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Kinetic and thermodynamic evaluation of pyrolysis of jeans waste via coats-redfern method

  • Environmental Engineering
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Abstract

Used textiles, such as jeans wastes, exhibit a high potential for generating renewable and sustainable energy. However, limited research has been devoted toward investigating the kinetic and thermodynamic parameters of textile wastes during pyrolysis and applying these wastes as feedstock for fuels such as biogas. Therefore, this study investigated the kinetic and thermodynamic aspects of the thermal decomposition of jeans waste to evaluate its potential for sustainable energy production. Jeans waste was heat treated at 50–850 °C under different heating rates of 10–40 °C min−1. Active pyrolysis for the decomposition of jeans waste occurred at temperatures ranging from 250 to 550 °C. Specific Coats-Redfern-type reaction mechanisms were applied to determine the kinetic and thermodynamic variables in the active temperature zone. The thermodynamic parameters (ΔH and ΔG) and activation energies increased when the heating rate was increased from 10 to 30 °C min−1. When the heating rate was further increased to 40 °C min−1, ΔH, ΔG, and the activation energies decreased. For heating rates of 10, 20, 30, and 40 °C min−1, the pre-exponential factors varied in the ranges of 7.4×103 to 1.4×104, 1.8×104 to 5.1×1010, 2.8×104 to 5.3×1010, and 3.6×104 to 3.1×1010 min−1, respectively. In each reaction mechanism model, the entropy changed negatively for all the heating rates examined in this study. This work and its results could serve as a guide for implementing such pyrolysis processes for textile wastes at a practical scale for bioenergy applications.

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References

  1. F. A. Brones, M. M. Carvalho and E. S. Zancul, J. Clean. Prod., 142, 8 (2017).

    Article  Google Scholar 

  2. H. Rezk, A. M. Nassef, A. Inayat, E. T. Sayed, M. Shahbaz and A. G. Olabi, Sci. Total Environ., 658, 1150 (2019).

    Article  Google Scholar 

  3. S. A. Sarkodie and V. Strezov, Sci. Total Environ., 639, 888 (2018).

    Article  Google Scholar 

  4. M. Nazar, A. Yasar, S. A. Raza, A. Ahmad, R. Rasheed, M. Shahbaz and A. B. Tabinda, Biomass Convers. Biorefin., 11, 1 (2021).

    Article  Google Scholar 

  5. J.-M. Ha, K.-R. Hwang, Y.-M. Kim, J. Jae, K. H. Kim, H. W. Lee, J.-Y. Kim and Y.-K. Park, Renew. Sust. Energ. Rev., 111, 422 (2019).

    Article  Google Scholar 

  6. S. Oh, J. Lee, S. S. Lam, E. E. Kwon, J.-M. Ha, D. C. W. Tsang, Y. S. Ok, W-H. Chen and Y.-K. Park, Bioresour. Technol., 342, 126067 (2021).

    Article  Google Scholar 

  7. M. Shahbaz, A. AlNouss, P. Parthasarathy, A. H. Abdelaal, H. Mackey, G. McKay and T. Al-Ansari, Biomass Convers. Biorefin., 12, 669 (2020).

    Article  Google Scholar 

  8. S. Polat and P. Sayan, Energ. Source. Part A., 42, 1 (2020).

    Article  Google Scholar 

  9. J.-Y. Kim, H. W. Lee, S. M. Lee, J. Jae and Y.-K. Park, Bioresour. Technol., 279, 373 (2019).

    Article  Google Scholar 

  10. J. Lee, E. E. Kwon, S. S. Lam, W.-H. Chen, J. Rinklebe and Y.-K. Park, J. Clean. Prod., 321, 128989 (2021).

    Article  Google Scholar 

  11. C. Park and J. Lee, Int. J. Energy Res., 45, 13088 (2021).

    Article  Google Scholar 

  12. L. J. R. Nunes, R. Godina, J. C. O. Matias and J. P. S. Catalão, J. Clean. Prod., 171, 1353 (2018).

    Article  Google Scholar 

  13. M. del Mar Barbero-Barrera, O. Pombo and M. de los Angeles Navacerrada, Compos. B. Eng., 94, 26 (2016).

    Article  Google Scholar 

  14. R. Paul, Denim, Woodhead Publishing, United Kingdom (2015).

  15. X. Meng, W. Fan, Y. Ma, T. Wei, H. Dou, X. Yang, H. Tian, Y. Yu, T. Zhang and L. Gao, Text. Res. J., 90, 695 (2020).

    Article  Google Scholar 

  16. P. Peña-Pichardo, G. Martínez-Barrera, M. Martínez-López, F. Ureña-Núñez and J. M. L. dos Reis, Constr. Build. Mater., 177, 409 (2018).

