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Directional design and synthesis of high-yield hollow Fe-MFI zeolite encapsulating ultra-small Fe2O3 nanoparticles by using mother liquid

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Abstract

How to directionally design the hollow zeolite via a green route is of great significance. Here, we successfully synthesized the hollow Fe-silicate-1 encapsulated ultra-small Fe2O3 nanoparticles (2.5 nm) with higher yield (85.2%) by mother liquid than traditional dissolution-recrystallization for the first time, which was achieved by precisely regulating the number and distribution of defects in zeolite and cleverly utilizing the TPAOH and nuclei in mother liquor. The effects of synthetic temperature, synthetic period and addition amount of parent zeolite on the formation of hollow zeolite have been investigated and the effect of synthetic conditions on the defects in parent zeolite has been also firstly quantified. The corresponding formation mechanism has been proposed. The abundant inner defects provided by the zeolite synthesized at 130 °C for 1 day and large amount of TPAOH remaining in mother liquid are conducive to the formation of hollow zeolite. Meanwhile, both parent zeolite and nuclei (4-, 5-member rings and structure units) in mother liquid obtained at 130 °C play the crucial roles in enhancing the zeolite yield. Notably, Fe2O3 nanoparticles could decompose into small fragments by the interaction with nuclei in mother liquid. Partial ultra-small Fe2O3 nanoparticles would be encapsulated in cavity and the rest could be inserted in the zeolite framework, which is significantly different from the conventional dissolution-recrystallization mechanism. The obtained encapsulated catalyst shows the superior catalytic performance and stability in phenol and tetracycline degradation reactions.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 21978198 and 22002052).

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Authors and Affiliations

  1. School of Chemical Engineering and Technology, Tianjin University, Tianjin, 300350, China

    Yi Zhai, Fumin Wang, Xubin Zhang, Yuzhou Wu, Tao Jiang, Qing Zhang, Mengyue Li, Mengyao Li & Yongkui Liu

  2. School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang, 212003, China

    Guojun Lv

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  1. Yi Zhai
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  2. Fumin Wang
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  3. Xubin Zhang
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Directional design and synthesis of high-yield hollow Fe-MFI zeolite encapsulating ultra-small Fe2O3 nanoparticles by using mother liquid

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Zhai, Y., Wang, F., Zhang, X. et al. Directional design and synthesis of high-yield hollow Fe-MFI zeolite encapsulating ultra-small Fe2O3 nanoparticles by using mother liquid. Nano Res. 14, 4304–4313 (2021). https://doi.org/10.1007/s12274-021-3747-7

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