B (2017) Factors controlling groundwater salinization and hydrogeochemical processes in coastal aquifers from southern Spain. Sci Total Environ 580:50–68. https://doi.org/10.1016/j.scitotenv.2016.11.173

    Article  Google Scholar 

  • Ayers R, Westcot D (1994) Food, Agriculture Organization of the United Nations (FAO), Water quality for agriculture, irrigation and drainage, Rome: Paper No. 29. Rev. 1, M-56

  • Beekman HE, Eggenkamp HGM, Appelo CAJ (2011) An integrated modelling approach to reconstruct complex solute transport mechanisms - Cl and δ37Cl in pore water of sediments from a former brackish lagoon in the Netherlands. Appl Geochem 26(3):257–268. https://doi.org/10.1016/j.apgeochem.2010.11.026

    Article  Google Scholar 

  • Ben Cheikh N (2013) Etude des relations hydrodynamiques entre la nappe profonde de Sfax et les systèmes aquifères méridionaux (Menzel Habib et Gabès Nord): origines et mécanismes de minéralisation des eaux souterraines. Unpublished PhD. Thesis, University of Sfax, Tunisia, 161 pp

  • Ben Hammouda MF, Carreira P, Marques JM, Egenkamp H (2013) Geochemical and isotopic investigations to study the origin of mineralization of the coastal aquifer of Sousse, Tunisia. Procedia Earth Planet Sci 7:61–64. https://doi.org/10.1016/j.proeps.2013.03.106

    Article  Google Scholar 

  • Bi Y, Wu J, Zhai X, Shen S, Tang L, Huang K, Zhang D (2021) Application of partial least squares-discriminate analysis model based on water chemical compositions in identifying water inrush sources from multiple aquifers in mines. Geofluids 2021:ID 6663827. https://doi.org/10.1155/2021/6663827

    Article  Google Scholar 

  • Bouri S, Abida H, Khanfir H (2008) Impacts of wastewater irrigation in arid and semiarid regions: case of Sidi Abid region, Tunisia. Environ Geol 53(7):1421–1432. https://doi.org/10.1007/s00254-007-0751-5

    Article  Google Scholar 

  • Chamtouri I, Abida H, Khanfir H, Bouri S (2008) Impacts of at-site wastewater disposal systems on the groundwater aquifer in arid regions: case of Sfax City, southern Tunisia. Environ Geol 55:1123–1133

    Article  Google Scholar 

  • Cheikh B, Zouari K, Abidi B (2012) Geochemical and isotopic study of paleogroundwater salinization in southeastern Tunisia (Sfax bain). Quat Int J 257:34–42

    Article  Google Scholar 

  • Chen KP, Jiao JJ (2007) Seawater intrusion and aquifer freshening near reclaimed coastal area of Shenzhen. Water Sci Technol Water Supply 7(2):137–145. https://doi.org/10.2166/ws.2007.048

    Article  Google Scholar 

  • Cruz JV, Andrade C (2016) Groundwater salinization in Graciosa and Pico islands (Azores archipelago, Portugal): processes and impacts. J Hydrol Reg Stud 12:69–87. https://doi.org/10.1016/j.ejrh.2017.04.003

    Article  Google Scholar 

  • De Montely V, Radakovitch O, Vallet-Coulomb C, Blavoux B, Hermitte D, Valles V (2008) Origin of groundwater salinity and hydrogeochemical processes in a confined coastal aquifer: case of the Rhône delta (Southern France). Appl Geochem 23(8):2337–2349. https://doi.org/10.1016/j.apgeochem.2008.03.011

    Article  Google Scholar 

  • Dougha M, Hasbaia M (2019) Contribution of the multivariate analysis and origin for groundwater quality of mixed aquifer in the M'sila plain (Algeria). Int J Hydrol Sci Technol 9(2):154–172. https://doi.org/10.1504/IJHST.2019.098160

    Article  Google Scholar 

  • DRE (1985) Direction Régionale des Ressources en Eaux de Gabès, 1985. Nappe phréatique de Segui El Hamma (Menzel Lahbib): caractéristiques et minéralisation totale, 15 p

  • DRE (1978) Direction Régionale des Ressources en Eaux de Gabès. Etude hydrogéologique préliminaire du Segui Zougrata, 25 p

