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Structural and magnetic properties of zinc- and aluminum-substituted cobalt ferrite prepared by co-precipitation method

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Abstract

Spinal ferrites having the general formula Co1 − x Zn x Fe2 − x Al x O4 (x = 0.0, 0.1, 0.2, 0.3, 0.4, 0.5, 0.6) were prepared using the wet chemical co-operation technique. The samples were annealed at 800°C for 12 h and were studied by means of X-ray diffraction, magnetization and low field AC susceptibility measurements. The X-ray analysis showed that all the samples had single-phase cubic spinel structure. The variation of lattice constant with Zn and Al concentration deviates from Vegard’s law. The saturation magnetization σ s and magneton number n B measured at 300 K using high field hysteresis loop technique decreases with increasing x, suggesting decrease in ferrimagnetic behaviour. Curie temperature T C deduced from AC susceptibility data decreases with x, suggesting a decrease in ferrimagnetic behaviour.

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Alone, S.T., Jadhav, K.M. Structural and magnetic properties of zinc- and aluminum-substituted cobalt ferrite prepared by co-precipitation method. Pramana - J Phys 70, 173–181 (2008). https://doi.org/10.1007/s12043-008-0015-2

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  • DOI: https://doi.org/10.1007/s12043-008-0015-2

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