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Interface-induced polymerization strategy for constructing titanium dioxide embedded carbon porous framework with enhanced chemical immobilization towards lithium polysulfides

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Abstract

The shuttle effect induced by soluble lithium polysulfides (LiPSs) is known as one of the crucial issues that limit the practical applications of lithium-sulfur (Li-S) batteries. Herein, a titanium dioxide nanoparticle embedded in nitrogen-doped porous carbon nanofiber (TiO2@NCNF) composite is constructed via an interface-induced polymerization strategy to serve as an ideal sulfur host. Under the protection of the nanofiber walls, the uniformly dispersed TiO2 nanocrystalline can act as capturing centers to constantly immobilize LiPSs towards durable sulfur chemistry. Besides, the mesoporous microstructure in the fibrous framework endows the TiO2@NCNF host with strong physical reservation for sulfur and LiPSs, sufficient pathways for electron/ion transfer, and excellent endurance for volume change. As expected, the sulfur-loaded TiO2@NCNF composite electrode presents a fabulous rate performance and long cycle lifespan (capacity fading rate of 0.062% per cycle over 500 cycles) at 2.0 C. Furthermore, the assembled Li-S batteries harvest superb areal capacity and cycling stability even under high sulfur loading and lean electrolyte conditions.

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Acknowledgements

The authors are grateful for the financial support from the National Natural Science Foundation of China (No. 22075042), Shanghai Rising-Star Program (No. 22QA1400300), the Natural Science Foundation of Shanghai (No. 20ZR1401400), the Shanghai Scientific and Technological Innovation Project (No. 22520710100), the Innovation Program of Shanghai Municipal Education Commission (No. 2021-01-07-00-03-E00108), the Fundamental Research Funds for the Central Universities, and the Donghua University (DHU) Distinguished Young Professor Program (No. LZB2021002).

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  1. Yue Ouyang Xiaoxiao Li, and Jiexin Zhu contributed equally to this work.

Authors and Affiliations

  1. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, 2999 North Renmin Road, Shanghai, 201620, China

    Yue Ouyang, Xiaoxiao Li, Wei Zong, Shengyuan Yang, Yue-E. Miao & Tianxi Liu

  2. The Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, 214122, China

    Tianxi Liu

  3. Advanced Fibrous Materials LAB, Institute for Advanced Textile Materials and Technologies (ATMT), School of Advanced Materials and Processes, Amirkabir University of Technology, Tehran, 15914, Iran

    Roohollah Bagherzadeh

  4. Christopher Ingold Laboratory, Department of Chemistry, University College London, 20 Gordon Street, London, WC1H 0AJ, UK

    Jiexin Zhu, Wei Zong, Yuhang Dai, Xuan Gao & Wei Zhang

  5. Department of Chemistry, KU Leuven, Celestijnenlaan 200F, Leuven, 3001, Belgium

    Feili Lai

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  1. Yue Ouyang
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Correspondence to Wei Zong or Yue-E. Miao.

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Interface-induced polymerization strategy for constructing titanium dioxide embedded carbon porous framework with enhanced chemical immobilization towards lithium polysulfides

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Ouyang, Y., Li, X., Zhu, J. et al. Interface-induced polymerization strategy for constructing titanium dioxide embedded carbon porous framework with enhanced chemical immobilization towards lithium polysulfides. Nano Res. 17, 1473–1481 (2024). https://doi.org/10.1007/s12274-023-5894-5

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