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Effects of Ni–TiO2 Pillared Clay–Montmorillonite Composites for Photocatalytic Enhancement Against Reactive Orange Under Visible Light

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Abstract

In this study, a composite material based on Ni–TiO2 Pillared Clay-Montmorillonite (Ni–TiO2/CMMT) was synthesized using the sol–gel method at room temperature and studied its photocatalytic performance under visible light irradiation for dye removal of Orange Reactive 84 (RO 84). The photocatalytic parameters studied were the effect of pH, contact time, mass of composite and the amount of Ni–TiO2/CMMT. SEM–EDS analysis showed that the composite surface consisted of aggregates with a small particle size of about 0.28 µm. Other results showed that the main chemical elements of the composite are Si, Al, O, C, Na, Ni and Ti. This was confirmed by the results of FTIR analysis which showed specific absorption for the Si–O–Si, Si–O–Al, Al–OH, Ti–O and Ni–O groups. Another characteristic of the compositing components was the band gap value of 2.91 eV which can be active in visible light irradiation. Based on the photocatalyst performance test, the composite significantly reduced the amount of RO 84 dye. The optimum pH obtained in this test was acidic (pH 5), with a color change efficiency of 63.66% for a contact time of 45 min.

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Acknowledgement

This work was supported by Ministry of research and technology/Research and Innovation National Agency of Indonesia under research Grant No. 171/SP2H/AMD/LT/DRPM/2020 and we grateful for Titania Research Group on implementation this research.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Mathematics and Natural Science, Universitas Halu Oleo, Jl. HEA Mokodompit Kampus Baru, Kendari, 93231, Southeast Sulawesi, Indonesia

    Muhammad Natsir, Yulianti Ika Putri, Maulidiyah Maulidiyah, La Ode Agus Salim, Thamrin Azis, Irwan Irwan & Muhammad Nurdin

  2. Department of Environmental Engineering, Faculty of Engineering, Universitas Muhammadiyah Kendari, Jl. KH. Ahmad Dahlan, Kendari, 93117, Southeast Sulawesi, Indonesia

    Dwiprayogo Wibowo

  3. Department of Chemistry, Faculty of Mathematics and Natural Sciences, Jl. Ir. M. Putuhena, Universitas Pattimura, Ambon, Maluku, Indonesia

    Catherina M. Bijang

  4. Department of Aquaculture, Faculty of Science and Technology, Institut Teknologi Dan Kesehatan Avicenna, Jl. Y. Wayong Lepo-Lepo, Kendari, 93117, Southeast Sulawesi, Indonesia

    Faizal Mustapa

  5. Department of Mathematics and Natural Sciences, Faculty of Tarbiyah, Institut Agama Islam Negeri (IAIN), Kendari, 93563, Southeast Sulawesi, Indonesia

    Zul Arham

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  1. Muhammad Natsir
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Natsir, M., Putri, Y.I., Wibowo, D. et al. Effects of Ni–TiO2 Pillared Clay–Montmorillonite Composites for Photocatalytic Enhancement Against Reactive Orange Under Visible Light. J Inorg Organomet Polym 31, 3378–3388 (2021). https://doi.org/10.1007/s10904-021-01980-9

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