Abstract
A novel low-temperature method is described for the direct synthesis of Fe2O3/mica pearlescent pigments with ferric chloride as a precursor and trace Fe(II) as a catalyst which does not require any calcination step. The as-synthesized pigments are characterized in detail by means of different techniques including X-ray diffraction, field emission scanning electron microscopy, energy dispersive spectroscopy, and colorimetry. The influence of various factors on the transformation from Fe(OH)3 coating layer to crystalline hematite coating layer is investigated, respectively. Furthermore, this paper studies several critical technological parameters pertaining to the influences on morphology and color properties of the pigments such as the coating temperature and the pH value.
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Knoth, M, Miehe, G, Fuess, H, “Characterization of Pearl Luster Pigments.” Adv. Eng. Mater., 7 928–931 (2005)
Cavalcante, PMT, Dondi, M, Guarini, G, Raimondo, M, Baldi, G, “Colour Performance of Ceramic Nano-pigments.” Dyes Pigments, 80 (2) 226–232 (2009)
Cho, JH, Lim, SH, “Internal Structure Analysis of Mica Particles Coated with Metal Oxide by Transmission Electron Microscopy.” Dyes Pigments, 69 (3) 192–195 (2006)
Maile, FJ, Pfaff, G, Reynders, P, “Effect Pigments: Past, Present and Future.” Prog. Org. Coat., 54 (3) 150–163 (2005)
Topuz, BB, Gündüz, G, Mavis, B, Çolak, Ü, “The Effect of Tin Dioxide (SnO2) on the Anatase–Rutile Phase Transformation of Titania (TiO2) in Mica–Titania Pigments and Their Use in Paint.” Dyes Pigments, 90 (2) 123–128 (2011)
Anselmann, R, “Nanoparticles and Nanolayers in Commercial Applications.” J. Nanopart. Res., 3 (4) 329–336 (2001)
Bertaux, S, Reynders, P, Heintz, JM, Lerch, M, “New (Oxy)nitride Pearlescent Pigments.” Mater. Sci. Eng. B, 121 (1–2) 137–144 (2005)
Pfaff, G, Reynders, P, “Angle-Dependent Optical Effects Deriving from Submicron Structures of Films and Pigments.” Chem. Rev., 99 (7) 1963–1981 (1999)
Tohidifar, MR, Taheri-Nassaj, E, Alizadeh, P, “Precursor Content Assessment and Its Influence on the Optical Interference of a Nano-sized Mica–Hematite Pearlescent Pigment.” Powder Technol., 204 (2–3) 194–197 (2010)
Ryu, YC, Kim, TG, Seo, GS, Park, JH, Suh, CS, Park, SS, et al., “Effect of Substrate on the Phase Transformation of TiO2 in Pearlescent Pigment.” J. Ind. Eng. Chem., 14 (2) 213–218 (2008)
Tohidifar, MR, Taheri-Nassaj, E, Alizadeh, P, “Optimization of the Synthesis of a Nano-sized Mica–Hematite Pearlescent Pigment.” Mater. Chem. Phys., 109 (1) 137–142 (2008)
Cavalcante, PMT, Dondi, M, Guarini, G, Barros, FM, Benvindo da Luz, A, “Ceramic Application of Mica Titania Pearlescent Pigments.” Dyes Pigments, 74 (1) 1–8 (2007)
Zhao, XW, Liu, ZB, Yang, H, Nagai, K, Zhao, YH, Gu, ZZ, “Uniformly Colorized Beads for Multiplex Immunoassay.” Chem. Mater., 18 (9) 2443–2449 (2006)
Linton, HR, “Nacreous Pigment Compositions.” US Patent 3,087,828, 1963
Linton, HR, “Micaceous Pigment Composition.” US Patent 3,087,829, 1963
Quinn, CA, Rieger, CJ, Bolomey, RA, “Method of Coating Surfaces with High Index Oxides.” US Patent 3,437,515, 1969
Kohlschütter, H, Getrost, H, Reich, W, Rossler, H, Horl, W, “Process for Coating Titanium Dioxide on Solid Materials.” US Patent 3,553,001, 1971
Bayat, N, Baghshahi, S, Alizadeh, P, “Synthesis of White Pearlescent Pigments Using the Surface Response Method of Statistical Analysis.” Ceram. Int., 34 (8) 2029–2035 (2008)
Pfaff, G, Gabel, P, Kieser, M, Maile, FJ, Joachim, W, Special Effect Pigments, 2nd ed. Hannover, Vincentz (2008)
Armanini, L, Bagala, F, “Iron Oxide Coated Mica Nacreous Pigments.” US Patent 4,146,403, 1979
Du, HY, Liu, CX, Sun, JY, Chen, QR, “An Investigation of Angle-Dependent Optical Properties of Multi-layer Structure Pigments Formed by Metal-Oxide-Coated Mica.” Powder Technol., 185 (3) 291–296 (2008)
Liu, H, Wang, GX, Park, J, Wang, JZ, Liu, HK, Zhang, C, “Electrochemical Performance of α-Fe2O3 Nanorods as Anode Material for Lithium-Ion Cells.” Electrochim. Acta, 54 (6) 1733–1736 (2009)
Tan, JR, Han, YF, Hou, WX, Chen, XZ, Fu, XS, “The Preparation and Characteristics of Cobalt Blue Mica Coated Titania Pearlescent Pigment.” Dyes Pigments, 52 (3) 215–222 (2002)
Tan, JR, Fu, XS, Hou, WX, Chen, XZ, Wang, L, “The Preparation and Characteristics of a Multi-cover-layer Type, Blue Mica Titania, Pearlescent Pigment.” Dyes Pigments, 56 (2) 93–98 (2003)
Jing, C, Shi, XB, Han, B, “The Preparation and Characteristics of Cobalt Blue Colored Mica Titania Pearlescent Pigment by Microemulsions.” Dyes Pigments, 75 (3) 766–769 (2007)
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The authors gratefully acknowledge financial support from the Natural Science Foundation of China (20671028), and thank Ouke Company for providing mica powder.
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Han, L., Chen, Y., You, M. et al. Catalytic synthesis of hematite–mica pearlescent pigments using a low-temperature method. J Coat Technol Res 9, 695–702 (2012). https://doi.org/10.1007/s11998-012-9419-5
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DOI: https://doi.org/10.1007/s11998-012-9419-5