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Host-guest interactions of 8-aniline-1-naphthalene sulfonic acid with two macrocycles containing 2,6-pyridylamide and dipyrrole units

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Abstract

The host-guest interactions of two macrocycles L1 and L2 with 8-aniline-1-naphthalene sulfonic acid (1,8-ANS) were evaluated by fluorescence emission spectra. It was found that 1,8-ANS had a quenching effect upon the addition of the two macrocycles, which contain both 2,6-pyridylamide and dipyrrole units, and the corresponding binding ratios were also obtained. Furthermore, the binding behavior was investigated by H NMR titration. The results show that both the binding ratios of L1 and L2 with 1,8-ANS molecule are 1:1, and the stability constants are 3.06×104 L·mol-1 and 6.58×103 L·mol-1, respectively.

Graphical abstract

The host-guest interactions of macrocycles L1 and L2 with 8-aniline-1-naphthalene sulfonic acid were evaluated by fluorescence spectra and H NMR titration. The binding ratios of L1 and L2 with the compound are both 1:1, and the stability constants are 3.06×104 L·mol-1 and 6.58×103 L·mol-1.

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Acknowledgments

The authors acknowledge the support from the National Natural Science Foundation of China (no. 21961007) and Guizhou Provincial Science and Technology Projects in China (ZK[2022]059).

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Authors and Affiliations

  1. Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang, 550025, People’s Republic of China

    Rui Yi, Hongjuan Liu, Ying Xiong, Dongmei Chen, Chao Huang & Bixue Zhu

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  1. Rui Yi
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  2. Hongjuan Liu
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  3. Ying Xiong
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  4. Dongmei Chen
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  5. Chao Huang
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Correspondence to Chao Huang or Bixue Zhu.

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Yi, R., Liu, H., Xiong, Y. et al. Host-guest interactions of 8-aniline-1-naphthalene sulfonic acid with two macrocycles containing 2,6-pyridylamide and dipyrrole units. J Chem Sci 134, 92 (2022). https://doi.org/10.1007/s12039-022-02085-7

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  • DOI: https://doi.org/10.1007/s12039-022-02085-7

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