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Sustainable Synthesis of Core-shell Structured ZSM-5@Silicalite-1 Zeolite

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Chemical Research in Chinese Universities Aims and scope

Abstract

Core-shell structured ZSM-5@Silicalite-1 zeolite could effectively hinder the deactivation of catalyst surface. Currently, organic structure directing agents(OSDAs) are necessary in the conventional route for the synthesis of this core-shell zeolite under hydrothermal conditions, which is costly and environmental-unfriendly. In this research, a synthesis of the core-shell structured ZSM-5@Silicalite-1 zeolite with a strategy of alcohol filling and zeolite seeding without any organic template or solvent is exhibited. The obtained products are well characterized by X-ray powder diffractometer(XRD), scanning electron microscopy(SEM), transmission electron microscopy(TEM), N2 sorption isotherms, solid magic angle spinning(MAS) NMR, temperature-programmed-desorption of ammonia(NH3-TPD), and X-ray photoelectron spectroscopy(XPS) techniques, in order to confirm the core-shell structure. More importantly, the core-shell structured ZSM-5@Silicalite-1 zeolite exhibits a long lifetime and a high p-xylene selectivity in the alkylation of toluene with methanol, compared with the conventional ZSM-5 catalyst.

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Acknowledgements

This work was supported by the National Key Research and Development Program of China(No.2017YFB0702803), the Fundamental Research Funds for the Central Universities, China(No.2021QNA4028), and the National Natural Science Foundation of China(Nos.21802121, 2217020097, 21720102001).

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Authors and Affiliations

  1. Key Laboratory of Applied Chemistry of Zhejiang Province, Zhejiang University, Hangzhou, 310028, P. R. China

    Huimin Luan, Yeqing Wang & Xiangju Meng

  2. College of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027, P. R. China

    Qinming Wu & Feng-Shou Xiao

  3. Beijing Advanced Innovation Center for Soft Matter, Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029, P. R. China

    Jian Zhang

Authors
  1. Huimin Luan
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  2. Qinming Wu
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  3. Jian Zhang
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  4. Yeqing Wang
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  5. Xiangju Meng
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  6. Feng-Shou Xiao
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Correspondence to Qinming Wu or Feng-Shou Xiao.

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Luan, H., Wu, Q., Zhang, J. et al. Sustainable Synthesis of Core-shell Structured ZSM-5@Silicalite-1 Zeolite. Chem. Res. Chin. Univ. 38, 136–140 (2022). https://doi.org/10.1007/s40242-021-1288-y

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  • DOI: https://doi.org/10.1007/s40242-021-1288-y

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