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Fabrication and multifunctional properties of fluorine-free durable nickel stearate based superhydrophobic cotton fabric

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Abstract

A fluorine-free superhydrophobic cotton fabric based on nickel stearate with multifunctional properties has been fabricated by a two step simple solution process. The cotton fabric (aNS-CF) exhibits static water contact angle, ~ 160°, and water shedding angle, < 10°, due to in-situ formation of hierarchical (micro and nano) broccoli-like structures of nickel stearate. The superhydrophobic cotton fabric, having superoleophilic property, has been used for separation of a series of light/heavy oil–water mixtures, and ~ 99% separation efficiency has been achieved after 10 cycles of separation process and it has been found to be slightly reduced to ~ 98% after 50 cycles. Antifouling and self-cleaning performance of the fabric has been evaluated effectively using solid and liquid contaminants as well as some common food liquids. The coating exhibits significant mechanical and chemical robustness and laundering durability in harsh conditions. The coated fabric possesses antibacterial (gram-negative E. coli and gram-positive S. aureus) and antifungal (C. albicans) properties leading to ~ 99.99% reduction in microbial growth, which has been remarkably sustained after 50 cycles of washing, abrasion and separation of oil–water mixtures. The stable multifunctional properties of the fabric exhibits a great potential towards a huge domain of practical implementations in smart textiles.

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References

  1. Li, X-M, Reinhoudt, D, Crego-Calama, M, “What Do We Need for a Superhydrophobic Surface? A Review on the Recent Progress in the Preparation of Superhydrophobic Surfaces.” Chem. Soc. Rev., 36 1350–1368 (2007)

    Article  Google Scholar 

  2. Sasmal, AK, Mondal, C, Sinha, AK, Gauri, SS, Pal, J, Aditya, T, Ganguly, M, Dey, S, Pal, T, “Fabrication of Superhydrophobic Copper Surface on Various Substrates for Roll-off, Self-Cleaning, and Water/Oil Separation.” ACS Appl. Mater. Interfaces, 6 22034–22043 (2014)

    Article  CAS  Google Scholar 

  3. Wei, Y, Hongtao, L, Wei, Z, “Preparation of Anti-Corrosion Superhydrophobic Coatings by an Fe-Based Micro/Nano Composite Electro-Brush Plating and Blackening Process.” RSC Adv., 5 103000–103012 (2015)

    Article  CAS  Google Scholar 

  4. Razavi, SMR, Oh, J, Haasch, RT, Kim, K, Masoomi, M, Bagheri, R, Slauch, JM, Miljkovic, N, “Environment-Friendly Antibiofouling Superhydrophobic Coatings.” ACS Sustain. Chem. Eng., 7 14509–14520 (2019)

    Article  CAS  Google Scholar 

  5. Shaban, M, Mohamed, F, Abdallah, S, “Production and Characterization of Superhydrophobic and Antibacterial Coated Fabrics Utilizing ZnO Nanocatalyst.” Sci. Rep., 8 3925 (2018)

    Article  CAS  Google Scholar 

  6. Zhou, X, Zhang, Z, Xu, X, Guo, F, Zhu, X, Men, X, Ge, B, “Robust and Durable Superhydrophobic Cotton Fabrics for Oil/Water Separation.” ACS Appl. Mater. Interfaces, 5 7208–7214 (2013)

    Article  CAS  Google Scholar 

  7. Lai, Y, Tang, Y, Gong, J, Gong, D, Chi, L, Lin, C, Chen, Z, “Transparent Superhydrophobic/Superhydrophilic TiO2-Based Coatings for Self-Cleaning and Anti-Fogging.” J. Mater. Chem., 22 7420–7426 (2012)

    Article  CAS  Google Scholar 

  8. Barthwal, S, Lim, S, “Rapid Fabrication of Dual-Scale Micro-Nanostructured Superhydrophobic Aluminum Surface with Delayed Condensation and Ice Formation Properties.” Soft Matter, 15 7945–7955 (2019)

    Article  CAS  Google Scholar 

  9. Zhu, T, Cheng, Y, Huang, J, Xiong, J, Ge, M, Mao, J, Liu, Z, Dong, X, Chen, Z, Lai, Y, “A Transparent Superhydrophobic Coating with Mechanochemical Robustness for Anti-Icing, Photocatalysis and Self-Cleaning.” Chem. Eng. J., 399 125746 (2020)

