Nano Research

, 2:783 | Cite as

The dynamics of the nucleation, growth and termination of single-walled carbon nanotubes from in situ Raman spectroscopy during chemical vapor deposition

  • Paul Finnie
  • Andrew Li-Pook-Than
  • Jacques Lefebvre
Open Access
Research Article


The dynamics of the chemical vapor deposition (CVD) of single-walled carbon nanotubes (SWNTs) is extracted experimentally using in situ Raman spectroscopy. Nanotubes are grown using a thin film cobalt catalyst and an ethanol precursor in a miniature hot walled reactor with optical access. Raman spectra at room temperature and at the growth temperature are compared for two growth temperatures. The evolution of the G-band, D-band, and radial breathing mode (RBM) is tracked at the growth temperature with time resolution of a few seconds. There are three identifiable phases in the evolution of the Raman signal intensity: an initial exponential increasing phase, a linear growth phase, and a saturation phase. In situ optical spectroscopy thus enables the study of nucleation, steady growth, and deactivation processes to be investigated separately in real time. The evolution curves for all bands (G, D, and RBM), when scaled, collapse onto the same curve, to within experimental uncertainty.


Single-walled carbon nanotube chemical vapor deposition Raman spectroscopy nucleation termination 


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Copyright information

© Tsinghua University Press and Springer Berlin Heidelberg 2009

Authors and Affiliations

  • Paul Finnie
    • 1
    • 2
  • Andrew Li-Pook-Than
    • 1
    • 2
  • Jacques Lefebvre
    • 1
  1. 1.Institute for Microstructural SciencesNational Research Council CanadaOttawaCanada
  2. 2.Department of PhysicsUniversity of OttawaOttawaCanada

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