Abstract
Aging precipitation and solid solution heat treatment were carried out on three steels which have chromium content of 18%, manganese content of 12%, 15%, 18%, and nitrogen content of 0.43%, 0.53%, 0.67%, respectively. The mechanisms of precipitation and solid solution of high nitrogen austenitic stainless steel were studied using the scanning electron microscopy, transmission electron microscopy, electron probe micro analysis and mechanical testing. The results show that, Cr2N is the primary precipitate in the tested stainless steels instead of Cr23C6. Cr2N nucleates at austenitic grain boundaries and grows towards inner grains with a lamellar morphology. By means of pre-precipitation of Cr2N at 800 °C, the microstructure of the steels at solid solution state can be refined, thus improving the strength and plasticity. After the proposed treatment, the tensile strength, the proof strength and the elongation of the tested steel reach 881 MPa, 542 MPa and 54%, respectively.
Similar content being viewed by others
References
LIU Zhi-hong, MA Xiao-bo, ZHU De-qing, LI Yu-hu, LI Qi-hou. Preparation of ferronickel from laterite ore in reduction smelting process [J]. Journal of Central South University: Science and Technolog, 2011, 42(10): 2905–2910. (in Chinese)
ROKANOPOULOU A, PAPADIMITRIOU G D. Production of high nitrogen surfaces on 2205 duplex stainless steel substrate using the PTA technique [J]. Materials Science and Technology, 2011, 27(9): 1391–1398.
YANG Ke, REN Yi-bin. Nickel-free austenitic stainless steels for medical applications [J]. Science and Technology of Advanced Materials, 2010, 11(1): 1–13.
WAN Peng, REN Yi-bin, ZHENG Bing-chun, YANG Ke. Analysis of magnetism in high nitrogen austenitic stainless steel and its elimination by high temperature gas nitriding [J]. J Mater Sci Tech., 2011, 27(12): 1139–1142.
PARK W I, JUNG S M, SASAKI Y. Fabrication of ultra high nitrogen austenitic stainless steel by NH3 solution nitriding [J]. ISIJ International, 2010, 50(11): 1546–1551.
HONG C M, SHI J, SHENG LY, CAO W C, HUI W J, DONG H. Effects of hot-working parameters on microstructural evolution of high nitrogen austenitic stainless steel [J]. Materials & Design, 2011, 32(7): 3711–3717.
LI Ji-chao, CHU Shao-jun. Effect of sampling methods on N detection in high nitrogen steel [J]. Steel Research International, 2011, 82(11): 1273–1277.
BAI Guang-hai, LI Jin-shan, HU Rui. Effect of thermal exposure on the stability of carbides in Ni-Cr-W based superalloy [J]. Materials Science and Engineering A, 2011, 528: 2339–2344.
CAROSI A, AMATI M, GREGORATTI L, KACIULIS S, MEZZI A, MONTANARI R, ROVATTI L, UCCIARDELLO N. Heating modification of an austenitic steel with high-nitrogen content [J]. Surface and Interface Analysis, 2010, 42(6/7): 726–729.
van der SCHAEVE F, TAILLARD R, FOCT J. Discontinuous precipitation of Cr2N in a high nitrogen, chromium-manganese austenitic stainless steel [J]. Materials Science, 1995, 30: 6035–6045.
LEE T H, KIM S J, JUNG Y C. Crystallographic details of precipitates in Fe-22Cr-21Ni-6Mo-(N) superaustenitic stainless steels aged at 900 °C [J]. Metallurgical and Materials Transactions A, 2000, 31(7): 1713–1718.
BLINOV V M, BOTVINA L P, TYUTIN M P, BLINOV E V, MUSHNIKOVA S Y and ZHARKOVA N A. Effect of heat treatment on the fracture toughness of hot-rolled corrosion-resistant austenitic high-nitrogen 0.4Cr20Ni6Mn11Mo2N0.5 steel [J]. Russian Metallurgy (Metally), 2011 (9): 831–836.
BRIANT C L, HALL E L. A comparison between grain boundary chromium depletion in austenitic stainless steel and corrosion in the modified Strauss test [J]. Corrosion, 1986, 42(9): 522–531.
BRIANT C L. Nitrogen segregation to grain boundaries in austenitic stainless steel [J]. Scripta Metallurgica, 1987, 21(1): 71–74.
BABA H, KATADA Y. Effect of nitrogen on crevice corrosion in austenitic stainless steel [J]. Corrosion Science, 2006, 48(9): 2510–2524.
BABA H, KODAMA T, KATADA Y. Role of nitrogen on the corrosion behavior of austenitic stainless steel [J]. Corrosion Science, 2002, 44(1): 2393–2407.
HU De-lin, LIU Zhi-en. Research on the migration of austenite grain boundary [J]. Acta Metallurgica Sinica, 1986, 22(4): 58–62 (in Chinese)
WANG Kun-lin. Fundamentals of materials engineering [M]. Beijing: Tsinghua University Press, 2009: 116–117. (in Chinese)
Author information
Authors and Affiliations
Corresponding author
Additional information
Foundation item: Project(50974014) supported by the National Natural Science Foundation of China
Rights and permissions
About this article
Cite this article
Li, Jy., Liu, Hn. & Huang, Pw. Effects of pre-precipitation of Cr2N on microstructures and properties of high nitrogen stainless steel. J. Cent. South Univ. Technol. 19, 1189–1195 (2012). https://doi.org/10.1007/s11771-012-1127-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11771-012-1127-x