  • Fud G (2018) Deep belief network based ensemble approach for cooling load forecasting of air-conditioning system. Energy 148(C):269–282. https://doi.org/10.1016/j.energy.2018.01.180

    Article  Google Scholar 

  • Galton F (1885) Regression toward mediocrity in heredity stature. J Anthropol Inst 15:246–263

    Google Scholar 

  • Gattacceca JC, Vallet-Coulomb C, Mayer A, Claude C, Radakovitch O, Conchetto E, Hamelin B (2009) Isotopic and geochemical characterization of salinization in the shallow aquifers of a reclaimed subsiding zone: the southern Venise Lagoon coastland. J Hydrol 378(1/2):46–61. https://doi.org/10.1016/j.jhydrol.2009.09.005

    Article  Google Scholar 

  • Ghabayen SMS, McKee M, Kemblowski M (2006) Ionic and isotopic ratios for identification of salinity sources and missing data in the Gaza aquifer. J Hydrol 318(1/4):360–373. https://doi.org/10.1016/j.jhydrol.2005.06.041

    Article  Google Scholar 

  • Gibbs RJ (1970) Mechanisms controlling world water chemistry. Science 170(3962):1088–1090. https://doi.org/10.1126/science.170.3962.1088

    Article  Google Scholar 

  • Gopinath S, Srinivasamoorthy K, Saravanan K, Prakash R (2019) Tracing groundwater salinization using geochemical and isotopic signature in Southeastern coastal Tamilnadu, India. Chemosphere 236:Article 124305. https://doi.org/10.1016/j.chemosphere.2019.07.036

    Article  Google Scholar 

  • Hani A, Karimineja MT (2010) Toxic metal distribution in Soils of Kaveh Industrial city Iran. World Appl Sci J 8/11:1333–1342. https://doi.org/10.1007/s13201-013-0091-4

    Article  Google Scholar 

  • IRA - Institut des Régions Arides (2011) Etat de référence environnemental 2010 dans l’observatoire de Menzel Habib, gouvernorat de Gabès, sud-est de la Tunisie

  • Isaaks EH, Srivastava RM (1989) An introduction to applied geostatistics. University Press, New York, Oxford, pp 278–322

    Google Scholar 

  • Jorgensen NO, Andersen MS, Engesgaard P (2008) Investigation of a dynamic seawater event using strontium isotopes (87Sr/86Sr). J Hydrol 348:257–269

    Article  Google Scholar 

  • Ju Q, Hu Y (2021) Source identification of mine water inrush based on principal component analysis and grey situation decision. Environ Earth Sci 80:157. https://doi.org/10.1007/s12665-021-09459-z

    Article  Google Scholar 

  • Kammoun S, Trabelsi R, Re V, Zouari K, Henchiri J (2018) Groundwater quality assessment in semi-arid regions using integrated approaches: the case of Grombalia aquifer (NE Tunisia). Environ Monit Assess 190:87. https://doi.org/10.1007/s10661-018-6469-x

    Article  Google Scholar 

  • Katz A, Starinsky A, Marion GM (2011) Saline waters in basement rocks of the Kaapvaal Craton, South Africa. Chem Geol 289(1/2):163–170. https://doi.org/10.1016/j.chemgeo.2011.08.002

    Article  Google Scholar 

  • Kharroubi A, Tlahigue F, Agoubi B, Azri C, Bouri S (2012) Hydrochemical and statistical studies of the groundwater salinization in Mediterranean arid zones: case of the Jerba coastal aquifer in southeast Tunisia. Environ Earth Sci 67/7:2089–2100. https://doi.org/10.1007/s12665-012-1648-5

    Article  Google Scholar 

  • Kim Y, Lee KS, Koh DC, Lee DH, Lee SG, Park WB, Koh GW, Woo NC (2003) Hydrogeochemical and isotopic evidence of groundwater salinization in costal aquifer: a case study in Jesu volcanic island, Korea. J Hydrol 270:282–294

    Article  Google Scholar 

  • Kloppman W, Bourhane A, Shomburgk S, Asfirane F (2011) Salinisation des masses d’eau en France : du constat au diagnostic. BRGM/RP-60186-FR, 41 pp