    Article  Google Scholar 

  17. H. Dahlbo, K. Aalto, H. Eskelinen and H. Salmenperä, Sustain. Prod. Consum., 9, 44 (2017).

    Article  Google Scholar 

  18. C. Wen, Y. Wu, X. Chen, G. Jiang and D. Liu, J. Therm. Anal. Calorim., 128, 581 (2017).

    Article  Google Scholar 

  19. A. Hanoğlu, A. Çay and J. Yanik, Energy J., 166, 664 (2019).

    Article  Google Scholar 

  20. X. Chen, Y. Chen, H. Yang, W. Chen, X. Wang and H. Chen, Bioresour. Technol., 233, 15 (2017).

    Article  Google Scholar 

  21. M. W. Seo, S. H. Lee, H. Nam, D. Lee, D. Tokmurzin, S. Wang and Y.-K. Park, Bioresour. Technol., 343, 126109 (2022).

    Article  Google Scholar 

  22. S. Jung, N. P. Shetti, K. R. Reddy, M. N. Nadagouda, Y.-K. Park, T. M. Aminabhavi and E. E. Kwon, Energy Convers. Manag., 236, 114038 (2021).

    Article  Google Scholar 

  23. Q. T. Trinh, A. Banerjee, K. B. Ansari, D. Q. Dao, A. Drif, N. T. Binh, D. T. Tung, P. M. Q. Binh, P. N. Amaniampong and P. T. Huyen, Biorefinery of alternative resources: Targeting green fuels and platform chemicals, Springer, Singapore (2020).

    Google Scholar 

  24. S. R. Naqvi, R. Tariq, Z. Hameed, I. Ali, S. A. Taqvi, M. Naqvi, M. B. K. Niazi, T. Noor and W. Farooq, Fuel, 233, 529 (2018).

    Article  Google Scholar 

  25. S. Yousef, M. Tatariants, M. Tichonovas, Z. Sarwar, I. Jonuškienė and L. Kliucininkas, Resour. Conserv. Recycl., 145, 359 (2019).

    Article  Google Scholar 

  26. J. Lee, E. E. Kwon and Y.-K. Park, Catal. Today, 355, 263 (2020).

    Article  Google Scholar 

  27. Y.-M. Kim, J. Jae, B.-S. Kim, Y. Hong, S.-C. Jung and Y.-K. Park, Energy Convers. Manag., 149, 966 (2017).

    Article  Google Scholar 

  28. S. Valizadeh, S. S. Lam, C. H. Ko, S. H. Lee, A. Farooq, Y. J. Yu, J.-K. Jeon, S.-C. Jung, G. H. Rhee and Y.-K. Park, Bioresour. Technol., 320, 124313 (2021).

    Article  Google Scholar 

  29. S. Valizadeh, S.-H. Jang, G. Hoon Rhee, J. Lee, P. Loke Show, M. Ali Khan, B.-H. Jeon, K.-Y. Andrew Lin, C. Hyun Ko, W.-H. Chen and Y.-K. Park, Chem. Eng. J., 433, 133793 (2022).

    Article  Google Scholar 

  30. D. Zeng, S. Wang, J. Peng, Y. Gui, H. Liu, F. Yang and M. Li, ChemistrySelect, 4, 7649 (2019).

    Article  Google Scholar 

  31. S. Yousef, J. Eimontas, N. Striūgas, M. Tatariants, M. A. Abdelnaby, S. Tuckute and L. Kliucininkas, Energy Convers. Manag., 196, 688 (2019).

    Article  Google Scholar 

  32. S. R. Naqvi, R. Tariq, Z. Hameed, I. Ali, M. Naqvi, W.-H. Chen, S. Ceylan, H. Rashid, J. Ahmad and S. A. Taqvi, Renew. Energy, 131, 854 (2019).

    Article  Google Scholar 

  33. G. Mishra, J. Kumar and T. Bhaskar, Bioresour. Technol., 182, 282 (2015).

    Article  Google Scholar 

  34. S. R. Naqvi, Z. Hameed, R. Tariq, S. A. Taqvi, I. Ali, M. B. K. Niazi, T. Noor, A. Hussain, N. Iqbal and M. Shahbaz, J. Waste Manag., 85, 131 (2019).

    Article  Google Scholar 

  35. K. A. Motghare, A. P. Rathod, K. L. Wasewar and N. K. Labhsetwar, J. Waste Manag., 47, 40 (2016).

    Article  Google Scholar 

  36. D. Yoon, K. Y. Chung, W. Chang, S. M. Kim, M. J. Lee, Z. Lee and J. Kim, Chem. Mater., 27, 266 (2015).

    Article  Google Scholar 

  37. T. Szabó, O. Berkesi, P. Forgó, K. Josepovits, Y. Sanakis, D. Petridis and I. Dékány, Chem. Mater., 18, 2740 (2006).

    Article  Google Scholar 

  38. A. Islam, Y. Molla, T. K. Dey, M. Jamal, R. Rathanasamy and M. Uddin, J. Polym. Res., 28, 1 (2021).

    Article  Google Scholar 

  39. D. Zhao, K. Chen, F. Yang, G. Feng, Y. Sun and Y. Dai, Cellulose, 20, 3205 (2013).

    Article  Google Scholar 

  40. S. Yousef, M. Tatariants, M. Tichonovas, L. Kliucininkas, S.-I. Lukošiūtė and L. Yan, J. Clean. Prod., 254, 120078 (2020).

