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The Al-Rich Part of the Fe-Al Phase Diagram


The Al-rich part of the Fe-Al phase diagram between 50 and 80 at.% Al including the complex intermetallic phases Fe5Al8 (ε), FeAl2, Fe2Al5, and Fe4Al13 was re-investigated in detail. A series of 19 alloys was produced and heat-treated at temperatures in the range from 600 to 1100 °C for up to 5000 h. The obtained data were further complemented by results from a number of diffusion couples, which helped to determine the homogeneity ranges of the phases FeAl2, Fe2Al5, and Fe4Al13. All microstructures were inspected by scanning electron microscopy (SEM), and chemical compositions of the equilibrium phases as well as of the alloys were obtained by electron probe microanalysis (EPMA). Crystal structures and the variation of the lattice parameters were studied by x-ray diffraction (XRD) and differential thermal analysis (DTA) was applied to measure all types of transition temperatures. From these results, a revised version of the Al-rich part of the phase diagram was constructed.

Introduction and Literature Review

Many investigations were done in the Fe-Al system since the 1920s regarding its capability as a replacement for steels due to the outstanding oxidation resistance at high temperatures and to the low density of Fe-Al based alloys.[1-3] These properties, which should improve with increasing Al content, strongly contribute to its candidate role as a high temperature structural material. However, the Al-rich part of the Fe-Al phase diagram with >50 at.% Al has not yet been finally determined. Five different intermetallic phases were identified by previous studies in this composition range, and their crystal structure details are listed in Table 1. The FeAl phase has a simple cubic (B2-type) crystal structure, whereas the Al-rich intermetallic phases FeAl2, Fe2Al5, and Fe4Al13 have complex structures of the triclinic, orthorhombic and monoclinic type, respectively.Footnote 1 The high-temperature phase Fe5Al8, which was designated only as ε phase in the literature due to its for long time unknown structure, decomposes on cooling in a rapid eutectoid reaction and cannot be quenched to room temperature. Therefore, its crystal structure was determined only recently and was found to be of the body-centered cubic Cu5Zn8 type.[5,6]

Table 1 Intermetallic phases and their crystal structures

The equilibrium diagram of the Fe-Al system in the range between 50 and 100 at.% Al was initially studied already in the 20s and 30s of the last century.[11-17] During the following about 80 years, only comparatively few more data were published contributing to this part of the phase diagram.[18-24] All available information was carefully assessed by Kubaschewski[25] and later on in the comprehensive overview of Kattner and Burton[26] that provides the most commonly used version of the Fe-Al phase diagram. More recent assessments of the experimental data were published by Burkhardt et al.[27] (however not containing a plotted phase diagram) and, most recently, by Turchanin et al.[28] The phase diagram in the latter publication is qualitatively identical to the version of Kattner and Burton, but some invariant reaction temperatures were corrected using DTA results provided by Stein and Palm.[29]

Figure 1(a) shows the Al-rich Fe-Al phase diagram as assessed by Kattner and Burton[26] including all relevant experimental data from the literature, and Fig. 1(b) presents a magnification of the high-temperature part of the diagram in the range between 50 and 90 at.% Al clearly revealing a strong scatter of the experimental data. This applies to the liquidus and all invariant reaction temperatures as well as to the homogeneity ranges of all occurring intermetallic phases as is briefly described in the following:

Fig. 1
figure 1

(a) Experimental data from the literature[12-15,18,20,21,23-25,29] and evaluated Al-rich Fe-Al phase diagram from Kattner and Burton[26] (solid and dashed lines) (b) magnification of the high-temperature part between 50-90 at.% Al

There is general agreement in the literature that the high-temperature phase Fe5Al8 forms peritectically from the liquid and FeAl and decomposes by a eutectoid reaction into FeAl and FeAl2. The literature values obtained from thermal analysis for the reaction temperatures vary strongly ranging from 1207 to 1232 °C for the peritectic reaction and from 1080 to 1103 °C for the eutectoid reaction.[13,14,16,19,21,29] This significant scatter in the invariant reaction temperatures is also reflected in the differing values reported in the four assessments,[25-28] see Table 2. For comparison, also calculated data from thermodynamic modelling applying the CALPHAD approach are given (Table 3).[30-33]

