The paper deals with the hot corrosion performance of FeAl base intermetallic HVOF coatings in molten Na2SO4 at 850 °C in an isothermal process over the span of 45 h under static conditions. The test was validated with electron microscopy and compositional analyses in the cross-section area, as well as x-ray diffraction techniques. All the coatings were characterized by Al-depleted regions, intersplat oxidation and different stoichiometric ratios of iron aluminides. The results were discussed in relation to the formation of oxide scales on the surface after exposition to corrosive media, as well as heterogeneity and defects of the sprayed coatings. The Fe40Al (at.%) powder showed quite uniform phase distribution after spraying and preserved its integrity after corrosion test; the FeCr-25% + FeAl-TiAl-Al2O3 (wt.%) and Fe46Al-6.55Si (at.%) powders exhibited interface oxidation, with localized corrosion attacks proceeding through particle boundaries and microcrack networks with no evidence of Na and S penetration. FexAly alloys are susceptible to accelerated damage and decohesion of the coating, whereas the formation of sulfides is observed at certain points.
High-temperature oxidation is believed to be the major reason for the degradation of materials used at elevated temperatures, which in consequence leads to prolonged downtime of elements such as boilers and turbines utilized in power production (Ref 1,2,3,4). As an adequate countermeasure to the above-mentioned issues, intermetallics and Ni-based alloys have gained significant attraction as coating materials (Ref 1,2,3, 5,6,7).
Transition metal aluminides, mainly those based on Ni and Fe, are potentially applicable at high temperatures and provide a sufficient alternative to superalloys (Ref 4,5,6, 8,9,10,11,12). The alumina layer, formed on the surface of materials, is responsible for their excellent resistance to oxidizing, sulfiding and carburizing atmospheres even at temperatures exceeding 1000 °C (Ref 5, 10, 13).
However, while showing good strength and environmental stability, other aspects such as poor ductility and toughness at room temperature, mediocre creep strength, as well as fabrication difficulties have greatly hindered the introduction of intermetallics as industrial structural materials (Ref 14). Therefore, their commercial application in some fields is still a matter of concern (Ref 15).
The applications of iron aluminides are, for the most part, based on their excellent corrosion resistance at high temperatures in environments that cause damage to Fe-Cr-Ni steels and other alloys (Ref 4). They show higher resistance to sulfidation and carburizing atmospheres, as well as to molten nitrates and carbonate salts in relation to multiple different iron- or nickel-based alloys (Ref 16, 17). FeAl alloys have demonstrated particularly improved resistance to various molten salts leading to hot corrosion in heat exchanging systems, incinerators and burners. This pertains to such chemicals as potassium sulfate (K2SO4), vanadium pentoxide (V2O5), mixtures of sodium sulfate and vanadium pentoxide (Na2SO4-V2O5), chlorates and carbonates, all of which can inflict severe damage in the energy sector (Ref 18,19,20,21,22,23,24).
High resistance to hot corrosion is a matter of paramount importance in many branches of industry concerning the construction of boilers, internal combustion engines, gas turbines, fluidized bed combustion and industrial waste incinerators. The material degradation is determined by the confluence of high-temperature oxidation, hot corrosion and erosion processes (Ref 1,2,3, 5,6,7, 11, 12, 25, 26).
However, iron aluminide corrosion resistance extends to temperatures at which these alloys exhibit limited or poor mechanical strength. Therefore, in many cases, they may be better utilized as clads or coatings for anti-corrosion protection, owing to their limited strength at elevated temperatures (Ref 26,27,28,29,30).
Numerous thermal spray techniques, most notably plasma spraying (Ref 28, 31, 32), high-velocity oxy-fuel (HVOF) (Ref 17, 27, 28, 33,34,35,36,37,38,39,40,41,42,43,44,45,46,47) and D-gun spraying processes (Ref 26, 29, 48,49,50,51,52,53,54,55,56,57,58,59) are considered for Fe-Al intermetallic coating materials. In comparison with other industrially used coatings such as CVD, PVD and hard chromium plating, a much thicker coating can be obtained by thermal spraying, which is a prerequisite in the energy sector. High-velocity arc spraying process (HVAS), a technique used to deposit Fe-Al intermetallic and Fe-Al/WC protective coatings, was designed for evaporator pipes subjected to corrosive and erosive influence of vapor at 550 °C and serves as an example, especially through the prism of their application in the Chinese industry (Ref 60).
