Skip to main content
SpringerLink
Log in

Mechanical properties, hydrophobic properties and thermal stability of the biodegradable poly(butylene adipate-co-terephthalate)/maleated thermoplastic starch blown films

  • Published:
Fibers and Polymers Aims and scope Submit manuscript

Abstract

Poly(butylene adipate-co-terephthalate) (PBAT) and thermoplastic starch (TPS) were blended by using maleic anhydride (MA) as a compatibilizer. Preferentially, TPS could be reacted with MA to obtain maleated thermoplastic starch (MTPS). Then PBAT/MTPS blends were blown films using blown technique. From dynamic mechanical analysis, the shifting of the glass transition temperatures toward each other suggested that PBAT was partially miscible with MTPS. From wide angle X-ray diffraction analysis, the degree of crystallinity of PBAT/MTPS films was decreased with increasing MTPS content. From rheological measurements, the melt elasticity and viscosity of the PBAT/MTPS blends increased. It was benefit to extrude blend and blow film. The contact angle values of bipolar liquid water were range from 100.2 to 77.7 ° decreased with increasing MTPS content from 0 to 50 %. The PBAT/MTPS films could satisfy the requirement for applying in our life.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. X. F. Ma, J. J. Rui, P. R. Chang, and J. G. Yu, Biomacromolecules, 9, 3314 (2008).

    Article  CAS  Google Scholar 

  2. I. A. Wolff, H. A. Davis, J. E. Cluskey, L. J. Gusdruji, and C. E. Rist, Ind. Eng. Chem., 43, 916 (1951).

    Google Scholar 

  3. R. Rundle, E. L. Daasch, and D. French, J. Am. Chem. Soc., 66, 130 (1944).

    Article  CAS  Google Scholar 

  4. M. M. Nobrega, J. B. Olivato, C. M. O. Müller, and F. Yamashita, Polimeros, 22, 475 (2012).

    CAS  Google Scholar 

  5. A. S. Jacqueline, V. D. Alives, and R. Narayan, J. Appl. Polym. Sci., 126, 135 (2012).

    Article  Google Scholar 

  6. A. Taguet, M. A. Huneault, and B. D. Favis, Polymer, 50, 5733 (2009).

    Article  CAS  Google Scholar 

  7. F. C. Soares, F. Yamashita, C. M. O. Müller, and A. T. N. Pires, Polym. Test., 33, 34 (2014).

    Article  CAS  Google Scholar 

  8. Z. Q. Liu, M. Jiang, X. Bai, X. G. Dong, J. Tong, and J. Zhou, J. Appl. Polym. Sci., 124, 3774 (2012).

    Article  CAS  Google Scholar 

  9. J. A. Ratta, P. J. Stenhouse, M. Auerbach, J. Mitchell, and R. Farrell, Polymer, 40, 6777 (1999).

    Article  Google Scholar 

  10. M. A. Shirai, J. B. Olivato, and P. S. Garcia, Mater. Sci. Eng. C., 33, 4112 (2013).

    Article  CAS  Google Scholar 

  11. M. Smita and K. N. Sanjay, Polym. Compos., 31, 1195 (2010).

    Google Scholar 

  12. E. Hablot, S. Dewasthale, Y. J. Zhao, Y. Z. Guan, X. K. Shi, D. Graiver, and R. Narayan, Eur. Polym. J., 49, 873 (2013).