Table 2 Invariant reaction temperatures in the Al-rich part of the Fe-Al system as assessed from the available literature data[25-28]
Table 3 Invariant reaction temperatures in the Al-rich part of the Fe-Al system as obtained from thermodynamic modelling based on the CALPHAD approach[30-33]

Fe5Al8 and Fe2Al5 form a eutectic at 68-69 at.% Al and at a temperature in the range 1153 °C[15] to 1166 °C.[14] Only few degrees below this temperature, FeAl2 forms in a peritectoid reaction from the phases Fe5Al8 and Fe2Al5. The scatter in the reported experimental reaction temperatures is similar as above, but the temperature interval between these two reactions is always about 10 °C (see also Table 2). This is worth to be mentioned because this finding is quite different from results of thermodynamic modelling, which in all cases give a much smaller interval of only 1-2 °C (see Table 3 listing calculated reaction temperatures).

There is some controversy in the literature about the reaction type of the formation of Fe4Al13. The question is whether the phase forms peritectically (L + Fe2Al5 ↔ Fe4Al13)[15,21] or congruently from the melt (L ↔ Fe4Al13).[14,19,22] Most of the assessments tend to the peritectic version (see e.g. Tables 2 and 3). In any case, the respective peritectic/eutectic composition will be very near to that of the melting point of Fe4Al13., as is also indicated in Kattner and Burton’s version, see Fig. 1(b).

Information about the homogeneity ranges of the different phases is only very scarce in the literature. For the high-temperature phase Fe5Al8, Kattner and Burton[26] estimate a composition range from ≈58 to ≈65 at.% Al. The homogeneity ranges of the Al-richer phases FeAl2, Fe2Al5, and Fe4Al13 are much smaller. In Kattner and Burton’s assessment, widths of 0.9 at.% (66.0 to 66.9 at.% Al), 3 at.% (70 to 73 at.% Al), and 2.1 at.% (74.5 to 76.6 at.% Al), respectively, are reported.[26] In a more recent study on the Fe-Al-Zr phase diagram,[34] values of 1.8, 2.2, 0.7 at.% were given for the widths of the homogeneity ranges of these intermetallic compounds at 1000 °C.

Summarizing the above and having in mind that several lines in the Al-rich part of the Fe-Al phase diagram are still drawn as dotted lines today, it can be stated that this part of the Fe-Al system deserves more detailed investigations. Therefore, in the present work a series of Fe-Al alloys with 57 to 79 at.% Al was produced and measured by DTA to obtain all reaction temperatures. Selected alloys were heat-treated in the range from 600 to 1100 °C for up to 5000 h to study the resulting microstructures and phase equilibria by SEM and EPMA. In addition, a number of diffusion couples made of Fe-50Al (alloy compositions are given in at.% throughout this paper) and pure Al were produced to get further information about the homogeneity ranges of FeAl2, Fe2Al5 and Fe4Al13 phases. Crystal structures and lattice parameter variations were studied by XRD. By combining all experimental results, a revised phase diagram was finally constructed.