Among thermal spray techniques, the scientists, manufacturers and global investors show much interest in HVOF, a state-of-the-art thermal spray technology, which not only yields positive results, but also is relatively cheap (Ref 3, 17, 26, 28, 33,34,35,36,37,38,39,40,41,42,43,44,45,46,47).
Thermal spray iron aluminide coatings were previously tested in high-temperature gaseous environments (Ref 17, 36, 37, 47, 61), but to the best of the authors’ knowledge, very few findings concerning their use under hot corrosion conditions were made (Ref 62). These authors report that no degradation (corrosion and wear) was noticed on the surface of the Fe-25%Al-Zr (wt.%) plasma and HVOF coatings sprayed onto low-carbon steel heat exchanger tubes, which were tested in a new industrial plant burning fuel of very poor quality. However, their research was not orientated toward the coating structures and corrosion evolution.
On the other hand, Singh Sidhu et al. 63 studied the corrosion of plasma-sprayed Ni3Al coatings in air and molten salt (Na2SO4-60%V2O5) at 900 °C on low-carbon steel substrates of extended application in boilers.
Other thermal spray coatings, widely studied in terms of hot corrosion protection resistance, are the case of plasma spraying of MCrAlY’s in TBC systems for aviation gas turbines purposes, which notably reduces their longevity under severe conditions involving molten sulfate-vanadate deposits (Ref 64,65,66,67,68). These coatings can be alternatively produced by HVOF process, which utilizes high-pressure combustion of oxygen and fuel to obtain a relatively low temperature of a supersonic gas jet in comparison with plasma spraying. HVOF allows us to obtain denser and less oxidized coatings, which are more resistant to corrosion (Ref 69).
The growing interest in the promising properties of intermetallic alloys based on the Fe-Al equilibrium phase diagram contributed to the gradual development of the HVOF spraying technique, which proved useful for the production of such intermetallic coatings in terms of their practical application on various steel elements, exposed to corrosive and erosive environment in the energy sector (Ref 28, 33,34,35,36,37,38,39,40,41,42,43,44,45,46,47, 70,71,72,73,74). The focus in these works was mostly placed on the structural properties of Fe-Al coatings and their wear resistance under dry friction (in congruence with ASTM G99-03), abrasive wear (in accordance with ASTM G65-00) and erosive wear, along with the involvement of Al2O3 particles (Ref 44). Furthermore, the research involved the performance of Fe-Al coatings under high-temperature oxidation conditions at 900, 1000 and 1100 °C—for 4, 36 and 72 h, respectively, in the atmospheric air (Ref 27).
Usitalo et al. 75 conducted studies on laser re-melting of HVOF-sprayed Ni-50Cr, Ni-57Cr, Fe3Al, Ni-21Cr-9Mo coatings and reported that the above-mentioned coatings did not suffer from any corrosive damage, whereas sprayed coatings were penetrated by corrosive species.
Other HVOF and novel cold-spray coatings, such as Cr3C2-NiCr and WC-Co, are widely studied regarding their wear resistance behavior (Ref 1,2,3, 7, 25, 76) while great emphasis is placed upon hot corrosion-related applications. Iron aluminide intermetallics appear to provide interesting properties favorable to hot corrosion protection and also manifest wear resistance at high temperatures, providing competition to cobalt binder in WC-Co composites and Ni-based superalloys (Ref 5, 6, 10,11,12, 60, 77,78,79,80,81).
Different alloying elements in iron aluminide and their effect on the oxide scales development when exposed to harsh environments have been investigated (Ref 17, 38, 42, 72,73,74). In this regard, we propose the application of several feedstock iron aluminide powders obtained from different manufacturing routes.
