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Photoelectrocatalysis performance of Se doped-TiO2/Ti nanotube arrays for visible-light-driven degradation of diazinon pesticide

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Abstract

The modification of ternary metal oxide to improve the photoelectrocatalysis (PEC) properties of TiO2 photocatalyst is a hot issue in environmental and resource applications. Herein, we present a novel photoelectrocatalytst of Se doped-TiO2/Ti nanotube arrays (Se@TiO2/Ti-NTAs) for high-efficiency degradation of diazinon pesticide. The Se@TiO2/Ti-NTAs were prepared to treat the TiO2-NTAs in Se-TiO2 sol-gel for 10 min, which was followed by calcination in air at 200 °C for 1 h. Optical absorption spectroscopy of the Se@TiO2/Ti-NTAs indicated that there is a red-shift in the optical energy gap to 2.95 eV if compared to the pristine TiO2/Ti NTAs, which suggests that the new photoelectrocatalyst is photoactive under visible light irradiation. We evaluated the photoactivity of the sample by using it as the photoelectrocatalyst in the degradation of diazinon pesticides under the PEC process. The results showed that the Se@TiO2/Ti-NTAs can degrade 95.62% for 1 h under visible light irradiation, which is equivalent to the degradation rate constant of 0.0183 s−1. For comparison, the pristine TiO2/Ti NTAs only degrades the diazinon as high as 87.65%, even then under UV light irradiation. Our result also indicated that the Se@TiO2/Ti-NTAs promote active photoelectron transfer and active radical formation, such as •OH and •O −2 , for rapid diazinon pesticide degradation. The Se@TiO2/Ti-NTAs photoelectrode should be a potential platform for environmental pollution treatment.

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Acknowledgement

We acknowledge the financial support from the Ministry of Education, Culture, Research and Technology of the Republic of Indonesia under the World Class Professor award grant no. 3252/E4/DT.04.03/2022.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Halu Oleo, Kendari, 93232 - Southeast Sulawesi, Indonesia

    Muhammad Nurdin, Abdul Haris Watoni, Muhammad Natsir, Sarifa Rahmatilah & Maulidiyah Maulidiyah

  2. Department of Environmental Engineering, Universitas Muhammadiyah Kendari, Kendari, 93127 - Southeast Sulawesi, Indonesia

    Muhammad Nurdin & Dwiprayogo Wibowo

  3. Department of Chemistry, Faculty of Science and Technology, Institut Sains Teknologi dan Kesehatan (ISTEK) ‘Aisyiyah Kendari, Kendari, 93116 - Southeast Sulawesi, Indonesia

    La Ode Agus Salim

  4. Institute of Microengineering and Nanoelectronics, Universiti Kebangsaan Malaysia, UKM Bangi, Bangi, 43600, Selangor, Malaysia

    Siti Naqiyah Sadikin & Akrajas Ali Umar

  5. Department of Chemistry, Faculty of Mathematics and Natural Sciences, Pattimura University, Ambon, 97233 - Maluku, Indonesia

    Catherina Manukpadang Bijang

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  1. Muhammad Nurdin
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  2. Abdul Haris Watoni
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Nurdin, M., Watoni, A.H., Natsir, M. et al. Photoelectrocatalysis performance of Se doped-TiO2/Ti nanotube arrays for visible-light-driven degradation of diazinon pesticide. Korean J. Chem. Eng. 40, 2209–2218 (2023). https://doi.org/10.1007/s11814-023-1395-1

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