Abstract
Effect pigments were originally developed to realize advanced optical effects by coating on several types of material surfaces. However, metallic effect pigments are expected to be valuable for many other applications, such as antimicrobial effects, electrical conductive coatings, or shielding against radio waves (electromagnetic shielding). Accordingly, the aim of this article is to evaluate the advanced properties which can be realized by application of coatings containing metallic effect pigments onto textile materials leading to new functional textiles. In total, four different metallic effect pigments were investigated and compared to silver and graphite pigments. By application of coatings with copper- or silver-containing effect pigments significant antibacterial properties against E. coli and S. aureus can be realized. To achieve electric conductive textiles, which also enable effective shielding against radio waves, a copper pigment carrying a silver coating leads to the best properties. Altogether, an effective coating method is presented to achieve functional textiles that offer a broad range of possible applications.
Similar content being viewed by others
References
Weitzel, J, Maile, FJ, Kieser, M, Gabel, P, Pfaff, G, Special Effect Pigments. Vincentz Network, Hannover, 2008
Wißling, P, et al., Metallic Effect Pigments: Fundamentals and Applications. Vincentz Network, Hannover, 2006
Chorro, E, Perales, E, Martinez-Verdu, FM, Campos, J, Pons, A, “Colorimetric and Spectral Evaluation of the Optical Anisotropy of Metallic and Pearlescent Samples.” J. Mod. Opt., 56 1457–1465 (2009)
Kirchner, E, van den Kleboom, G-J, Njo, L, Super, R, Gottenbos, R, “Observation of Visual Texture of Metallic and Pearlescent Materials.” Color Res. Appl., 32 256–266 (2007)
Schwarz, S, Endriss, H, “Inorganic Colour Pigments and Effect Pigments—Technical and Environmental Aspects.” Color Technol., 25 6–17 (1995)
Germer, TA, Nadal, ME, “Modelling the Appearance of Special Effect Pigment Coatings.” Proc. SPIE, 4447 77–86 (2001)
Maile, FJ, Pfaff, G, Reynders, P, “Effect Pigments—Past, Present and Future.” Prog. Org. Coat., 54 150–163 (2005)
Debeljak, M, Hladnik, A, Cerne, L, Gregor-Svetec, D, “Use of Effect Pigments for Quality Enhancement of Offset Printed Specialty Papers.” Color Res. Appl., 38 168–176 (2013)
Gunde, MK, Kunaver, M, “Infrared Reflection—Absorption Spectra of Metal-Effect Coatings.” Appl. Spectrosc., 57 1266–1272 (2003)
Kerr, S, “Creating Special Effects in Plastics.” Plast. Addit. Compd., 8 40–43 (2006)
Maisch, R, Stahlecker, O, Kieser, M, “Mica Pigments in Solvent Free Coatings Systems.” Prog. Org. Coat., 27 145–152 (1996)
Tenorio Cavalcante, PM, Dondi, M, Guarini, G, Barros, FM, Benvindo da Luz, A, “Ceramic Application of Mica Titania Pearlescent Pigments.” Dyes Pigments, 74 1–8 (2007)
Bertaux, S, Reynders, P, Schweda, E, “The Reaction of Ceria Coatings on Mica with H2S: An In Situ X-ray Diffraction Study.” Mater. Res. Bull., 39 793–801 (2004)
Wissling, P, “State-of-the-Art Technology in Aluminium Pigments for Aqueous Paints.” Surf. Coat. Int., 82 335–336 (1999)
Egerton, TA, Purnama, H, “Does Hydrogen Peroxide Really Accelerate TiO2 UV-C Photocatalysed Decolouration of Azo-dyes Such as Reactive Orange 16?” Dyes Pigments, 101 280–285 (2014)