Notably, Senderowski Ref (56) developed a new concept of nanocomposite Fe-Al intermetallic coatings created in situ during gas detonation spraying out of powder with compounds from the Fe-Al phase diagram, manufactured by the self-decomposition method (Ref 57). It was assumed that those powders would exhibit sufficient plastic susceptibility under the spraying test conditions, acceptable mechanical properties of the coatings and good stability of the structure during high-temperature heating. The shortlisted properties of these powders are mostly related to reduced brittleness caused by dynamic oxidation at high temperatures (especially above 500 °C), in the oxygen containing environment.
Particle size control of the self-decomposed powders, especially of the fraction below 80 μm, gives them a more prominent role in the HVOF spraying process. Furthermore, the price of self-decomposing powder is about three times lower than the price of powders of equivalent compositions, produced by gas atomization.
Therefore, after considering the potential advantages of the implementation of the self-decomposing intermetallic Fe-Al-type powders, the aim of the present research was twofold:
developing several iron aluminide HVOF coatings from a Fe40Al (at.%) and FeCr-25% + FeAl-TiAl-Al2O3 (wt.%) powders and comparing them with self-decomposed and SHS (self-propagating high-temperature synthesis)-manufactured powders of different compositions and
evaluating the performance of these coatings in Na2SO4 molten salt at 850 °C, as the ultimate solution for typical application in industrial boilers.
It is well known that the application area of the FeAl coatings depends on their extensive properties. On the basis of the comprehensive results of own research (Ref 59, 82) already conducted, a comprehensive analysis of the impact of the structure, the level of strengthening and the state of residual stress of FeAl coatings on their adhesive strength was carried out. The mechanism of residual stress generation in FeAl coating under supersonic D-gun spraying conditions was presented, with a multi-phase structure of Fe-Al coatings and changes in the Young’s modulus of the FeAl coating at elevated temperatures up to 900 °C taken into account. The mechanism of structure degradation of hybrid coating systems in different load states was subjected to an analysis by means of TAT (tensile adhesion test) and a three-dimensional bending test coupled with acoustic emission recording (Ref 82). The TAT test showed that the FeAl coating sprayed directly onto a steel substrate exhibits significantly lower adhesive strength, compared to hybrid coating systems of NiCr-20 or NiAl-5 sprayed onto the steel substrate before the FeAl base coating. The average adhesive strength of individual coating systems was, respectively: FeAl/steel—23 MPa, FeAl/NiAl5/steel—31 MPa, NiAl5/steel and NiCr20/steel—33 MPa, and FeAl/NiCr20/steel system—37 MPa (Ref 82).
Because we have already considered some aspects of the mechanical performance of the Fe-Al-type coatings, it is a good reason to focus in this paper on the phase and microstructural changes as the “corrosion performance” of the coatings at high temperature in an aggressive environment.
At the same time, the “corrosion performance” that we are studying makes reference to the qualitative phase and microstructural evolution of the coatings, without a quantitative evaluation of weight changes as oxidation dynamics, which is relatively simple for bulk materials. Such an analysis is not so simple in the case of the coating-substrate system, due to the strong oxidation of substrate material at high temperature, which does not lead to reliable results in regard to the FeAl coating itself.
Therefore, in this work, we focused on the analysis of structural stability during high-temperature oxidation at 850 °C in the aggressive Na2SO4 environment of as-sprayed Fe-Al coatings, under the same HVOF process conditions with various types of alloy powders of different chemical composition.
The nominal compositions and characteristics of the powders used in the tests are presented in Table 1. The commercial FeAl grade 3 with a near equiatomic composition, provided by Mecachrome (France), is a pre-alloyed, gas atomized and subsequently ball-milled powder (powder 1). Both powder 2 and powder 3 were produced in the Department of Materials Science of the Silesian Technical University by the self-decomposed method described in detail in Ref 57.
Powder 4 was also produced in the Department of Materials Science of the Silesian Technical University through the SHS technique, contained Fe-Al-type phases agreed upon as FexAly. Their complex phase composition, properties and morphology were considered with a view to possible applications as protective coatings in the power industry sector.
