Abstract
Electrodeposition of zinc on steel was obtained from acid chloride bath containing condensation products (CP) of 3,4,5-trimethoxy benzaldehyde (TMB) and chitosan (CTN). The effect of bath constituents, pH, current density and temperature on the nature of deposit was studied by Hull cell experiments. The bath composition and operating parameters were optimized. The adhesion, ductility and corrosion resistance of the deposits were discussed. Throwing power and current efficiency values under different plating conditions were measured. SEM photomicrographs of the deposit were taken to study the surface morphology. The inclusion of addition agent in the deposit was investigated from IR spectrum of the scrapped deposit. The consumption of brightener in the lab scale is 10 mLL−1 for 1000 amp-h.
Similar content being viewed by others
References
Arcilless 1979 US patent. 852, 439
Arthoba Naik Y and Venkatesha T V 2005 Bull. Mater. Sci. 28 495
Arthoba Naik Y, Venkatesha T V and Vasudeva Nayak P 2000 Bull. Electrochem. 16 481
Arthoba Naik Y, Venkatesha T V and Vasudeva Nayak P 2001 Indian J. Chem. Technol. 390
Bapu G N K, Devaraj R G and Ayyapparaj J 1998 J. Solid State Electrochem. 3 48
Budman Edward 1995 Met. Finish 93 60
Degorre J M 1993 Galvano-organo. 62 845
Geduld H 1974 Met. Finish 36 72
Morrison R T and Boyd R N 1973 Organic chemistry (New Delhi: Prentice-Hall of India Pvt Ltd) 2nd ed., p. 633
Ostrow R and Kessler R B 1970 Plating 57 357
Parthasarathy N V 1989 Practical electroplating handbook (New Jersey: Prentice Hall Inc) 1st ed., p. 283
Ramachandran A and Mayanna S M 1992 Met. Finish 90 61
Schneider H S 1977 Plating Surf Finish 64 52
Venkatesha T V 1987 Development of brighteners for noncyanide industrial zinc-cadmium electroplating baths, Ph.D. thesis, Bangalore University, Bangalore
Venkatesha T V, Balachandra J, Dambal R P and Mayanna S M 1985 Met. Finish 83 33
Venkatesha T V, Balachandra J, Dambal R P and Mayanna S M 1988 Proc. Interfinish. Paris, France 88 52
Wang Ruixiang 1992 Cailiao Baohu. 25 33
Zeng Lingxi 1996 Cailiao Baohu. 29 28
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Shivakumara, S., Manohar, U., Arthoba Naik, Y. et al. Effect of condensation product on electrodeposition of zinc on mild steel. Bull Mater Sci 30, 463–468 (2007). https://doi.org/10.1007/s12034-007-0073-y
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s12034-007-0073-y