A series of Fe-Al binary alloys with nominal compositions between 57 and 79 at.% Al was produced from high purity Fe (99.98 wt.%) and Al (99.99 wt.%) by vacuum induction melting or levitation melting with casting into a cold copper mould, or by arc melting (Table 4). In all cases, these processes were performed in pure argon. EPMA was applied to determine the actual chemical compositions of all alloys. The analyzed compositions, which are listed in Table 4, were found to agree with the nominal compositions within 1.0 at.% Al. Pieces of each alloy were cut by electrical discharge machining (EDM) and encapsulated in quartz tubes back-filled with argon and were heat-treated at different temperatures for times as given in Table 4. Besides the series of cast alloys, three diffusion couples between an Fe-50Al alloy and pure Al were prepared and heat-treated at 620 °C (solid-solid diffusion couple), 800 and 850 °C (solid-liquid diffusion couples) in an Ar atmosphere. The first diffusion couple consisted of 5 × 5 × 10 mm3 cuboid shaped parts which were connected to each other directly with light pressure by using Mo clamps. The second diffusion couple was made of one pure Al cylinder of 8 mm in diameter and 8 mm in height, which was pressed in a cylinder-shaped hole with the same dimensions in a block of Fe-50Al alloy. The whole assembly was covered with a 5 mm thick lid made of the Fe-50Al alloy, placed in an alumina crucible, and completely covered with alumina powder. On top of the alumina powder, some Ti filings were added as an oxygen getter. The third diffusion couple was made of two cylinders of pure Al and Fe-50Al alloy (both 18 mm in diameter and 10 mm in height) with the Fe-50Al cylinder placed on top of the pure Al piece inside an alumina crucible. Again this diffusion couple was covered with alumina powder and Ti filings were used as getter material. All diffusion couples were furnace-cooled. More information on heat treatment times and observed phase layers is given in Table 5.

Table 4 Analyzed compositions (EPMA), type of melting and conditions and phases of the investigated Fe-Al samples (VIM: vacuum induction melting, LM: levitation melting, AM: arc melting)
Table 5 Solid-solid and solid-liquid Fe-50Al/Al diffusion couples and observed phase layers

Microstructures were studied by scanning electron microscopy (SEM) using a JEOL-6490 instrument with a working distance of 10 mm. Chemical compositions of individual phases were established by wavelength dispersive spectrometry (WDS) carried out on an EPMA JEOL JXA-8100. The instrument was operated at 15 kV and 20 nA. The pure elements were used as standards. Crystal structures of the phases were identified by XRD of powdered samples, which were easily obtained by crushing in a steel mortar. On a Seifert ID 3003 x-ray diffraction instrument, the 2θ range from 20° to 130° was scanned using Co-Kα1 radiation (λ = 0.17890 nm). The program CaRine Crystallography 3.1 (Divergent S.A., Compiègne, France) was used to calculate theoretical XRD patterns in order to compare them with the experimental results, and lattice parameters were refined by using the least-squares fitting software LCLSQ 8.5 (C.W. Burnham, Harvard University, 1993). DTA was performed on a Setaram SETSYS-18 instrument. Cylindrical samples with 3 mm in diameter and 3 mm in height were placed into alumina crucibles and heated under argon at rates of 1, 5, and 10 °C/min. The accuracy of the temperature calibration is ±1 °C. Each sample was heated and cooled at least twice to check the reproducibility of the results.

Results and Discussion

Stability and Homogeneity Range of the High-Temperature Phase Fe5Al8 (ε Phase)

Three representative microstructures of as-cast alloys with compositions in the range of the Fe5Al8 phase are shown in Fig. 2. The dependence of the as-cast microstructures on the Al content in this composition range was already described in our previous paper.[35] The alloys consist of the phases FeAl and FeAl2 and contain a fine-scaled lamellar matrix of these two phases as a result of the rapid eutectoid decomposition of Fe5Al8 phase during cooling.[5] Alloys with less Al than the eutectoid value additionally contain (pre-eutectoid) FeAl particles (Fig. 2a), while alloys with Al contents above this limit show certain amounts of FeAl2 (Fig. 2c). As-cast Fe-60.9Al shows a fully lamellar microstructure with an average lamellar spacing of about 200 nm (Fig. 2b and d). It must be mentioned here that the values given for the alloy compositions in Ref 35 partially are slightly different from the present ones. Data in Ref 35 were from wet chemical analysis of separate alloy pieces, while in the present study all given compositions, i.e. phase as well as alloy compositions, are directly from EPMA analysis of the investigated samples. With the latter results, the composition of the eutectoid point is determined as 60.9 at.% Al.