    Article  CAS  Google Scholar 

  10. Tudu, BK, Sinhamahapatra, AK, “A Surface Modification of Cotton Fabric Using TiO2 Nanoparticles for Self-Cleaning, Oil-Water Separation, Antistain, Anti-Water Absorption, and Antibacterial Properties.” ACS Omega, 5 7850–7860 (2020)

    Article  CAS  Google Scholar 

  11. Yang, M, Liu, W, Jiang, C, Xie, Y, Shi, H, Zhang, F, Wang, Z, “Facile Construction of Robust Superhydrophobic Cotton Textiles for Effective UV Protection, Self-Cleaning and Oil-Water Separation.” Colloids Surf. A Physicochem. Eng. Asp., 570 172–181 (2019)

    Article  CAS  Google Scholar 

  12. Pakdel, E, Wang, J, Kashi, S, Sun, L, Wang, X, “Advances in Photocatalytic Self-Cleaning, Superhydrophobic and Electromagnetic Interference Shielding Textile Treatments.” Adv. Colloid Interface Sci., 277 102116 (2020)

    Article  CAS  Google Scholar 

  13. Chen, X, He, Y, Fan, Y, Yang, Q, Zeng, G, Shi, H, “Facile Fabrication of a Robust Superwetting Three-Dimensional (3D) Nickel Foam for Oil/Water Separation.” J. Mater. Sci., 52 2169–2179 (2017)

    Article  CAS  Google Scholar 

  14. Singh, AK, Singh, JK, “Fabrication of Zirconia Based Durable Superhydrophobic Superoleophilic Fabrics Using Non Fluorinated Materials for Oil–Water Separation and Water Purification.” RSC Adv., 6 103632–103640 (2016)

    Article  CAS  Google Scholar 

  15. Xu, C-L, Wang, Y-Z, “One-Step Approach to the Growth of ZnO Nano-/Microrods on Cellulose Toward Its Durable Superhydrophobicity.” Adv. Mater. Interfaces, 4 1700550 (2017)

    Article  CAS  Google Scholar 

  16. Manatunga, DC, de Silva, RM, de Silva, KMN, “Double Layer Approach to Create Durable Superhydrophobicity on Cotton Fabric Using Nano Silica and Auxiliary Non Fluorinated Materials.” Appl. Surf. Sci., 360 777–788 (2016)

    Article  CAS  Google Scholar 

  17. Chen, D, Mai, Z, Liu, X, Ye, D, Zhang, H, Yin, X, Zhou, Y, Liu, M, Xu, W, “UV-Blocking, Superhydrophobic and Robust Cotton Fabrics Fabricated Using Polyvinylsilsesquioxane and Nano-TiO2.” Cellulose, 6 3635–3647 (2018)

    Article  CAS  Google Scholar 

  18. Hong, HR, Kim, J, Park, CH, “Facile Fabrication of Multifunctional Fabrics: Use of Copper and Silver Nanoparticles for Antibacterial, Superhydrophobic, Conductive Fabrics.” RSC Adv., 8 41782–41794 (2018)

    Article  CAS  Google Scholar 

  19. Xu, H, Liu, J, Chen, Y, Tang, J, Zhao, Z, “Facile Fabrication of Superhydrophobic Polyaniline Structures and Their Anticorrosive Properties.” J. Appl. Polym. Sci., 133 44248 (2016)

    Google Scholar 

  20. Cheng, Q-Y, Zhao, X-L, Weng, Y-X, Li, Y-D, Zeng, J-B, “Fully Sustainable, Nanoparticle-Free, Fluorine-Free, and Robust Superhydrophobic Cotton Fabric Fabricated via an Eco-Friendly Method for Efficient Oil/Water Separation.” ACS Sustain. Chem. Eng., 7 15696–15705 (2019)

    Article  CAS  Google Scholar 

  21. Dashairya, L, Rout, M, Saha, P, “Reduced Graphene Oxide-Coated Cotton as an Efficient Absorbent in Oil-Water Separation.” Adv. Compos. Hybrid. Mater., 1 135–148 (2018)

    Article  CAS  Google Scholar 

  22. Song, Q, Wang, H, Han, S, Wang, J, Zhang, B, Zhang, Y, “Halloysite Nanotubes Functionalized Cotton Fabric for Oil/Water Separation.” Prog. Org. Coat., 148 105839 (2020)

    Article  CAS  Google Scholar 

  23. Cheng, Q-Y, Guan, C-S, Wang, M, Li, Y-D, Zeng, J-B, “Cellulose Nanocrystal Coated Cotton Fabric with Superhydrophobicity for Efficient Oil/Water Separation.” Carbohyd. Polym., 199 390–396 (2018)