    Article  CAS  Google Scholar 

  13. J. B. Olivato, M. V. E. Grossmann, A. P. Bilck, and F. Yamashita, Carbohydr. Polym., 90, 159 (2012).

    Article  CAS  Google Scholar 

  14. J. M. Raquez, Y. Nabar, M. Srinivasan, B. Y. Shin, R. Narayan, and P. Dubois, Polym. Eng. Sci., 74, 159 (2008).

    CAS  Google Scholar 

  15. J. H. Yin and Z. S. Mo, “Modern Polymer Physics”, p.44, Science Press, Beijing, 2001.

    Google Scholar 

  16. Q. X. Zhang, Z. S. Mo, H. F. Zhang, and S. Y. Liu, Macromolecules, 33, 5999 (2000).

    Article  CAS  Google Scholar 

  17. C. H. Macgillavry and G. D. Rieck, “International tables for X-ray Crystallography”, p.71, Kynoch, Birmingham, 1974.

    Google Scholar 

  18. M. Yokouchi, Y. Sakakibara, Y. Chatani, H. Tadokoro, T. Tanaka, and K. Yoda, Macromolecules, 9, 266 (1976).

    Article  CAS  Google Scholar 

  19. I. H. Hall and M. G. Pass, Polymer, 17, 807 (1976).

    Article  CAS  Google Scholar 

  20. B. Stambaugh, J. L. Koenig, and J. B. Lando, J. Polym. Sci. Pt. C-Polym. Lett., 15, 299 (1977).

    Article  CAS  Google Scholar 

  21. I. J. Desborough and I. H. Hall, Polymer, 18, 825 (1977).

    Article  CAS  Google Scholar 

  22. M. G. Bereton, G. R. Davies, R. Jakeways, T. Smith, and I. M. Ward, Polymer, 19, 17 (1978).

    Article  Google Scholar 

  23. B. Stambaugh, J. L. Koenig, and J. B. Lando, J. Polym. Sci. Pt. B-Polym. Phys., 17, 1053 (1979).

    Article  CAS  Google Scholar 

  24. H. L. Zhang, S. L. Sun, M. Q. Ren, Q. Y. Chen, J. B. Song, H. F. Zhang, and Z. S. Mo, J. Appl. Polym. Sci., 109, 4082 (2008).

    Article  CAS  Google Scholar 

  25. Q. X. Zhang, Z. Z. Yu, X. L. Xie, K. Naito, and Y. Kagawa, Polymer, 48, 7193 (2007).

    Article  CAS  Google Scholar 

  26. Y. J. Bian, L. J. Han, C. Y. Han, H. L. Zhang, J. J. Bian, and L. S. Dong, CrystEngComm., 16, 2702 (2014).

    Article  CAS  Google Scholar 

  27. D. F. Wu, Y. S. Zhang, M. Zhang, and W. Yu, Biomacromolecules, 10, 417 (2009).

    Article  CAS  Google Scholar 

  28. R. P. H. Brandelero, F. Yamashita, and M. V. E. Grossmann, Carbohydr. Polym., 82, 1102 (2010).

    Article  CAS  Google Scholar 

  29. S. Wu, “Polymer Interface and Adhesion”, p.11, Marcel Dekker, New York, 1982.

    Google Scholar 

  30. F. M. Fowkes, J. Phys. Chem., 66, 382 (1962).

    Article  CAS  Google Scholar 

  31. D. K. Owens and R. C. Wendt, J. Appl. Polym. Sci., 13, 1741 (1969).

    Article  CAS  Google Scholar 

  32. C. J. Vanoss, R. J. Good, and M. K. Chaudhury, J. Protein. Chem., 2, 179 (1988).

    Article  Google Scholar 

  33. B. Janczuk, T. Bialopiotrowicz, and A. J. Zdziennicka, J. Colloid. Interface Sci., 211, 96 (1999).

    Article  Google Scholar 

  34. Y. C. Zhang, X. Yuan, M. R. Thompson, and Q. Liu, J. Appl. Polym. Sci., 125, 3250 (2012).

    Article  CAS  Google Scholar 

  35. V. P. Cyras, L. B. Manfredi, M. T. Ton-That, and A. Vázquez, Carbohydr. Polym., 73, 55 (2008).

    Article  CAS  Google Scholar 

  36. M. R. Kamal, J. U. Calderon, and R. B. Lennox, J. Adhes. Sci. Technol., 23, 663 (2009).

    Article  Google Scholar 

  37. D. Pasquini, M. N. Belgacem, A. Gandini, and A. A. S. Curvelo, J. Colloid. Interface Sci., 295, 79 (2006).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Key Laboratory of Polymer Ecomaterials, Chinese Academy of Sciences, Changchun Institute of Applied Chemistry, Changchun, 130022, P. R. China

    Hongwei Pan, Dandan Ju, Yan Zhao, Huili Yang, Huiliang Zhang & Lisong Dong

  2. Changchun University of Technology, Changchun, 130022, P. R. China

    Hongwei Pan, Yan Zhao & Zhe Wang

Authors
  1. Hongwei Pan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Dandan Ju
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yan Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Zhe Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Huili Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Huiliang Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Lisong Dong
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Huiliang Zhang.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Pan, H., Ju, D., Zhao, Y. et al. Mechanical properties, hydrophobic properties and thermal stability of the biodegradable poly(butylene adipate-co-terephthalate)/maleated thermoplastic starch blown films. Fibers Polym 17, 1540–1549 (2016). https://doi.org/10.1007/s12221-016-6379-x

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12221-016-6379-x

Keywords

Search

Navigation