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Experimental Investigation of the Effect of ZnO-Citrus sinensis Nano-additive on the Electrokinetic Deposition of Zinc on Mild Steel in Acid Chloride

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TMS 2018 147th Annual Meeting & Exhibition Supplemental Proceedings (TMS 2018)

Abstract

This work investigated the effect of ZnO-Citrus sinensis nano-additive on the electrokinetic deposition of Zinc on mild steel in acid chloride. Fifty-four plates of (100 × 10 × 3) mm3 mild steel samples were cut, cleaned with dilute H2SO4 solution, rinsed in water and dried. The nano-additive was produced by infusing 30 ml Orange Juice extract in Zinc Oxide solution. The acid chloride electrolyte consisting of 71 g ZnCl, 207 g KCl and 35 g H3BO3 in 1 l of distilled water was divided into six portions. The nano-additive with different molar concentrations 0(0.2)1.0 was added to each portion of the acid chloride. Nine plates of mild steel samples were electroplated with zinc as the anode in each of the six prepared electrolyte solution and plated at different times (three plates each at 10, 15 and 20 min). The effects of electroplating on the average weights were measured and the results from the experiment showed the optimal nano-additive concentration and electroplating time.

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References

  1. Singh MK (2016) Application of Steel in Automotive Industry. Int J Emerg Technol Adv Eng 6(7):2250–2459

    Google Scholar 

  2. DeCicco JM (2005) Steel and iron technologies for automotive light weighting. Environ Defense

    Google Scholar 

  3. Ultralight Steel Auto Body (1998) Final report. American Iron and Steel Institute, Southfield, MI. March

    Google Scholar 

  4. Opbroek E, Weissert U (1998) Ultralight steel auto closures project. SAE Paper No. 982308

    Google Scholar 

  5. Popoola API, Fayomi OS (2011) Performance evaluation of zinc deposited mild steel in chloride medium. Int J Electrochem Sci 6(2011):3254–3263

    CAS  Google Scholar 

  6. Fang F, Brown B, Nesic S (2010) Corr Sci Sect 67:1–12

    Google Scholar 

  7. Abdullah M, Fouda AS, Shama SA, Afifi EA (2008) Africa J Pure Appl Chem 2(2008):83–91

    Google Scholar 

  8. Donald RA (1994) The science and engineering of materials. PWS Publishing Company, Washington, p 8

    Google Scholar 

  9. Joo YL, Joe WK, Min KL, Hyun TK, Su-moon P (2004) J Electrochem Soc 151:C25–C31

    Article  CAS  Google Scholar 

  10. de Pedro N, Adriana N, Correia P, Walney SA (2007) J Braz Chem Soc 18:1164–1175

    Article  Google Scholar 

  11. Shivakumara S, Manohar U, Arthoba Naik Y, Venkatesha Enkatesha TU (2007) Influence of additives on electrodeposition of bright Zn–Ni alloy on mild steel from acid sulphate bath. Bull Mater Sci 30(5):455–462. © Indian Academy of Sciences

    Article  CAS  Google Scholar 

  12. Popoola API, Fayomi OSI (2011) Effect of some process variables on zinc coated low carbon steel substrates. Sci Res Essays 6(20):4264–4272, 19 Sept 2011. https://doi.org/10.5897/sre11.777. ISSN 1992-2248 ©2011 Academic Journals

    Article  CAS  Google Scholar 

  13. Hague IU, Ahmad N, Akhan Jour A (2005) Chem Soc Pak 27:307–311

    Google Scholar 

  14. Field S, Weil AD (1951) Electroplating. Sir Isaac Pitman & Sons Ltd., London, p 136

    Google Scholar 

  15. Dini JW (1993) Electrodeposition—the materials science of coatings and substrates. Noyes Publications, New Jersey, USA, p 195

    Google Scholar 

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Correspondence to Oluseyi O. Ajayi .

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Ajayi, O.O. et al. (2018). Experimental Investigation of the Effect of ZnO-Citrus sinensis Nano-additive on the Electrokinetic Deposition of Zinc on Mild Steel in Acid Chloride. In: & Materials Society, T. (eds) TMS 2018 147th Annual Meeting & Exhibition Supplemental Proceedings. TMS 2018. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-319-72526-0_4

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