  • Kouzana L, Ben Mammou A, Sfar Felfoul M (2009) Seawater intrusion and associated processes: case of the Korba aquifer (Cap-Bon, Tunisia). C R Geosci 341(1):21–35. https://doi.org/10.1016/j.crte.2008.09.008

    Article  Google Scholar 

  • Li J, Wang Y, Xie X (2015) Cl/Br ratios and chlorine isotope evidences for groundwater salinization and its impact on groundwater arsenic, fluoride and iodine enrichment in the Datong basin, China. Sci Total Environ 544:158–167. https://doi.org/10.1016/j.scitotenv.2015.08.144

    Article  Google Scholar 

  • Martos FS, Bosch AP, Sanchez LM, Izquierdo AV (2002) Identification of the origin of salinization in groundwater using minor ions (lower Andarax, Southeast Spain). Sci Total Environ 297(1-3):43–58. https://doi.org/10.1016/s0048-9697(01)01011-7

    Article  Google Scholar 

  • Matheron G (1963) Principles of geostatistics. Econ Geol 58:1246–1266

    Article  Google Scholar 

  • Mejri S, Chekirbene A, Tsujimura M, Boughdiri M, Mlayah A (2018) Tracing groundwater salinization processes in an inland aquifer: a hydrogeochemical and isotopic approach in Sminja aquifer (Zaghouan, northeast of Tunisia). J Afr Earth Sci 147:511–522. https://doi.org/10.1016/j.jafrearsci.2018.07.009

    Article  Google Scholar 

  • Mollema PN, Antonellini M, Dinelli E, Gabbianelli G, Greggio N, Stuyfzand PJ (2013) Hydrochemical and physical processes influencing salinization and freshening in Mediterranean low-lying coastal environments. Appl Geochem 34:207–221. https://doi.org/10.1016/j.apgeochem.2013.03.017

    Article  Google Scholar 

  • Monjerezi M, Rolf DV, Per Aagaard A, Gebru G, Saka JDK (2011) Using 87Sr/86Sr, δ18O and δ2H isotopes along with major chemical composition to assess groundwater salinization in lower Shire valley, Malawi. Appl Geochem 26:2201–2214. https://doi.org/10.1016/j.apgeochem.2011.08.003

    Article  Google Scholar 

  • Montgomery DC, Peck EA (1992) Introduction to linear regression analysis, second edn. John Willey & Sons, New York

    Google Scholar 

  • Mountadar S, Younsi A, Hayani A, Siniti M, Tahiri S (2018) Groundwater salinization process in the coastal aquifer Sidi Abed-Ouled Ghanem (Province of El Jadida, Morocco). J Afr Earth Sci 147:169–177. https://doi.org/10.1016/j.jafrearsci.2018.06.025

    Article  Google Scholar 

  • Myers RH (1990) Classical and modern regression with applications, second edn. PWS-KENT Publishing Co., Boston

    Google Scholar 

  • Neter J, Wasserman W, Kutner MH (1985) Applied linear statistical models, 2nd edn. Irwin Inc, Homewood, lL, Richard D

    Google Scholar 

  • Ouled Ghrib, Slimane MF (1994) Nouvelles données géologiques sur l’Atlas méridional de la Tunisie: mise en évidence du Trias dans la chaîne de Gafsa. Notes de service géologique de Tunisie 60, 5-10

  • Pisinaras V, Tsihrintzis VA, Petalas C, Ouzounis K (2010) Soil salinization in the agricultural lands of Rhodope district, northeastern Greece. Environ Monit Assess 166(1/4):79–94. https://doi.org/10.1007/s10661-009-0986-6

    Article  Google Scholar 

  • Rao NS (2002) Geochemistry of groundwater in parts of Guntur district, Andhra Pradesh, India. Environ Geol 41(5):552–562. https://doi.org/10.1007/s002540100431

    Article  Google Scholar 

  • Rao U, Hollocher K, Sherman J, Eisele I, Frunzi MN, Swatkoski SJ, Hammons AL (2005) The use of 36Cl and chloride/bromide ratios in discerning salinity sources and fluid mixing patterns: a case study at Saratoga Springs. Chem Geol 222(1/2):94–111. https://doi.org/10.1016/j.chemgeo.2005.06.011