The substrate material was a low-alloy carbon steel G41350 UNS (AISI 4135) of chemical composition presented in Table 2, in the form of coupons with dimensions of 50 × 20 × 5 mm which were grit-blasted (Ra = 4 μm), directly before the HVOF spraying to provide mechanical bonding.
The equipment used for the spraying process was a Diamond Jet Hybrid (DJH2700) designed by SULZER METCO. The following spraying parameters were applied: H2 flow rate = 717 l min−1, oxygen flow rate = 147 l min−1, feeding rate = 20 g/min, spraying distance = 250 mm, traverse gun speed = 500 mm/s and number of layers = 9. In addition, the samples were cooled with compressed air during the spraying process. Nitrogen was used as the powder carrying and shielding gas.
Hot corrosion studies were conducted in molten salt (Na2SO4) at 850 °C for all specimens (Ref 80, 81) with dimensions of 35 × 20 × 5 mm. The samples were cut using the wire electric discharge machining technique, following the HVOF spraying. The Na2SO4 tablet (0.2 g pulp and 5 mm in diameter) was pressed under 0.4 MPa and placed on the surfaces of the coatings. First, the samples were mounted in a furnace preheated to 950 °C and annealed for 10 min in an oven to melt Na2SO4. (Melting point of the salt is close to 890 °C.) Then, the temperature was lowered to 850 °C and the samples were saturated successively for 45 h in order to evaluate the coatings behavior under hot corrosion conditions in the aggressive environment.
The microstructural characteristics of the feedstock powder, as well as initial and corroded coatings, were obtained by SEM/EDS using the Quanta 3D FEG Dual Beam and JEOL 5310 microscopes operating at 20 kV. The backscattered images were obtained with a K.E. developments detector. Coating porosity was evaluated by means of the image analysis ImageJ software. Qualitative microanalysis was performed by EDS with a RÖNTEC detector. Additionally, the roughness of the coatings was measured by confocal microscopy (Leica DCM3D).
XRD was used to characterize the phases and assess the degree of order in the feedstock powders and sprayed coatings. All x-ray measurements were carried out with the Bragg-Brentano θ/2θ Siemens D-500 diffractometer with Cu Kα radiation.
Results and Discussion
Figure 1 shows the particle size distribution of the powders. It can be observed that the ball-milled powder 1 is characterized by the Gaussian distribution centered at a mean size of 30 µm, while powder 2 shows a non-symmetric distribution with d10 = 3 µm/d90 = 56 µm. The self-decomposed powder 3 contains a large amount of fine particles with d10 = 3 µm/d90 = 60 µm, while d10 = 7 µm/d90 = 68 µm was recorded in powder 4.
The SEM-BSE micrographs of the cross sections show that all the powder particles exhibit irregular morphology and reveal uniform composition of powder 1, whereas the rest presents a varying degree of grayness (Fig. 2). Their compositions are presented in Table 3 for different EDX point microanalysis. Powder 2 contains a varying chemical composition with diversified content of Al, Cr and Ti in individual particles, as well as separate regions of Al2O3 (Fig. 2b). Self-decomposed powder 3 shows regions identified as SiO2 and predominant light gray areas with aluminum content significantly higher than iron (Fig. 2c). In powder 4, the distribution of the phases from one particle to the other is quite different (Fig. 2d), with some particles exhibiting a mixed laminar structure of two phases. Thus, it was determined that the SHS intermetallic powder showed a wide range of chemical compositions of the Fe-Al-based phases in single powder particles (52-73 at.%), which suggests that they were secondary solutions based on Fe-Al phases with wide range of Al content and trace amounts of Cr.
Figure 3 shows the XRD results of the powders. Powder 1 presents typical fundamental lines of the FeAl pattern (h + k + l = even), exhibited only when the structure is disordered, as otherwise, the superlattice lines (h + k + l = odd) would also appear. The occurrence of broad peaks is related to the fine grain size and microstrains resulting from the milling.