Fig. 2
figure 2

SEM back-scattered electron (BSE) micrograph for the as-cast alloys (a) Fe-59.0Al, (b) Fe-60.9Al, and (c) Fe-62.6Al; (d) fully lamellar microstructure of Fe-60.9Al in high magnification[35]

The composition of the Al-poor and -rich limit of the homogeneity range of Fe5Al8 cannot be directly measured but can be extrapolated from the DTA results. Figure 3 shows the Fe5Al8 phase region of the Fe-Al phase diagram as obtained by the present DTA experiments. The reaction temperatures for the peritectic formation and eutectoid decomposition are 1231 and 1095 °C, respectively. Both, the entrance and exit of the Fe5Al8 single-phase field can be well measured by DTA giving the shape of the phase field as shown in Fig. 3. From this information, the homogeneity range of Fe5Al8 is found to extend from 56.0 to 64.5 at.% Al.

Fig. 3
figure 3

Phase field of the high-temperature phase Fe5Al8 as determined by DTA

Liquidus and Invariant Reactions of FeAl2, Fe2Al5 and Fe4Al13 Phases

Some representative as-cast microstructures of Fe-Al alloys in the composition range from 67 to 79 at.% Al are shown in Fig. 4 and 5. The microstructure of the as-cast alloy Fe-66.8Al (Fig. 4a), which should be single-phase FeAl2 in the equilibrium state at room temperature, contains three different phases FeAl (light contrast in BSE mode), FeAl2 (grey), and Fe2Al5 (dark). This observation can be well explained by the fact that FeAl2 does not form congruently from the melt but in the solid state in a peritectoid type of reaction. Coming from the liquid state, the first solidification step is the precipitation of Fe5Al8 phase, which in a later stage of cooling transforms into a fine mixture of FeAl + FeAl2 (white-grey mixture in the core of the grains). The rest of the liquid solidifies eutectically into Fe5Al8 and Fe2Al5 and only then, in the completely solidified state, FeAl2 grows peritectoidally between the two phases Fe5Al8 and Fe2Al5. As Fig. 4(b) shows and as is expected from the phase diagram, this three-phase as-cast microstructure transforms completely to single-phase FeAl2 by heat treatment at elevated temperatures.

Fig. 4
figure 4

SEM-BSE micrographs of Fe-66.8Al in the (a) as-cast and (b) heat-treated (900 °C/840 h) state, and of (c) alloy Fe-72.9Al in as-cast state

Fig. 5
figure 5

SEM-BSE micrographs of Fe-74.2Al in the (a) as-cast and (b) heat-treated (1000 °C/100 h) state

As mentioned in the introduction, there is still uncertainty about the reaction type leading to the formation of Fe4Al13 (peritectic or congruent). In case this phase forms congruently from the melt, there must be a eutectic between Fe2Al5 and Fe4Al13. The as-cast microstructure of the alloy Fe-72.9Al in Fig. 4(c) shows Fe2Al5 primary dendrites embedded in an Fe4Al13 matrix. There are no indications of a eutectic reaction. Therefore, either the eutectic point is extremely near to the congruent melting point or the reaction is of the peritectic type. As there are no indications of a eutectic, we stick with the peritectic version. In Fig. 5(a), the as-cast microstructure of the alloy Fe-74.2Al is presented. It does not show any Fe2Al5 phase and appears completely single-phase Fe4Al13. This is also true for the as-cast alloys Fe-74.5Al and Fe-74.9Al (see also Table 4). After heat treatment, in all cases precipitates of Fe2Al5 were found (Fig. 5b) in accordance with the phase diagram.