    Article  Google Scholar 

  • Rosenthal E, Zilberbrand M, Livshitz Y (2007) The hydrochemical evolution of brackish groundwater in central and northern Sinai (Egypt) and in the western Negev (Israel). J Hydrol 337(3):294–314. https://doi.org/10.1016/j.jhydrol.2007.01.042

    Article  Google Scholar 

  • Sanchez-Martos F, Jiménez-Espinosa R, Pulido A (2001) Mapping groundwater quality varibels using PCA and geostatistics: a case study of Bajo Andarax, Southeastern Spain. Hydrol Sci J 46(2):227–242. https://doi.org/10.1080/02626660109492818

    Article  Google Scholar 

  • Shirnezhad Z, Azma A, Foong LK, Jahangir A, Rastegarnia A (2020) Assessment of water resources quality of a karstic aquifer in the Southwest of Iran. Bulletin of Engineering Geology and the Environment: 1/2021

  • Souid F, Agoubi B, Telahigue F, Chahlaoui A, Kharroubi A (2018) Groundwater salinization and seawater intrusion tracing based on Lithium concentration in the shallow aquifer of Jerba Island, southeastern Tunisia. J Afr Earth Sci 138:233–246. https://doi.org/10.1016/j.jafrearsci.2017.11.013

    Article  Google Scholar 

  • Telahigue F, Agoubi B, Souid F, Kharroubi A (2018) Groundwater chemistry and radon-222 distribution in Jerba Island, Tunisia. J Environ Radioact 182:74–84. https://doi.org/10.1016/j.jenvrad.2017.11.025

    Article  Google Scholar 

  • Telahigue F, Mejri H, Mansouri B, Souid F, Agoubi B, Chahlaoui A, Kharroubi A (2020) Assessing seawater intrusion in arid and semi-arid Mediterranean coastal aquifers using geochemical approaches. J Phys Chem Earth 115:102811. https://doi.org/10.1016/j.pce.2019.102811

    Article  Google Scholar 

  • Trabelsi R, Zaïri M, Smida H, Ben Dhia H (2005) Salinisation des nappes côtières : cas de la nappe nord du Sahel de Sfax, Tunisie. Compt Rendus Geosci 337:515–524. https://doi.org/10.1016/j.crte.2005.01.010

    Article  Google Scholar 

  • Wackernagel H (2003) Multivariate geostatistics: an introduction with applications. Springer-Verlag Berlin Heidelberg GmbH, p 388

  • Walter J, Chesnaux R, Cloutier V, Gaboury D (2017) The influence of water/rock − water/clay interactions and mixing in the salinization processes of groundwater. J Hydrol Reg Stud 13:168–188. https://doi.org/10.1016/j.ejrh.2017.07.004

    Article  Google Scholar 

  • Yan SF, Yu S, Wu Y, Pan DF, Dong JG (2018) Understanding groundwater table using a statistical model. Water Sci Eng 11(1):1–7. https://doi.org/10.1016/j.wse.2018.03.003

    Article  Google Scholar 

  • Zakhem BA, Al-Charideh A, Kattaa B (2017) Using principal component analysis in the investigation of groundwater hydrochemistry of Upper Jezireh Basin, Syria. Hydrol Sci J 62(14):2266–2279. https://doi.org/10.1080/02626667.2017.1364845

    Article  Google Scholar 

Download references

Acknowledgements

The authors gratefully thank the contributions of the technical staff at the Laboratory Applied Hydrosciences Research Unit of Higher Institute of Water Sciences and Techniques of Gabès (Tunisia) for their help during laboratory analysis.

Funding

This work is co-funded by the national Funds provided by FCT - Fundação para a Ciência e a Tecnologia, I.P., with the projects UIDB/04683/2020 and UIDP/04683/2020.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Oussama Dhaoui.

Ethics declarations

Conflict of interest

The authors declare that they have no competing interests.

Additional information

Responsible Editor: Broder J. Merkel

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Dhaoui, O., Antunes, I., Agoubi, B. et al. Geochemical processes of groundwater salinization in an arid area, southeastern Tunisia. Arab J Geosci 14, 1721 (2021). https://doi.org/10.1007/s12517-021-08155-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s12517-021-08155-3

Keyword

Navigation