Based on Senderowski’s results (Ref 57), the low-energy milling of the powder particles causes crystallite fragmentation, resulting in the formation of the nanocrystalline structure of the powder particles. Low-energy milling decreases the ordering degree of the FeAl secondary solution, which in turn limits the strength of the particles. Nevertheless, this is compensated with strengthening, which originates from the crystallite fragmentation.
Powder 2 contains Fe-Al and Ti-Al intermetallics, while the XRD of powder 3 confirms the presence of different intermetallic Fe-Al phases, mainly Fe2Al5 and FeAl3, together with trace amounts of SiO2. Silicon embrittles the material. A clear explanation and concise description of the self-decomposing process are presented in Ref 56, 57, where it was reported that many hypothesis can be introduced to explain the self-decomposition of the Pyroferal cast-iron casts.
The Pyroferal casts structure, which depends on the chemical composition, is made of the following intermetallic phases: Fe3Al and FeAl, or FeAl and Al4C3 aluminum carbide, trace amounts of graphite. The most common hypothesis of the self-decomposition suggests that secretions of aluminum carbide Al4C3 react with water vapor on the surface of the Fe-Al-C-Me alloys (Me = Ni, Mn, Cr, Mo, V, B, Si) and create aluminum hydroxide and methane (Ref 57):
The cracking and fragmenting of the castings occur under the influence of stresses caused by the product Al(OH)3, characterized by a higher specific volume than reacting Al4C3 carbide.
Powder 4 consists of strongly oxidized secondary solution on the FeAl intermetallic base with a widely varying content of aluminum and thin Al2O3 films covering the particle surface, which has a bearing on their growing importance in the production of coatings with a nanocomposite structure.
The strong diversification of chemical composition between single particles as well as within the area inside shows that the tested powder has the structure of a secondary solution based on phases from the Fe-Al equilibrium phase diagram, with a wide span of changes in Al and sparse distribution of Cr and Si. It is to be assumed that the formation of oxide films on the surface of the powder particles is most likely attributable to self-propagating high-temperature synthesis, a phenomenon strongly exothermic in its nature. The oxide formation may as well be related to the technological process consisting of crashing and high-energy mechanical milling during selective heat sintering onto a powder.
In consequence, the XRD analysis of powder 4 revealed the formation of FeAl, FeAl2, Fe2Al5 and FeAl2O4 phases under the SHS process. Relatively high half-width of the overlapping reflections of Fe-Al phases is the result of a wide span of Al content across the area containing individual powder particles (Fig. 3), which leads to a network deformation within each phase and generation of residual stress. Moreover, the latter is amplified by crushing and high-energy mechanical milling of sinters following the SHS process.
As-Sprayed Coating Microstructures
Figure 4 shows the cross sections of as-sprayed HVOF coatings with thickness of 103 ± 9; 84 ± 10; 76 ± 13; and 93 ± 11 µm, obtained through spraying nine layers, for each one of the four powders presented in Table 1. The coating obtained with the pre-alloyed powder (powder 1) is quite uniform in thickness, whereas other are less homogeneous; the values of roughness were found to be Ra = 3.6 ± 0.6; 5.1 ± 0.7; 4.3 ± 0.3; and 6.8 ± 0.4 µm, respectively. The highest porosity of 1.45 ± 0.02% corresponds to coating 4 (as-sprayed powder 4, from now on label coating X stands for as-sprayed powder X).
The examination of the microstructure indicates that the uniform distribution of the oxidation occurs in-flight rather than after the splat impact.
The powder particles are usually melted or at least pre-melted, as a result of HVOF spraying, during which the gas mixture is being continuously combusted under high pressure (Ref 28, 33,34,35, 39,40,41,42,43, 46). As a result of the thermal activation of gaseous products in the HVOF process, the in situ formation of thin and complex oxide films on the internal splat interfaces is affected. The oxide films, identified mainly as Al203 compounds, become a specific composite reinforcement in a Fe-Al intermetallic coating (Ref 33, 34, 40,41,42,43, 45, 46). Oxides are formed during the HVOF process in the phase during which the gaseous products transport the powder particles, along with rapid chemical reactions, accompanied by the release of a great amount of thermal energy (Ref 40,41,42,43).
