Abstract
The aim of the present study was to investigate the UV absorption properties of PVA-g-PAN/ZnO nanocomposite films prepared by free radical graft copolymerization of acrylonitrile on to PVA and subsequent in situ precipitation of ZnO nanoparticles into the polymer matrix. The nanocomposites were characterized by various analytical methods such as Fourier transform infrared spectroscopy (FTIR), Raman spectroscopy, Scanning electron microscopy (SEM) and Atomic force microscopy (AFM) etc. The size of the crystallites and extent of crystallinity were ascertained by X-ray diffraction (XRD) analysis. The SEM with Energy Dispersive X-ray analysis (EDX) showed that the ZnO nanoparticles were uniformly dispersed within the host copolymer matrix. The transmission electron microscopy (TEM) results clearly indicated that the size of zinc oxide nanoparticles varied in the range 10–30 nm. The surface morphology and topography of the PVA-g-PAN/ZnO nanocomposite films were investigated using atomic force microscopy (AFM). The UV-absorption properties of so prepared films were also studied using UV-visible absorption spectroscopy. The results showed that the films were capable of absorbing more than 95 % of incident UV radiations. The antibacterial activities of so prepared nanocomposites were determined against the Gram-negative bacterium Escherichia coli and Pseudomonas aerugenosa, and Gram-positive Micrococcus luteus and Staphylococcus aureus by the disc diffusion test method which showed that the antibacterial activity increased with increasing content of ZnO in the film. The prepared nanocomposites were also studied for swelling behavior.
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L. L. Becreft and C. K. Ober, J. Chem. Mat., 9, 1302 (1997).
F. Hussain and M. Hojjati, J. Compos. Mater., 40, 1511 (2006).
T. Maier and H. C. Korting, Skin Pharmacol. Physiol., 18, 253 (2005).
S. K. Mallik and T. Arora, Man Made Text. India, 46, 164 (2003).
F. Palacin, Melliand Int., 3, 169 (1997).
A. Di-Martino, A. R. Vaccaro, J. Y. Lee, V. Denaro, and M. R. Lim, Spine, 30, 16 (2005).
J. Scheirs in “Historicaloverview of Styrenepolymers”, 1st ed. (J. Scheirs and D. Priddy Eds.), Vol.1, pp.3–24, John Wiley, Chichester, 2003.
R. M. Silverstein, G. C. Bassler, and T. C. Morrill, “Spectrometric Identification of Organic Compounds”, pp.218–219, John Wiley and Sons, USA, 1981.
J. E. Guillet, Pure Appl. Chem., 49, 249 (1977).
M. M. Demir, M. Memesa, P. Castignolles, and G. Wegner, Macromol. Rapid Commun., 27, 763 (2006).
J. He, W. Shao, L. Zhang, C. Deng, and C. Li, J. Appl. Polym. Sci., 11, 1303 (2009).
A. Ammala, A. J. Hill, P. Meakin, S. J. Pas, and T. W. Turney, J. Nanopart. Res., 4, 167 (2002).
D. W. Chae and B. C. Kim, J. Appl. Polym. Sci., 99, 1854 (2006).
D. W. Chae and B. C. Kim, Polym. Adv. Technol., 16, 846 (2006).
S. Livraghi, I. Corazzari, M. C. Paganini, G. Ceccone, E. Giamello, B. Fubini, and I. Fenoglio, Chem. Commun., 46, 8478 (2010).
