Abstract
This paper presents petrographic details and geochemical data on gemstone-producing pegmatites and the rocks enclosing them, Sumayar pluton exposed in the vicinity, and chemical composition of a variety of gemstones to elucidate the nature and source of gemstone-forming fluids in the Chumar Bakhoor area of Gilgit-Baltistan, northern Pakistan. The pegmatites occur as patches, pods, lenses, and dykes in calc-silicate rocks and amphibolite belonging to the southern Karakoram Metamorphic Complex (KMC) as well as in the intrusive Sumayar pluton. A close spatial association suggests the possibility of a strong genetic relationship between the Sumayar pluton and the gemstone-hosting granitic pegmatites. Hence, the latter most likely represent pegmatitic phase of a granitic system that in its orthomagmatic stage produced the Sumayar pluton. The pegmatites thus solidified from pockets of volatile-rich melt residues after the granitic magma that solidified as Sumayar pluton. The mineralogical make-up of the pegmatite, the gemstone assemblage, and chemical characteristics of the individual gemstones suggest that the pegmatite-forming melt was highly enriched in Be, B, F, Cl, and H2O, and depleted in Li, REE, and Ta relative to its parent granitic magma. Owing to a strong likelihood of generation by localized partial melting of metapelitic rocks at shallow depth in a post-collisional tectonic setting, the magma parental to the Sumayar pluton had the potential to evolve through the process of differentiation into residues containing gemstone-forming fluids. The calc-silicate rocks, which host the gemstone-producing pegmatites, were formed by isochemical metamorphism of calcareous mudstones rather than metasomatism of carbonate rocks, although they show some mineralogical similarities with skarn-type assemblages. However, the calc-silicate rocks neither played any role in the formation of gemstones nor caused any change in the gemstone chemistry.
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References
Agheem MH, Shah MT, Khan T, Murata M, Arif M, Dars H (2014) Shigar valley gemstones, their chemical composition and origin, Skardu, Gilgit-Baltistan. Pakistan Arab J Geosci 7(9):3801–3814. https://doi.org/10.1007/s12517-013-1045-8
Barton MD, Ilchik RP, Marikos MA (1991) Metasomatism. Rev Mineral 26:321–350
Benard F, Moutou P, Pichavant M (1985) Phase relations of tourmaline leucogranites and the significance of tourmaline in silicic magmas. The Journal of Geology 93(3):271–291. https://doi.org/10.1086/628952
Bill H, Sierro J, Lacroix R (1967) Origin of coloration in some fluorites. American Mineralogist: Journal of Earth and Planetary Materials 52(7-8):1003–1008
Černý P (1991) Rare-element granitic pegmatites. Part II: regional to global environments and petrogenesis. Geosci Can 18(2):68–81
Černý P, Ercit TS (2005) The classification of granitic pegmatites revisited. Can Mineral 43(6):2005–2026. https://doi.org/10.2113/gscanmin.43.6.2005
Crawford M, Searle M (1993) Collision-related granitoid magmatism and crustal structure of the Hunza Karakoram, North Pakistan. Geol Soc Lond Spec Publ 74(1):53–68. https://doi.org/10.1144/GSL.SP.1993.074.01.05
Crawford MB, Windley BF (1990) Leucogranites of the Himalaya/Karakoram: implications for magmatic evolution within collisional belts and the study of collision-related leucogranite petrogenesis. J Volcanol Geotherm Res 44(1-2):1–19. https://doi.org/10.1016/0377-0273(90)90008-4
Deer W, Zussman J, Howie R.(1966) An introduction to the rock-forming minerals: Longman: London
Dostal J (2016) Rare metal deposits associated with alkaline/peralkaline igneous rocks. Rev Econ Geol 18:33–54. https://doi.org/10.5382/Rev.18.02