Figure 6 shows representative DTA heating curves for the Al-rich alloys with 67 to 79 at.% Al, which were measured with a heating rate of 1 °C/min. All transition temperatures obtained from the DTA measurements are summarized in Table 6. The transition temperatures were determined from the intersection point of the two tangents as shown at the onset of the peaks. This procedure follows the definition given by Höhne et al.[36,37] Comparing the curves of the Fe-68.0Al and Fe-69.4Al samples, it is obvious that the peritectoid reaction peak of the dissolution of FeAl2 is missing in case of the Al-richer alloy. This indicates that the composition of the Fe2Al5 phase in the peritectoid reaction Fe5Al8 + Fe2Al5 ↔ FeAl2 is between 68.0 and 69.4 at.% Al. While the eutectic/peritectic temperatures are clearly visible in the heating curves and can usually be determined with an accuracy of ±1 or 2 °C, this is not the case for the liquidus temperatures due to the partially very small temperature intervals between solidus and liquidus. In order to get the correct values for the liquidus temperatures, they were determined according to a method described in detail in Ref 38 using both the heating and cooling curves. Nonetheless, the accuracy of some of the determined liquidus values is only ±4 °C. Therefore, the DTA data are not adequate to exclude definitely the existence of a eutectic point near 75 to 76 at.% Al. As such a eutectic composition would be inside the homogeneity range of Fe4Al13 at intermediate temperatures (see final phase diagram in Fig. 10), the eutectic microstructure would not be visible at room temperature. On the basis of all DTA results, the high-temperature part of the phase diagram between 65 and 80 at.% Al was drawn as shown in Fig. 7.

Fig. 6
figure 6

DTA heating curves (1 °C/min) of as-cast Fe-68.0Al, Fe-69.4Al and Fe-74.2Al

Table 6 Transition temperatures of the investigated alloys (67-79 at.% Al) as obtained from DTA measurements (the numbers given in parentheses notify the accuracy of the respective values)
Fig. 7
figure 7

Redetermination of the Fe-Al phase diagram in the Al-rich composition range at high temperatures above 1130 °C

Homogeneity Ranges of FeAl2, Fe2Al5, and Fe4Al13

In order to study the equilibrium compositions and homogeneity ranges of all phases concerned, heat treatments in the range of 600 to 1100 °C were performed as is listed in Table 4. The resulting equilibrium phase compositions are given in Table 7. In addition, the occurring phases and their lattice parameters were studied by XRD. As an example, Fig. 8 shows a comparison of the XRD patterns of as-cast and heat-treated (800 °C/200 h) Fe-69.4Al. In the as-cast state only the peaks characteristic for the crystal structure of Fe2Al5 are visible, while after the heat treatment the reflections of both FeAl2 and Fe2Al5 can be clearly detected in good agreement with the microstructural observations (see Table 4). The lattice parameters obtained from some selected heat-treated alloys are listed in Table 8. As expected, the unit cell volume of a certain phase increases with increasing Al content due to the larger atomic size of Al compared to Fe.

Table 7 Equilibrium phase compositions as obtained from EPMA analysis of heat-treated samples (HT) and diffusion couples (DC), accuracy is ±0.5 at.%
Fig. 8
figure 8

Low-angle part of the XRD pattern of as-cast and heat-treated (800 °C/200 h) Fe-69.4Al (Co-Kα radiation)

Table 8 Lattice parameters of intermetallic phases in representative heat-treated alloys as obtained from powder XRD (‘vol’ means the volume of the unit cell)

As already mentioned in the section 2, in addition to heat-treated alloys of fixed compositions, three diffusion couples between Fe-50Al and pure Al were used for determining equilibrium phase compositions and homogeneity ranges of the intermetallic phases (Table 5). This method takes advantage of the local equilibrium existing at the phase interfaces. The concentration profiles resulting from the heat treatments were measured by EPMA with step widths of 1 µm. As an example, Fig. 9(a) shows the microstructure with the resulting diffusion zones of the different intermetallic phases in the diffusion couple heat-treated at 850 °C, and in Fig. 9(b) and (c) one of the concentration profiles measured along the marked line is plotted. The profile clearly shows the jumps in concentration between the four intermetallic phases FeAl, FeAl2, Fe2Al5, and Fe4Al13 as well as pure Al, and from extrapolations to the interfaces, the equilibrium compositions of the phases can be obtained. The results are included in Table 7. The growth kinetics of the intermetallic phases differs very much from each other. As is well-known from the literature and nicely confirmed in Fig. 9(a), Fe2Al5 grows much quicker than the other phases, and FeAl2 often grows so slowly that it is hardly visible or totally missing. This happened in case of the present solid-solid diffusion couple (620 °C for 5 h), where the concentration directly jumps from that of FeAl to Fe2Al5.