    Article  CAS  Google Scholar 

  24. Gao, S, Dong, X, Huang, J, Li, S, Li, Y, Chen, Z, Lai, Y, “Rational Construction of Highly Transparent Superhydrophobic Coatings Based on a Non-Particle, Fluorine-Free and Water-Rich System for Versatile Oil-Water Separation.” Chem. Eng. J., 333 621–629 (2018)

    Article  CAS  Google Scholar 

  25. Cao, C, Wang, F, Lu, M, “Preparation of Superhydrophobic CuS Cotton Fabric with Photocatalytic and Antibacterial Activity for Oil/Water Separation.” Mater. Lett., 260 126956 (2020)

    Article  CAS  Google Scholar 

  26. Zhang, M, Pang, J, Bao, W, Zhang, W, Gao, H, Wang, C, Shi, J, Li, J, “Antimicrobial Cotton Textiles with Robust Superhydrophobicity via Plasma for Oily Water Separation.” Appl. Surf. Sci., 419 16–23 (2017)

    Article  CAS  Google Scholar 

  27. Fu, Y, Jin, B, Zhang, Q, Zhan, X, Chen, F, “pH-Induced Switchable Superwettability of Efficient Antibacterial Fabrics for Durable Selective Oil/Water Separation.” ACS Appl. Mater. Interfaces, 9 30161–30170 (2017)

    Article  CAS  Google Scholar 

  28. Dong, X, Gao, S, Huang, J, Li, S, Zhu, T, Cheng, Y, Zhao, Y, Chen, ZY, “A Self-Roughened and Biodegradable Superhydrophobic Coating with UV Shielding, Solar Induced Self-Healing and Versatile Oil–Water Separation Ability.” J. Mater. Chem. A, 7 2122–2128 (2019)

    Article  CAS  Google Scholar 

  29. Seth, M, Khan, H, Jana, S, “Hierarchically Structured Alpha-Nickel Hydroxide Based Superhydrophobic and Antibacterial Coating on Cellulosic Materials for Oil-Water Separation.” Mater. Chem. Phys., 249 123030 (2020)

    Article  CAS  Google Scholar 

  30. Seth, M, Jana, S, “Fabrication and Multifunctional Properties of Marigold-Like Nanostructured β-Ni(OH)2 Coated Cotton Fabric.” Cellulose, 28 1731–1752 (2021)

    Article  CAS  Google Scholar 

  31. Seth, M, Khan, H, Jana, S, “Antimicrobial Activity Study of Ag-ZnO Nanoflowers Synthesised from Neem Extract and Application in Cotton Textiles.” Int. J. Nanotechnol., 18 531–544 (2021)

    Article  CAS  Google Scholar 

  32. Zimmermann, J, Reifler, FA, Fortunato, G, Gerhardt, L-C, Seeger, S, “A Simple, One-Step Approach to Durable and Robust Superhydrophobic Textiles.” Adv. Funct. Mater., 18 3662–3669 (2008)

    Article  CAS  Google Scholar 

  33. Xu, N, Sarkar, DK, Chen, X-G, Tong, WP, “Corrosion Performance of Superhydrophobic Nickel Stearate/Nickel Hydroxide Thin Films on Aluminum Alloy by a Simple One-Step Electrodeposition Process.” Surf. Coat. Technol., 302 173–184 (2016)

    Article  CAS  Google Scholar 

  34. Seth, M, Khan, H, Bhowmik, R, Karmakar, S, Jana, S, “Facile Fabrication of Fluorine Free Zirconium Zinc Stearate Based Superhydrophobic and Superoleophilic Coating on Cotton Fabric with Superior Antibacterial Property.” J. Sol Gel Sci. Technol., 94 127–140 (2020)

    Article  CAS  Google Scholar 

  35. Yin, J, Zhou, G, Gao, X, Chen, J, Zhang, L, Xu, J, Zhao, P, Gao, F, “α- and β-Phase Ni-Mg Hydroxide for High Performance Hybrid Supercapacitors.” Nanomaterials, 9 1686 (2019)

    Article  CAS  Google Scholar 

  36. Latthe, SS, Terashima, C, Nakata, K, Fujishima, A, “Superhydrophobic Surfaces Developed by Mimicking Hierarchical Surface Morphology of Lotus Leaf.” Molecules, 19 4256–4283 (2014)