Allen, NS, Edge, M, Verran, J, Stratton, J, Maltby, J, Bygott, C, “Photocatalytic Titania Based Surfaces: Environmental Benefits.” Polym. Degrad. Stab., 93 1632–1646 (2008)
Eckart, “Speziell beschichtete Effektpigmente.” Technische Textilien, 56 64 (2013)
Shackleton, R, Wendon, G, “Developments in Metallic Pigments.” Pigment Resin Technol., 1 27–30 (1972)
Kim, TN, Feng, QL, Kim, JO, Wu, J, Wang, H, Chen, GC, Cui, FZ, “Antimicrobial Effects of Metal Ions (Ag+, Cu2+, Zn2+) in Hydroxyapatite.” J. Mater. Sci. Mater. Med., 9 129–134 (1998)
Tsukada, M, Arai, T, Colonna, GM, Boschi, A, Freddi, G, “Preparation of Metal-Containing Protein Fibers and Their Antimicrobial Properties.” J. Appl. Polym. Sci., 89 638–644 (2003)
Mahltig, B, Soltmann, U, Haase, H, “Modification of Algae with Zinc, Copper and Silver Ions for Usage as Natural Composite for Antibacterial Applications.” Mater. Sci. Eng. C, 33 979–983 (2013)
Sondi, I, Salopek-Sondi, B, “Silver Nanoparticles as Antimicrobial Agent.” J. Colloid Interface Sci., 275 177–182 (2004)
Kumar, R, Münstedt, H, “Silver Ion Release from Antimicrobial Polyamide/Silver Composites.” Biomaterials, 26 2081–2088 (2005)
Textor, T, Fouda, MMG, Mahltig, B, “Deposition of Durable Thin Silver Layers onto Polyamides Employing a Heterogeneous Tollen’s Reaction.” Appl. Surf. Sci., 256 2337–2342 (2010)
Mahltig, B, Fiedler, D, Fischer, A, Simon, P, “Antimicrobial Coatings on Textiles—Modification of Sol–Gel Layers with Organic and Inorganic Biocides.” J. Sol Gel. Sci. Technol., 55 269–277 (2010)
Mahltig, B, Haase, H, “Comparison of the Effectiveness of Different Silver-Containing Textile Products on Bacteria and Human Cells.” J. Text. Inst., 103 1262–1266 (2012)
Jiang, SX, Qin, WF, Guo, RH, Zhang, L, “Surface Functionalization of Nanostructured Silver-Coated Polyester Fabric by Magnetron Sputtering.” Surf. Coat. Technol., 204 3662–3667 (2010)
Mahltig, B, Cheval, N, Astachov, V, Malkoch, M, Montanez, MI, Haase, H, Fahmi, A, “Hydroxyl Functional Polyester Dendrimers as Stabilizing Agent for Preparation of Colloid Silver Particles—A Study in Respect to Antimicrobial Properties and Toxicity Against Human Cells.” Colloid Polym. Sci., 290 1413–1421 (2012)
Mahltig, B, Tatlises, B, Fahmi, A, Haase, H, “Dendrimer Stabilized Silver Particles for the Antimicrobial Finishing of Textiles.” J. Text. Inst., 104 1042–1048 (2013)
Alimonhammadi, F, Gashti, MP, Shamei, A, “A Novel Method for Coating of Carbon Nanotube on Cellulose Fiber Using 1,2,3,4-Butanetetracarboxylic Acid as a Cross-Linking Agent.” Prog. Org. Coat., 74 470–478 (2012)
Alimonhammadi, F, Gashti, MP, Shamei, A, “Functional Cellulose Fibers Via Polycarboxylic Acid/Carbon Nanotube Composite Coating.” J. Coat. Technol. Res., 10 123–132 (2013)
Deokar, AR, Lin, L-Y, Chang, C–C, Ling, Y-C, “Single-Walled Carbon Nanotube Coated Antibacterial Paper: Preparation and Mechanistic Study.” J. Mater. Chem. B, 1 2639–2646 (2013)
Hu, W, Peng, C, Luo, W, Lv, M, Li, X, Li, D, Huang, Q, Fan, C, “Graphene-Based Antibacterial Paper.” ACS Nano, 4 4317–4323 (2010)
Simoncic, B, Tomsic, B, “Structures of Novel Antimicrobial Agents for Textiles—A Review.” Text. Res. J., 80 1721–1737 (2010)