The presence of a lamellar structure resulting from partly melted and oxidized particles with inhomogeneous compositions (Table 4) and intersplat porosity can be observed at higher magnification (Fig. 4). The nature of coating 1 is well documented by partially and fully melted particles exhibiting different degrees of grayness at the boundaries of the intersplats (Fig. 4a). The light areas in the intersplats correspond to the Al-depleted regions, whereas the darkest ones are attributed to spinel oxides (Ref 56).
Furthermore, the XRD results confirm the findings (Fig. 5); the additional peaks, also identified as FeAl, correspond to the superlattice lines due to ordering of the intermetallic phase as a result of the thermal history of particles in the flame. Light regions around the intersplat boundaries of coating 2 in Fig. 4(b) are poorer in Al and Ti, which in fact are located next to the dark gray areas identified as oxides (Fig. 5). Coating 2 is reinforced by the incorporation of alumina, visible as intensely dark areas in the shape of circle-like figures. The SiO2 particles act as some sort of reinforcement in coating 3 (dark regions in Fig. 4c). The light gray regions in coating 3 correspond to iron-rich phases, while the darker predominant contrast reveals more balanced iron and aluminum content (Fig. 4c). Some porosity is observed; however, the extend of oxidation is significantly lower in relation to coating 1. SiO2 particles from the feedstock can be found as very dark regions, uniformly distributed within the coating. In coating 4, the lightest regions are poorer in aluminum than the medium gray ones and are identified as Fe3Al phase, whereas the medium gray contrast is mainly identified as FeAl2 and Fe2Al5 (Fig. 4d).
The degree of melting or semi-melting of the particles in HVOF within the coating can be controlled by process variables, i.e., fuel and oxygen flow rates, spraying distance and particle size. The process variables determine particle temperature and velocity upon impact and, thus, the typical lamellar structure of thermal-sprayed coatings. Many different iron aluminide compositions have been deposited using these technologies (Ref 17, 27, 28, 33,34,35,36,37,38,39,40,41,42,43,44,45,46,47, 82). However, different distributions of the intermetallic phases and Fe-rich areas are usually observed after the evaluation of their structural characterization. Moreover, these areas are aluminum-depleted as a result of the thermal history of the particles in the flame.
Low oxygen-to-fuel ratio is normally preferred in order to minimize oxidation, whereas lower carrying gas flow implies slower particle velocities; a higher in-flight period promotes further oxidation (Ref 43, 70). The formation of intersplat oxides, and thus the occurrence of Al-depleted regions, may stimulate corrosion in field performance; at the same time, such oxides may also increase coating hardness and wear resistance. For example, Totemeier et al. 70 observed a decrease in the oxide content and coating porosity both in Fe3Al and in FeAl cases when the chamber pressure was increased, because it directly affects particle velocity and thus their degree of melting. However, the particle temperature for FeAl was lower than for the Fe3Al powder, probably because of the lesser thermal conductivity of FeAl. Considering those factors, Al2O3 can clearly act as a reinforcement phase in coating 2, aiding Al and Cr oxidation which leads to forming a protective layer. On the whole, it is important to point out that the resulting Al content and distribution in the as-sprayed coating also determine corrosion properties.
Some microcracks, formed perpendicularly to the layer, were observed particularly in coating 4 and less noticeably in coating 3; such microcracks are attributed to the brittleness of the intermetallic phases, which are unable to withstand the deformation upon impact at high particle velocities. The grain boundaries were not the most common areas favoring the propagation of cracks, and therefore good cohesive strength is assumed. The microcrack network for the as-sprayed SHS powder (coating 4, see arrows in inset Fig. 4d) does not exhibit a specific direction within individual splats, which confirms the correspondence between embrittlement and the occurrence of Al-rich phases, namely Fe2Al5 and FeAl2.