    Article  CAS  Google Scholar 

  37. Arfaoui, MA, Dolez, PI, Dubé, DÉ, “Development and Characterization of a Hydrophobic Treatment for Jute Fibres Based on Zinc Oxide Nanoparticles and a Fatty Acid.” Appl. Surf Sci., 397 19–29 (2017)

    Article  CAS  Google Scholar 

  38. Yang, Y, Guo, Z, Huang, W, Zhang, S, Huang, J, Yang, H, Zhou, Y, Xu, W, Gu, S, “Fabrication of Multifunctional Textiles with Durable Antibacterial Property and Efficient Oil-Water Separation via In Situ Growth Of Zeolitic Imidazolate Framework-8 (ZIF-8) on Cotton Fabric.” Appl. Surf Sci., 503 144079 (2020)

    Article  CAS  Google Scholar 

  39. Agrawal, N, Low, PS, Tan, JSJ, Fong, EWM, Lai, Y, Chen, Z, “Durable Easy-Cleaning and Antibacterial Cotton Fabrics Using Fluorine-Free Silane Coupling Agents and CuO Nanoparticles.” Nano Mater. Sci., 2 281–291 (2020)

    Article  Google Scholar 

  40. Sathiyavimal, S, Vasantharaj, S, Bharathi, D, Saravanan, M, Manikandan, E, Kumar, SS, Pugazhendhi, A, “Biogenesis of Copper Oxide Nanoparticles (CuO NPs) Using Sida acuta and Their Incorporation Over Cotton Fabrics to Prevent the Pathogenicity of Gram Negative and Gram Positive Bacteria.” J. Photoch. Photobiol. B, 188 126–134 (2018)

    Article  CAS  Google Scholar 

  41. Seth, M, Jana, S, “Nanomaterials Based Superhydrophobic and Antimicrobial Coatings.” NanoWorld J., 6 26–28 (2020)

    Article  CAS  Google Scholar 

  42. Raj, P, Singh, A, Singh, A, Singh, N, “Syntheses and Photophysical Properties of Schiff Base Ni(II) Complexes: Application for Sustainable Antibacterial Activity and Cytotoxicity.” ACS Sustain. Chem. Eng., 5 6070–6080 (2017)

    Article  CAS  Google Scholar 

  43. Garcia-Rubio, R, de Oliveira, HC, Rivera, J, Trevijano-Contador, N, “The Fungal Cell Wall: Candida, Cryptococcus, and Aspergillus Species.” Front. Microbiol., 10 2993 (2020)

    Article  Google Scholar 

  44. Karim, N, Afroj, S, Lloyd, K, Oaten, LC, Andreeva, DV, Carr, C, Farmery, AD, Kim, I-D, Novoselov, KS, “Sustainable Personal Protective Clothing for Healthcare Applications: A Review.” ACS Nano, 14 12313–12340 (2020)

    Article  CAS  Google Scholar 

  45. Seth, M, Khan, H, Bera, S, Naskar, A, Jana, S, “Green Synthesis of Hierarchically Structured Metal and Metal Oxide Nanomaterials.” In: Inamuddin, BR, Ahamed, MI, Khan, A (eds.) Advances in Green Synthesis Advances in Science, Technology and Innovation, pp. 91–113. Springer, Cham (2021)

    Google Scholar 

  46. Silhavy, TJ, Kahne, D, Walker, S, “The Bacterial Cell Envelope.” Cold Spring Harb. Perspect. Biol., 2 a000414 (2012)

    Google Scholar 

  47. Yin, B, Liu, T, Yin, Y, “Prolonging the Duration of Preventing Bacterial Adhesion of Nanosilver-Containing Polymer Films Through Hydrophobicity.” Langmuir, 28 17019–17025 (2012)

    Article  CAS  Google Scholar 

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Acknowledgments

Malobi Seth thankfully acknowledges Department of Science and Technology (DST), Government of India for providing her Ph.D Research Fellowship under DST-Inspire Fellowship Scheme. All the authors acknowledge the help rendered by Electron Microscopy Section for some materials characterizations.

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  1. Specialty Glass Division, CSIR-Central Glass and Ceramic Research Institute, 196 Raja S.C. Mullick Road, Jadavpur, Kolkata, 700032, India

    Malobi Seth & Sunirmal Jana

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  2. Sunirmal Jana
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Correspondence to Sunirmal Jana.

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Seth, M., Jana, S. Fabrication and multifunctional properties of fluorine-free durable nickel stearate based superhydrophobic cotton fabric. J Coat Technol Res 19, 813–827 (2022). https://doi.org/10.1007/s11998-021-00559-w

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