    Article  Google Scholar 

  41. Z. Akyürek, Sustainability, 11, 2280 (2019).

    Article  Google Scholar 

  42. A. Skreiberg, Ø. Skreiberg, J. Sandquist and L. Sørum, Fuel, 90, 2182 (2011).

    Article  Google Scholar 

  43. X. Yang, Y. Zhao, R. Li, Y. Wu and M. Yang, Thermochim. Acta, 665, 20 (2018).

    Article  Google Scholar 

  44. W.-H. Chen, C. F. Eng., Y.-Y. Lin and Q.-V. Bach, Energy Convers. Manag., 221, 113165 (2020).

    Article  Google Scholar 

  45. A. Zaker, Z. Chen, M. Zaheer-Uddin and J. Guo, J. Environ. Chem. Eng., 9, 104554 (2021).

    Article  Google Scholar 

  46. G. Xia, W. Han, Z. Xu, J. Zhang, F. Kong, J. Zhang, X. Zhang and F. Jia, J. Environ. Chem. Eng., 9, 106182 (2021).

    Article  Google Scholar 

  47. V. Balasundram, N. Ibrahim, R. M. Kasmani, M. K. A. Hamid, R. Isha, H. Hasbullah and R. R. Ali, J. Clean. Prod., 167, 218 (2017).

    Article  Google Scholar 

  48. X. Yuan, T. He, H. Cao and Q. Yuan, Renew. Energy, 107, 489 (2017).

    Article  Google Scholar 

  49. S. C. Turmanova, S. D. Genieva, A. S. Dimitrova and L. T. Vlaev, Express Polym. Lett., 2, 133 (2008).

    Article  Google Scholar 

  50. A. C. M. Loy, D. K. W. Gan, S. Yusup, B. L. F. Chin, M. K. Lam, M. Shahbaz, P. Unrean, M. N. Acda and E. Rianawati, Bioresour. Technol., 261, 213 (2018).

    Article  Google Scholar 

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Acknowledgements

The authors would like to thank the University of the Punjab, Lahore, Pakistan, and Hamad bin Khalifa University, Qatar, for financial and technical assistance for this study. Additional support from the Korea Institute of Energy Technology Evaluation and Planning (KETEP) granted financial resource from the Ministry of Trade, Industry & Energy (MOTIE), Republic of Korea (No. 2021010000001B) was also appreciated.

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Authors and Affiliations

  1. School of Engineering, Monash University Malaysia, 47500, Bandar Sunway, Malaysia

    Rumaisa Tariq

  2. Department of Sustainable and Renewable Energy Engineering, University of Sharjah, 27272, Sharjah, United Arab Emirates

    Abrar Inayat & Chaouki Ghenai

  3. Division of Sustainable Development, College of Science and Engineering, Hamad Bin Khalifa University (HBKU), Qatar Foundation, 5825, Doha, Qatar

    Muhammad Shahbaz & Tareq Al-Ansari

  4. Institute of Energy and Environmental Engineering, University of the Punjab, Q&A Campus, Lahore, Pakistan

    Hassan Zeb

  5. SKKU Advanced Institute of Nanotechnology (SAINT), Sungkyunkwan University, 2066 Seobu-ro, Jangan-gu, Suwon, Gyeong Gi-do, 16419, Korea

    Jaehoon Kim

  6. School of Mechanical Engineering, Sungkyunkwan University, 2066 Seobu-ro, Jangan-gu, Suwon, Gyeong Gi-do, 16419, Korea

    Jaehoon Kim

  7. School of Chemical Engineering, Sungkyunkwan University, 2066 Seobu-ro, Jangan-gu, Suwon, Gyeong Gi-do, 16419, Korea

    Jaehoon Kim

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  1. Rumaisa Tariq
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  2. Abrar Inayat
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Correspondence to Hassan Zeb or Jaehoon Kim.

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Tariq, R., Inayat, A., Shahbaz, M. et al. Kinetic and thermodynamic evaluation of pyrolysis of jeans waste via coats-redfern method. Korean J. Chem. Eng. 40, 155–161 (2023). https://doi.org/10.1007/s11814-022-1248-3

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  • DOI: https://doi.org/10.1007/s11814-022-1248-3

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