Fraser JE, Searle MP, Parrish RR, Noble SR (2001) Chronology of deformation, metamorphism, and magmatism in the southern Karakoram Mountains. J Geological Society of America Bulletin 113(11):1443–1455. https://doi.org/10.1130/0016-7606(2001)113
Fuertes-Fuente M, Martin-Izard A, Boiron MC, Viñuela JM (2000) P-T path and fluid evolution in the Franqueira granitic pegmatite, central Galicia, northwestern Spain. Can Mineral 38(5):1163–1175. https://doi.org/10.2113/gscanmin.38.5.1163
Gaetani M, Casnedi R, Fois E, Garzanti E, Jadoul F, Nicora A, Tintori A (1986) Stratigraphy of the Tethys Himalaya in Zanskar, Ladakh. Riv Ital Paleontol Stratigr 91:443–478
Giuliani G, France-Lanord C, Zimmermann J, Cheilletz A, Arboleda C, Charoy B, Coget P, Fontan F, Giard D (1997) Fluid composition, δD of channel H2O, and δ18O of lattice oxygen in beryls: genetic implications for Brazilian, Colombian, and Afghanistani emerald deposits. Int Geol Rev 39(5):400–424. https://doi.org/10.1080/00206819709465280
Grande L, Augustyn, A (2009) Gems and gemstones: timeless natural beauty of the mineral world: University of Chicago Press
Hussain A, Zhao KD, Arif M, Palmer MR, Chen W, Zhang Q, Li Q, Jiang SY, Girei MB (2020) Geochronology, mineral chemistry and genesis of REE mineralization in alkaline rocks from the Kohistan Island Arc, Pakistan. Ore Geol Rev 103749. https://doi.org/10.1016/j.oregerev.2020.103749
Jahns RH, Burnham CW (1969) Experimental studies of pegmatite genesis; l, A model for the derivation and crystallization of granitic pegmatites. Econ Geol 64(8):843–864. https://doi.org/10.2113/gsecongeo.64.8.843
Kempe U, Götze J, Dandar S, Habermann D (1999) Magmatic and metasomatic processes during formation of the Nb-Zr-REE deposits Khaldzan Buregte and Tsakhir (Mongolian Altai); indications from a combined CL-SEM study. J Mineralogical Magazine 63(2):165–177
LaMaskin TA, Dorsey RJ, Vervoort JD (2008) Tectonic controls on mudrock geochemisry, Mesozoic rocks of eastern Oregon and western Idaho, USA: implications for cordilleran tectonics. J Sediment Res 78(12):765–783. https://doi.org/10.2110/jsr.2008.087
Laurs BM, Dilles JH, Snee LW (1996) Emerald mineralization and metasomatism of amphibolite, Khaltaro granitic pegmatite-hydrothermal vein system, Haramosh Mountains, northern Pakistan. Can Mineral 34(6):1253–1286
Linnen RL, Van Lichtervelde M, Černý P (2012) Granitic pegmatites as sources of strategic metals. Elements 8(4):275–280. https://doi.org/10.2113/gselements.8.4.275
London D (1987) Internal differentiation of rare-element pegmatites: effects of boron, phosphorus, and fluorine. Geochim Cosmochim Acta 51(3):403–420. https://doi.org/10.1016/0016-7037(87)90058-5
London D (1990) Internal differentiation of rare-element pegmatites: a synthesis of recent research. Geol Soc Am Spec Pap 246:35–50
London D (2005) Granitic pegmatites: an assessment of current concepts and directions for the future. Lithos 80(1-4):281–303. https://doi.org/10.1016/j.lithos.2004.02.009
London D, Evensen JM (2002) Beryllium in silicic magmas and the origin of beryl-bearing pegmatites. Rev Mineral Geochem 50(1):445–486. https://doi.org/10.2138/rmg.2002.50.11
Lum JE, Viljoen F, Cairncross B, Frei D (2016) Mineralogical and geochemical characteristics of Beryl (aquamarine) from the Erongo Volcanic Complex. Namibia J Afr Earth Sci 124:104–125. https://doi.org/10.1016/j.jafrearsci.2016.09.006
Sun SS, McDonough WF (1989) Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes. Geol Soc Lond Spec Publ 42(1):313–345
Merz JL, Pershan P (1967) Charge conversion of irradiated rare-earth ions in calcium fluoride. Phys Rev 162(2):217. https://doi.org/10.1103/PhysRev.162.217
