Abstract
Reported herein is the effect of dispersion of a fixed amount of 0.5% (wt/wt) ZnO nanoparticles (NPs) in a nematic (E7) liquid crystal (LC) mixture. Dispersion of ZnO NPs results in a significant improvement in electro-optical and dielectric parameters of the nematic mixture. Comparative analysis of undoped and NP-dispersed samples shows a reduced threshold voltage with better transmittance without compromising dielectric permittivity characteristics. In addition, an increase in the contrast ratio, birefringence, alternating-current conductivity and band gap was observed after dispersion of ZnO NPs in LCs. A polarized optical microscopic study of the NP-dispersed sample substantiates a slight increase in nematic–isotropic phase transition temperature of LCs.
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Nayek P, Karan S, Kundu S, Lee S H, Gupta S D, Roy S K et al 2012 J. Phys. D: Appl. Phys. 45 235303
de Gennes P G 1974 The physics of liquid crystals (Oxford: Clarendon Press)
Robbie K, Broer D J and Brett M J 1999 Nature 399 764
Grollau S, Abbott N L and de Pablo J J 2003 Phys. Rev. E 67 051703
Fukuda J, Yoneya M and Yokoyama H 2002 Phys. Rev. E 65 041709
Loudet C J, Barois P and Poulin P 2000 Nature 407 611
Andrienko D, Allen M P, Skacej G and Zumer S 2002 Phys. Rev. E 65 041702
Woltmann S J, Jay G D and Crawford G P 2007 Nat. Mater. 6 929
Eskalen H, Ozgan S, Alver U and Kerli S 2015 Acta Phys. Pol. A 127 756
Vardanyan K K, Palazzo E D and Walton R D 2011 Liq. Cryst. 38 709
Dolgov L, Yaroshchuk O and Lebovka M 2008 Mol. Cryst. Liq. Cryst. 496 212
Tripathi P K, Misra A K, Pandey K K and Manohar R 2013 Chem. Rapid Commun. 1 20
Chen W T, Chen P S and Chao C Y 2009 Jpn. J. Appl. Phys. 48 015006
Manohar R, Yadav S P, Srivastava A K and Misra A K 2009 Jpn. J. Appl. Phys. 48 101501
Reznikov Y, Buchnev O, Tereshchenko O, Reshetnyak V, Glushchenko A and West J 2003 Appl. Phys. Lett. 82 1917
Li F, Buchnev O, Cheon C I, Glushchenko A, Reshetnyak V, Reznikov Y et al 2006 Phys. Rev. Lett. 97 147801
Lee W, Wang C Y and Shih Y C 2004 Appl. Phys. Lett. 85 513
Lee C W and Shih W P 2010 Mater. Lett. 64 466
Maleki A, Ara M H M and Saboohi F 2016 Phase Transit. 90 371
Brochard F and de Gennes P G 1970 J. Phys. France 31 691
Rahman M and Lee W 2009 J. Phys. D: Appl. Phys. 42 063001
Misra A K, Srivastava A K, Shukla J P and Manohar R 2008 Phys. Scr. 78 065602
Allagulov A I, Pikin S A and Chigrinov V G 1989 Liq. Cryst. 5 1099
Zennyoji M, Yokoyama J, Takanishi Y, Ishikawa K, Takezoe H and Itoh K 1998 Jpn. J. Appl. Phys. 37 6071
Lagerwall S T 1999 Ferroelectric and antiferroelectric liquid crystals (Weinhelm: Wiley-VCH) p 200
Wu P C, Yang S Y and Lee W 2016 J. Mol. Liq. 218 150
Tomylko S, Yaroshchuk O, Kovalchuk O, Maschke U and Yamaguchi R 2012 Ukr. J. Phys. 5 239
Singh U B, Dhar R, Dabrowski R and Pandey M B 2014 Liq. Cryst. 41 953
Singh U B, Dhar R, Dabrowski R and Pandey M B 2013 Liq. Cryst. 40 774
Kurochkin O, Mavrona E, Apostolopoulos V, Blach J-F, Henninot J-F, Kaczmarek M et al 2015 Appl. Phys. Lett. 106 043111
Roy A, Pathak G, Herman J, Inamdar S R, Srivastava A and Manohar R 2018 Appl. Phys. A 124 273
Malik A, Choudhary A, Silotia P and Biradar A M 2011 J. Appl. Phys. 110 064111
Al-Zangana S, Turner M and Dierking I 2017 J. Appl. Phys. 121 085105
Kumar P, Debnath S, Rao N V S and Sinha A 2018 J. Phys. Condens. Matter 30 095101
Khushboo, Sharma P, Malik P and Raina K K 2017 Liq. Cryst. 44 1717
Prasad A and Das M K 2010 J. Phys. Condens. Matter 22 195106
West J L, Zhang G and Glushchenko A 2005 Appl. Phys. Letts. 86 031111
Pande M, Tripathi P K, Gupta S K, Manohar R and Singh S 2015 Liq. Cryst. 42 1465
Basu R and Shalov S A 2017 Phys. Rev. E. 96 012702
Mavrona E, Chodorow U, Barnes M E, Parka J, Palka N, Saitzek S et al 2015 AIP Adv. 5 077143
Montgomery G P Jr and Vaz N A 1987 Appl. Opt. 26 738
Raina K K, Kumar P and Malik P 2006 Bull. Mater. Sci. 29 599
Singh D P, Pandey S, Gupta S K, Manohar R, Daoudi A, Sahraoui A H et al 2016 J. Lumin. 173 250
Porov P, Chandel V S and Manohar R 2016 Trans. Electr. Electron. Mater. 17 69
Koneracka M, Kellnerova V, Kopcansky P and Kuczynski T 1995 J. Magn. Magn. Mater. 140 1455
Cole K S and Cole R H 1941 J. Chem. Phys. 9 341
Gouda F, Skarp K and Lagerwall S T 1991 Ferroelectric 113 165
Dhar R 2004 Ind. J. Pure Appl. Phys. 42 56
Chaudhary A, Malik P, Mehra R and Raina K K 2012 Phase Transit. 85 244
Srivastava S L and Dhar R 1996 Radiat. Phys. Chem. 47 287
Khushboo, Sharma P, Malik P and Raina K K 2016 Liq. Cryst. 43 1671
Hassanien A S and Akl Alaa A 2016 Superlattices Microstruct. 89 153
Acknowledgements
The authors sincerely thank the Director, NIT Jalandhar for continuous encouragement and support. The authors also thank DST, SERB and CSIR India for financial support under the Project Numbers EMR/2016/003560 and CSIR/03-1451/18/EMR-II, respectively.
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Sharma, A., Malik, P., Dhar, R. et al. Improvement in electro-optical and dielectric characteristics of ZnO nanoparticles dispersed in a nematic liquid crystal mixture. Bull Mater Sci 42, 215 (2019). https://doi.org/10.1007/s12034-019-1902-5
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DOI: https://doi.org/10.1007/s12034-019-1902-5