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Network and guest dependent thermal stability and thermal expansion in a trigonal host

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Abstract

Thermal stability and thermal expansion of bromo trimer synthon mediated hexagonal inclusion compounds of 2,4,6-tris(4-bromophenoxy)-1,3,5-triazine (BrPOT) with dichloromethane (DCM), tetrahydrofuran (THF) and hexamethyl benzene (HMB) and also the guest-free form of BrPOT are reported. Each of these three guests produced two concomitant inclusion compounds with BrPOT. The thermal stability of the solvate lattice increases with decreasing cavity size. The channel network of the DCM inclusion compound is stable only for a few seconds at room temperature outside the mother liquor, whereas the cage network of the DCM solvate is stable for months under similar conditions. Thermal expansions of the lattices depend upon the network, guest content as well as the type of guest molecules. The guest-free form exhibits the least thermal expansion in this series of systems.

Thermal stability and thermal expansion of hexagonal inclusion compounds of 2,4,6-tris(4-bromophenoxy)-1,3,5-triazine with dichloro- methane, tetrahydrofuran and hexamethyl benzene and also the guest-free form are reported.

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Acknowledgements

B K S thanks CSIR for research funding (No. 02(0026)/11/EMR-II, dated 16/12/11). We gratefully thank DST, India for SXRD facility, Dr. R N Bhowmik, Dept. of Physics, Pondicherry University for PXRD facilities, C.I.F, P.U. for TG-DSC and NMR facilities. V G S thanks UGC, M.A.B thanks CSIR and S.B. thanks Pondicherry University for fellowships.

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  1. Department of Chemistry, Pondicherry University, Puducherry, 605 014, India

    VISWANADHA G SARASWATULA, MUKHTAR AHMAD BHAT, SUMAN BHATTACHARYA & BINOY K SAHA

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  1. VISWANADHA G SARASWATULA
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  2. MUKHTAR AHMAD BHAT
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Correspondence to BINOY K SAHA.

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Supplementary Information

ORTEP plots, pictures of the single crystals, crystallographic information table, thermal expansion coefficient values, and interhalogen interaction geometry are given. Electronic supplementary information can be seen at www.ias.ac.in/chemsci.

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SARASWATULA, V.G., BHAT, M.A., BHATTACHARYA, S. et al. Network and guest dependent thermal stability and thermal expansion in a trigonal host. J Chem Sci 126, 1265–1273 (2014). https://doi.org/10.1007/s12039-014-0690-0

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  • DOI: https://doi.org/10.1007/s12039-014-0690-0

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