Naldrett D, Lachaine A, Naldrett S (1987) Rare-earth elements, thermal history, and the colour of natural fluorites. Can J Earth Sci 24(10):2082–2088. https://doi.org/10.1139/e87-197
Norton JJ, Redden JA (1990) Relations of zoned pegmatites to other pegmatites, granite, and metamorphic rocks in the southern Black Hills. South Dakota Am Mineral 75(5-6):631–655
Parat F, Bucher K (2009) Topaz-fluorite granites from the Black Forest, Germany: evolution of F-rich felsic magmas. Geochimica et Cosmochimica Acta Supplement 73:A992
Rehman HU, Seno T, Yamamoto H, Khan T (2011) Timing of collision of the Kohistan–Ladakh Arc with India and Asia: debate. Island Arc 20(3):308–328. https://doi.org/10.1111/j.1440-1738.2011.00774.x
Rosenberg PE (1972) Paragenesis of topaz-bearing portion of Brown Derby no.1 pegmatite, Gunnison Country Colorado. Am Mineral 57(3-4):571
Rudnick R, Gao S, Holland H, Turekian K (2003) Composition of the continental crust. In The Crust, vol. 3 (ed. R. L. Rudnick). Elsevier, pp. 1-64
Schaltegger U, Zeilinger G, Frank M, Burg JP (2002) Multiple mantle sources during island arc magmatism: U–Pb and Hf isotopic evidence from the Kohistan arc complex, Pakistan. Terra Nova 14(6):461–468. https://doi.org/10.1046/j.1365-3121.2002.00432.x
Searle MP (1991) Geology and tectonics of Karakoram Mountain: John Wiley &Sons: New Jersey, USA
Searle M, Khan, MA (1997) Geological map of north Pakistan: and adjacent areas of Northern Ladakh and Western Tibet:(Western Himalaya, Salt Ranges, Kohistan, Karakoram, Hindu Kush): British Geological Service (BGS)
Searle M, Tirrul R (1991) Structural and thermal evolution of the Karakoram crust. Geol Soc Lond Spec Publ 148(1):65–82. https://doi.org/10.1144/gsjgs.148.1.0065
Siegel K, Vasyukova OV, Williams-Jones AE (2018) Magmatic evolution and controls on rare metal-enrichment of the Strange Lake A-type peralkaline granitic pluton, Québec-Labrador. Lithos 308:34–52. https://doi.org/10.1016/j.lithos.2018.03.003
Simmons WB, Pezzotta F, Shigley JE, Beurlen H (2012) Granitic pegmatites as sources of colored gemstones. Elements 8(4):281–287. https://doi.org/10.2113/gselements.8.4.281
Sylvester PJ (1998) Post-collisional strongly peraluminous granites. Lithos 45(1-4):29–44. https://doi.org/10.1016/S0024-4937(98)00024-3
Tracy RJ (1991) Phase equilibria and thermobarometry of calcareous, ultramafic and mafic rocks, and iron formations. Rev Mineral 26:207–289
Voillot P (1995) Chumar Bakar. carnet de route d'un chercheur de pierres precieuses. Criterion, France
Webster JD, Rebbert CR (1998) Experimental investigation of H 2 O and Cl− solubilities in F-enriched silicate liquids; implications for volatile saturation of topaz rhyolite magmas. Contrib Mineral Petrol 132(2):198–207. https://doi.org/10.1007/s004100050416
Winter JD (2010) An introduction to igneous and metamorphic petrology. Prentice Hall, New York
Acknowledgements
We are thankful to Dr. Peter Gadas of the Department of Geological Sciences, Masaryk University Brno and Czech Geological Survey, Czech Republic, for his kind favor to carry out EMPA analyses.
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Highlights
•Chumar Bakhoor granitic pegmatites are highly productive in gemstones.
•These pegmatites have NYF-type pegmatites affinity.
•No role of host rocks in gemstone mineralization.
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Hussain, A., Shah, M.T., Arif, M. et al. Chemical composition of gemstones and characterization of their host pegmatites and country rocks from Chumar Bakhoor, Gilgit-Baltistan, Pakistan: implications for the source of gem-forming fluids. Arab J Geosci 14, 1303 (2021). https://doi.org/10.1007/s12517-021-07682-3
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DOI: https://doi.org/10.1007/s12517-021-07682-3