Höfer, D, “Antimicrobial Textiles, Skin-Borne Flora and Odour.” Curr. Probl. Dermatol., 33 67–77 (2006)
Ricci, G, Patrizi, A, Bellini, F, Medri, M, “Use of Textiles in Atopic Dermatitis.” Curr. Probl. Dermatol., 33 127–143 (2006)
Haug, S, Roll, A, Schmid-Grendelmeier, P, Johansen, P, Wüthrich, B, Kündig, TM, Senit, G, “Coated Textiles in the Treatment of Atopic Dermatitis.” Curr. Probl. Dermatol., 33 144–151 (2006)
Butterly, A, Schmidt, U, Wiener-Kronish, J, “Methicillin-Resistant Staphylococcus aureus Colonization, Its Relationship to Nosocomial Infection, and Efficacy of Control Methods.” Anesthesiology, 113 1453–1459 (2010)
Blaker, JJ, Nazhat, SN, Boccaccini, AR, “Development and Characterisation of Silver-Doped Bioactive Glass-Coated Sutures for Tissue Engineering and Wound Healing Applications.” Biomaterials, 25 1319–1329 (2004)
Yin, HQ, Langford, R, Burrell, RE, “Comparative Evaluation of the Antimicrobial Activity of ACTICOAT Antimicrobial Barrier Dressing.” J. Burn Care Res., 20 195–200 (1999)
Bertuleit, K, “Silver Coated Polyamide: A Conductive Fabric.” J. Coat. Fabr., 20 211–215 (1991)
Meoli, D, May-Plumlee, T, “Interactive Electronic Textile Development.” J. Text. Appar. Technol. Manag., 2 1–12 (2002)
Rizvi, SAH, Crown, EM, Osei-Ntiri, K, Smy, PR, Gonzalez, JA, “Electrostatic Characteristics of Thermal-Protective Garments at Low Humidity.” J. Text. Inst., 86 549–558 (1995)
Li, T–T, Wang, R, Lou, C-W, Lin, M-C, Lin, J-H, “Manufacture and Effectiveness Evaluations of High-Modulus Electromagnetic Interference Shielding/Puncture Resisting Composites.” Text. Res. J., 83 1796–1807 (2013)
Ceken, F, Kayacan, Ö, Özkurt, A, Ugurlu, SS, “The electromagnetic shielding properties of some conductive knitted fabrics produced on single or double needle bed of a flat knitting machine.” J. Text. Inst., 103 968–979 (2012)
Wieckowski, TW, Janukiewicz, JM, “Methods for Evaluating the Shielding Effectiveness of Textiles.” Fibers Text. East. Europe, 14 18–22 (2006)
Lee, CY, Lee, DE, Jeong, CK, Hong, YK, Shim, JH, Joo, J, Kim, MS, Lee, JY, Jeong, SH, Byun, SW, Zang, DS, Yang, HG, “Electromagnetic Interference Shielding by Using Conductive Polypyrrole and Metal Compound Coated on Fabrics.” Polym. Adv. Technol., 13 577–583 (2002)
Jiang, SX, Guo, RH, “Electromagnetic Shielding and Corrosion Resistance of Electroless Ni–P/Cu–Ni Multilayer Plated Polyester Fabric.” Surf. Coat. Technol., 205 4274–4279 (2011)
Gashti, MP, Almasian, A, Gashti, MP, “Preparation of Electromagnetic Reflective Wool Using Nano-ZrO2/Citric Acid as Inorganic/Organic Hybrid Coating.” Sens. Actuators, 187 1–9 (2012)
Al-Saleh, MH, Saadeh, WH, Sundararaj, U, “EMI Shielding Effectiveness of Carbon Based Nanostructured Polymeric Materials: A Comparative Study.” Carbon, 60 146–156 (2013)
Liang, J, Wang, Y, Huang, Y, Ma, Y, Liu, Z, Cai, J, Zhang, C, Gao, H, Chen, Y, “Electromagnetic Interference Shielding of Grapheme/Epoxy Composites.” Carbon, 47 922–925 (2009)
Wang, L-L, Tay, B-K, See, K-Y, Sun, Z, Tan, L-K, Lua, D, “Electromagnetic Interference Shielding Effectiveness of Carbon-Based Materials Prepared by Screen Printing.” Carbon, 47 1905–1910 (2009)