Fig. 9
figure 9

(a) SEM-BSE micrograph of the diffusion layers and (b-c) variation of Al content across Fe-50Al/Al solid-liquid diffusion couple interface obtained by EPMA for sample annealed at 850 °C for 2 h


Figure 10 shows a revised version of the Al-rich part of the Fe-Al phase diagram as obtained from a combination of all results from phase analysis in heat-treated alloys and diffusion couples, investigation of as-cast and heat-treated microstructures, and determination of liquidus, solidus, and invariant reaction temperatures.

Fig. 10
figure 10

Al-rich part of the Fe-Al phase diagram as obtained from the present investigations

The main results can be summarized as follows:

  1. 1.

    The homogeneity range of Fe5Al8 phase extends from 56.0 to 64.4 at.% Al. At the low-Al side, it ends in the peritectic reaction L + FeAl ↔ Fe5Al8 at 1231 °C and the Al-rich side in the peritectoid reaction Fe2Al5 + Fe5Al8 ↔ FeAl2 at 1145 °C. The eutectoid reaction Fe5Al8 ↔ FeAl2 + FeAl is confirmed to occur at 1095 °C and the composition of the eutectoid point is 60.9 at.% Al.

  2. 2.

    The eutectic reaction L ↔ Fe5Al8 + Fe2Al5 occurs at 1155 °C. Fe2Al5 forms congruently from the liquid at 71.4 at.% Al and an estimated temperature of 1159 °C. Fe4Al13 forms at 1150 °C. The reaction most likely is of the peritectic type (L + Fe2Al5 ↔ Fe4Al13) with the peritectic point very near to the Fe4Al13 composition, but for the present data it cannot be finally excluded that the reaction is congruent.

  3. 3.

    At 800 °C, Fe4Al13 has a very narrow homogeneity range of about 0.5 at.%, the Fe2Al5 phase extends from 70.0 to 72.6 at.% Al, and FeAl2 from 65.8 to 67.1 at.% Al. At 1000 °C, the widths of homogeneity ranges of FeAl2, Fe2Al5, and Fe4Al13 are 2.0, 2.5, and 1.0 at.%, respectively. At the Al-rich end of the phase diagram, the eutectic reaction L ↔ Fe4Al13 + Al is determined to occur at 654 °C, which agrees well with all reported literature values.


  1. It should be mentioned that the phase Fe4Al13 originally was denoted as FeAl3 in the old literature, even though already in 1955 Black[10] found that the true composition corresponds to a formula Fe4Al13. Only since Grin et al.[9] published their structure refinement of this phase in 1994, the formula Fe4Al13 is generally accepted in the literature.


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The authors would like to thank Mr. G. Bialkowski for cutting samples for microstructure investigation and DTA specimens by EDM, Mr. B. Breitbach for XRD measurements, and Mrs. I. Wossack for EPMA. The financial support by the Deutsche Forschungsgemeinschaft is gratefully acknowledged.

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Correspondence to Xiaolin Li.

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Li, X., Scherf, A., Heilmaier, M. et al. The Al-Rich Part of the Fe-Al Phase Diagram. J. Phase Equilib. Diffus. 37, 162–173 (2016).

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  • differential thermal analysis (DTA)
  • diffusion couples
  • electron probe microanalysis (EPMA)
  • intermetallics
  • phase diagram
  • phase transformation