W. F. Chen, F. S. Li, J. Y. Yu, and Y. X. Li, J. Rare Earths, 24, 434 (2006).
W. I. Park, G. C. Yi, J. W. Kim, and S. M. Park, Appl. Phys. Lett., 82, 4358 (2003).
Y. Zhou, S. H. Yu, C. Y. Wang, and X. G. Li, Adv. Mater., 11, 850 (1999).
P. K. Khanna, R. Gokhale, and V. V. V. S. Subbarao, J. Mater. Sci., 39, 3773 (2004).
D. Wu, X. Ge, and Y. Huang, Mater. Lett., 57, 3549 (2003).
O. L. A. Monti, J. T. Fourkas, and D. J. Nesbitt, J. Phys. Chem. B., 108, 1604 (2004).
J. Xue, M. A. McKinney, and C. A. Wilkie, Polym. Degrad. Stabil., 58, 193 (1997).
J. Zheng, R. W. Siegel, and C. G. Toney, J. Polym. Sci. Pt. B-Polym. Phys., 41, 1033 (2003).
J. Zhou, F. Zhao, Y. Wang, Y. Zhang, and L. Yang, J. Lumin., 122, 195 (2007).
Z. M. Khoshhesab, M. Sarfaraz, and M. A. Asadabad, Synth. React. Inorg. M., 41, 814 (2011).
M. Pattabi, B. S. Amma, and K. Manzoor, Mater. Res. Bull., 42, 828 (2007).
D. M. Fernandes, R. Silva, A. A. Hechenleitner, W. E. Radovanovic, M. A. C. Melo, and E. A. G. Pineda, Mater. Chem. Phy., 11, 110 (2009).
H. Bundela and A. K. Bajpai, Express Polym. Lett., 2, 201 (2008).
S. Deshpande-Deepti, R. Bajpai, and A. K. Bajpai, Int. J. Chem. Res., 3, 74 (2011).
A. Takshi, A. Dimopoulos, and J. D. Madden, Solid-State Electron., 52, 107 (2007).
D. S. Deshpande, R. Bajpai, and A. K. Bajpai, J. Polym. Res., 19, 9938 (2012).
P. S. Gils, D. Ray, G. P. Mohanta, R. Manavalan, and P. Sahoo, Int. J. Pharm. Sci., 1, 43 (2009).
M. Hamed, H. Sabah, and A. Sarkawt, Asian Trans. Sci. Technol., 1, 16 (2012).
P. Huh, F. Li, L. Kim, M. R. Mosurkal, L. A. Samuelson, and J. Kumar, J. Mater. Chem., 18, 637 (2008).
J. F. Rabek, “Polymer Photodegradation-Mechanisms, Experimental Methods”, p.664, Springer Science & Business Media, London, 1995.
P. Liu and T. Wang, Curr. Appl. Phys., 8, 66 (2008).
G. E. Mckee, A. Kistenmacher, H. Goerrissen, and M. Breulmann in “Modern Styrenic Polymers: Poly Styrenes and Styrenic Copolymers” (J. Scheirs and D. Priddy Eds.), pp.341–362, John Wiley & Sons, Wiltshire, 2003.
B. Lobo, M. R. Ranganath, T. S. G. Ravi-Chandran, G. Rao, V. Ravindrachary, and S. Gopal, Phys. Rev. B., 59, 13693 (1999).
H. Zahr-El-Deenb and A. I. Hafez, The Arabian J. Sci. Eng., 34, 13 (2009).
A. Wasan, T. Mohammed, and K. Tagreed, J. Baghdad. Sci., 8, 543 (2011).
J. J. Sawai, J. Microbiol. Methods, 54, 177 (2003).
O. Akhavan, M. Mehrabian, K. Mirabbaszadeh, and R. Azimirad, J. Phys. D-Appl. Phys., 42, 225305 (2009).
Q. L. Feng, J. Wu, G. Q. Chen, F. Z. Cui, T. N. Kim, and J. O. Kim, J. Biomed. Mater. Res. Part A, 52, 662 (2000).
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Chouhan, S., Bhatt, R., Bajpai, A.K. et al. Investigation of UV absorption and antibacterial behavior of zinc oxide containing poly(vinyl alcohol-g-acrylonitrile) (PVA-g-PAN) nanocomposites films. Fibers Polym 16, 1243–1254 (2015). https://doi.org/10.1007/s12221-015-1243-y
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DOI: https://doi.org/10.1007/s12221-015-1243-y