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Synergistic effect of homojunction and Ohmic junctions in CdS boosting spatial charge separation for U(VI) photoreduction

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Abstract

Photo-excited holes usually migrate to the surface of the catalyst and rapidly recombine with electrons, reducing the photocatalytic reduction efficiency of uranium(VI) (U(VI)) in radioactive wastewater. Consequently, we employed a straightforward synthesis technique to meticulously shape and manipulate the morphology of CdS to precisely construct CdS-Ni dandelion-like composites with different aspect ratios. Briefly, the introduction of crystal facet homojunction with Ohmic contacts in this unique morphology siqnificantly improves the photocatalytic efficiency. Temperature-dependent photoluminescence spectroscopy (TD-PL) verifies that the composite material positively effects on the dissociation of excitons. Within 30 min, CdS(002)/(102)/Ni-4 removed 98% of the uranium content in solution and showed a rather high apparent rate constant (0.114 min−1), which was 4.8 times higher than that of CdS nanospheres (NSs) (0.024 min−1) and 3.7 times higher than that of CdS nanorods (NRs) (0.031 min−1). This is much higher the most reported photocatalysts for U(VI) reduction. Even after 5 consecutive cycles, the photocatalytic efficiency only decreased by 7%. This offers a fresh perspective on constructing a new perspective for building a green, efficient, and multi mechanism collaborative catalytic system to remediate environmental pollution.

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Nos. 22066003, U2167223, 22206024, 22076022, and 22006014), and the Natural Science Foundation of Jiangxi province (Nos. 20224ACB203005 and 20232BAB213034). This work was carried out at Shanxi Supercomputing Center of China, and the calculations were performed on TianHe-2.

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  1. Haonan Pei and Zhimin Dong contributed equally to this work.

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  1. State Key Laboratory of Nuclear Resources and Environment, East China University of Technology, Nanchang, 330013, China

    Haonan Pei, Zhimin Dong, Zifan Li, Jian Huang, Yuanping Jiang, Zuojia Li, Lin Xu, Xiaohong Cao, Yunhai Liu, Zhibin Zhang & Guoping Yang

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  1. Haonan Pei
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  2. Zhimin Dong
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Correspondence to Yunhai Liu, Zhibin Zhang or Guoping Yang.

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Synergistic effect of homojunction and Ohmic junctions in CdS boosting spatial charge separation for U(VI) photoreduction

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Pei, H., Dong, Z., Li, Z. et al. Synergistic effect of homojunction and Ohmic junctions in CdS boosting spatial charge separation for U(VI) photoreduction. Nano Res. (2024). https://doi.org/10.1007/s12274-024-6637-y

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