Wessling, B, Hiesgen, R, Meissner, D, “STM Investigations on Primary Particle Morphology of Polyaniline.” Acta Polym., 44 132–134 (1993)
Alam, J, Riaz, U, Ahmad, S, “High Performance Corrosion Resistant Polyaniline/Alkyd Ecofriendly Coatings.” Curr. Appl. Phys., 9 80–86 (2009)
Phang, SW, Tadokoro, M, Watanabe, J, Kuramoto, N, “Synthesis, Characterization and Microwave Absorption Property of Doped Polyaniline Nanocomposites Containing TiO2 Nanoparticles and Carbon Nanotubes.” Synth. Met., 158 251–258 (2008)
Biscaro, RS, Rezende, MC, Faez, R, “Reactive Doping of PAni-CSA and Its Use in Microwave Absorbing Materials.” Polym. Adv. Technol., 20 28–34 (2009)
Yan, J, Wei, T, Fan, Z, Qian, W, Zhang, M, Shen, X, Wei, F, “Preparation of Graphene Nanosheet/Carbon Nanotube/Polyaniline Composite as Electrode Material for Supercapacitors.” J. Power Sources, 195 3041–3046 (2010)
Ying, D, Li, J, Yang, X, “Polyaniline as Nonmetal Catalyst for Styrene Synthesis by Oxidative Dehydrogenation of Ethylbenzene.” Catal. Commun., 9 2331–2333 (2008)
Kaltenberg, J, Plum, L, Ober-Blöbaum, J, Hönscheidt, A, Rink, L, Haase, H, “Zinc Signals Promote IL-2-Dependent Proliferation of T Cells.” Eur. J. Immunol., 40 1496–1503 (2010)
Mahltig, B, Reibold, M, Gutmann, E, Textor, T, Gutmann, J, Haufe, H, Haase, H, “Preparation of Silver Nanoparticles Suitable for Textile Finishing Processes to Produce Textiles with Strong Antibacterial Properties Against Different Bacteria Types.” J. Chem. Sci., 66B 905–919 (2011)
Kirchner, E, “Film Shrinkage and Flake Orientation.” Prog. Org. Coat., 65 333–336 (2009)
Bhat, NV, Gore, AV, Nate, MM, Upadhyay, SS, “Development of Antistatic and Antibacterial Fabrics Using Novel Materials.” Bombay Text. Res., 36 1–6 (2006)
Seshadri, DT, Bhat, NV, “Use of Polyaniline as an Antimicrobial Agent in Textiles.” Indian J. Fibre Text. Res., 30 204–206 (2005)
Wallhäußer, KH, Praxis der Sterilisation Desinfektion-Konservierung. Georg Thieme Verlag, Stuttgart, 1995
Müller, B, Schubert, M, “Corrosion Inhibition of Copper and Brass Pigments in Aqueous Alkaline Media by Copolymers.” Prog. Org. Coat., 37 193–197 (1999)
Acknowledgments
For funding of the electromicroscopic equipment the authors acknowledge very gratefully the program FH-Basis of the German federal country North-Rhine-Westphalia NRW. For support of metallic effect pigments, the company Eckart GmbH is gratefully acknowledged and many thanks for helpful and interesting discussions are given to Dr. P. Wissling. All product and company names mentioned in this article may be trademarks of their respective owners, also without labeling. The results presented in the current paper are a part of a broader investigation of effect pigment coatings on textiles performed by Kristin Topp during her master thesis (University of Applied Sciences, Mönchengladbach, Germany, October 2013).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Topp, K., Haase, H., Degen, C. et al. Coatings with metallic effect pigments for antimicrobial and conductive coating of textiles with electromagnetic shielding properties. J Coat Technol Res 11, 943–957 (2014). https://doi.org/10.1007/s11998-014-9605-8
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11998-014-9605-8