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Applications of Transition Metal (Fe, Co, Ni)-Based Metal–Organic Frameworks and their Derivatives in Batteries and Supercapacitors

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Abstract

Metal–organic frameworks (MOFs), which are generally considered to be crystalline materials comprising metal centers and organic ligands, have attracted growing attention because of their controllable structures and high porosity. MOFs based on transition metals (Fe, Co, Ni) are highly efficient electrode materials for electrochemical energy storage. In this review, the characteristics of Fe-MOFs, Co-MOFs, Ni-MOFs, and their derivatives are summarized, and the relationships between the structures and performance are unveiled in depth. Additionally, their applications in lithium–ion batteries, lithium–sulfur batteries, and supercapacitors are discussed. This review sheds light on the development of MOFs and their derivatives to realize excellent electrochemical performance.

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Fig. 1
Fig. 2

Reproduced with permission from Ref. [39]. Copyright © 2017 American Chemical Society. b Crystal structure of MOF (Ni–Me4bpz); Ni: red, Cl: green, N: blue, C: black. Reproduced with permission from Ref. [50]. Copyright © 2015 Elsevier. c N/S co-doped carbon enhance the properties of supercapacitors. Reproduced with permission from Ref. [65]. Copyright © 2013 The Royal Society of Chemistry

Fig. 3

Reproduced with permission from Ref. [84]. Copyright © 2012 American Chemical Society. d SEM image of FCNSC. e Schematic diagram of the FCNSC preparation. f Cycling performance and Coulombic efficiency at 1 A/g. Reproduced with permission from Ref. [105]. Copyright © 2017 The Royal Society of Chemistry

Fig. 4

Reproduced with permission from Ref. [119]. Copyright © 2014 The Royal Society of Chemistry. d Illustration of the fabrication of Ni@NC-rGO. e SEM of Ni@NC-rGO. f Cycling performance of a Ni@NC-rGO electrode at 1 A/g. Reproduced with permission from Ref. [67]. Copyright © 2019 The Royal Society of Chemistry

Fig. 5

Reproduced with permission from Ref. [124]. Copyright © 2018 Elsevier. c SEM image of Fe-soc@GO. d Charge/discharge curves of S/Fe-soc@rGO at 0.1 C. Reproduced with permission from Ref. [135]. Copyright © 2020 Elsevier. e SEM image of Co–N-GC composite materials. f Rate capability of S@Co–N-G. Reproduced with permission from Ref. [137]. Copyright © 2016 The Royal Society of Chemistry. g SEM image of Co, N-CNTs-CNS/CFC. h Rate performance of the Co, N-CNTs-CNS/CFC electrode. Reproduced with permission from Ref. [140] Copyright © 2019 WILEY–VCH

Fig. 6

Reproduced with permission from Ref. [148]. Copyright © 2017 Wiley–VCH. d SEM image of Co9S8/NS-C. e Synthetic process for Co9S8/NS-C. f Charge and discharge curves of Co9S8/NS-C. Reproduced with permission from Ref. [65]. Copyright © 2017 The Royal Society of Chemistry

Fig. 7

Reproduced with permission from Ref. [37]. Copyright © 2011 Elsevier. c TEM of a Co-MOF material. d Charge–discharge profiles of the Co-MOF electrode. Reproduced with permission from Ref. [152]. Copyright © 2016 Wiley–VCH

Fig. 8

Reproduced with permission from Ref. [160]. Copyright © 2018 The Royal Society of Chemistry. d TEM image of Ni/Co-MOF. e The synthesis process of Ni/Co-MOF and Ni-MOF. f CV curves of Ni/Co-MOF in 1 M LiOH solution. Reproduced with permission from Ref. [162]. Copyright © 2017 Springer

Fig. 9

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. NSFC-U1904215), the Top-notch Academic Programs Project of Jiangsu Higher Education Institutions (TAPP), and the Natural Science Foundation of Jiangsu Province (No. BK20200044). Program for Young Changjiang Scholars of the Ministry of Education, China (No. Q2018270). We also acknowledge the Priority Academic Program Development of Jiangsu Higher Education Institutions.

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  1. School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002, China

    Xinguo Jin, Yuying Shan, Fancheng Sun & Huan Pang

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Jin, X., Shan, Y., Sun, F. et al. Applications of Transition Metal (Fe, Co, Ni)-Based Metal–Organic Frameworks and their Derivatives in Batteries and Supercapacitors. Trans. Tianjin Univ. 28, 446–468 (2022). https://doi.org/10.1007/s12209-022-00340-z

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