For the as-sprayed self-decomposed powder (coating 3, see arrows in inset Fig. 4c), the microcracks are perpendicular to the coating surface, which suggests that the cracking is also due to the influence of tensile thermal strain sustained during rapid quenching of splats. The values of the linear thermal expansion coefficient for Fe-Al-type intermetallic phases (ranging from 15 × 10−6 up to 22 × 10−6 K−1) are significantly different in comparison with these of the steel substrate (12 × 10−6 K−1) (Ref 58, 59). Some of the cracks found in the ball-milled Cr- and Ti-alloyed powder (coating 2, see arrows in inset Fig. 4b) may be additionally linked to the impact of the hot metallic particles entering cooler Al2O3 regions.
Additionally, it was previously observed for Fe40Al type coatings that equiaxed small grains were displayed in the unmelted areas, while columnar grains, typical for rapid solidification processes, were visible in the melted regions. Interestingly, as a result of the thermal history of the milled particles in the flame, the final FeAl phase appears to be the ordered B2 lattice, present in the areas that reached the molten state (Ref 34, 46). Taking into consideration a higher melting point of the FeAl stoichiometric compound in relation to Fe2Al5 and FeAl2 (1250, 1171 and 1157 °C, respectively), and the high particle heterogeneity of powders 3 and 4, there is a great likelihood that these phases melt during the formation of amorphous oxide (AO) (Ref 29, 46, 51,52,53,54,55,56). This results in the multi-phase (composite-like) structure of the Fe-Al coatings (Ref 29, 56).
Degradation and infiltration of Na and S elements within the coatings following exposure to Na2SO4 at 850 °C are examined in Fig. 6 to 9. The cross section of coating 1 (Fig. 6a, b) does not show significant damage compared to Fig. 4(a); the coating preserves its original thickness all along the tested sample. No infiltration of the salt can be observed within the splat boundaries (Fig. 6c-g). The light contrast (Fig. 6b) is poorer in aluminum than the as-sprayed state (spot 1-coating 1 Table 5), while the intersplat dark contrast is richer in oxygen.
A similar case is observed in the as-sprayed powders 2 (Fig. 7) and 3 (Fig. 8) where the oxygen diffusion is detected even within the splats. Following the tests, the non-oxidized phase in the as-sprayed coating 2 (spot 3-coating 2 Table 4), which is nearly equal in Fe and Al content, becomes oxidized and enriched in chromium at the expense of depleted rate of titanium (spot 3-coating 2 Table 5). By contrast, the dark gray phase doubles its Al content while O content is reduced (spot 2-coating 2 Table 4 compared to spot 4-coating 2 Table 5). The silicon in coating 3 appears to diffuse the core of the splats. Also, some oxide microareas are detected at the coating-substrate interface and have been identified as aluminum oxide (Fig. 8b). No significant amounts of sodium or sulfur were identified within the EDS maps (Fig. 7c-h, 8c-h).
Coating 4 suffered the highest damage as splat shapes are no longer visible and the deposit consists of a composite containing Al-rich oxide network with a Fe-rich matrix (Fig. 9a, b). Such a structure is visible to progress uniformly from the air-coating interface (area 1-coating 4 Table 5); it displays higher oxygen content than the rest of the coating (area 2-coating 4 Table 5). For that coating, regions near to the edges of the sample were severely damaged with considerable degradation observed; in these cases, Na and S concentrations escalated in proportion to visible infiltration.
Top surface oxide morphologies in Fig. 10 are contrasting with more granular shapes discovered in coatings 1, 3 and 4, whereas coating 2 is more needle-shaped. Coating 1 was covered by iron oxide even when exposed to oxidation atmosphere (Ref 83). The needles in coating 2 were identified as mixed Fe and Ti oxides, with an oxide layer below, also rich in Al and Cr (Fig. 7). Coating 3 was mostly covered by alumina layer, while coating 4 was a mixed Fe and Al oxide; the scale fluxing may involve an interactive reaction between the basic dissolution of Al2O3 and the acidic dissolution of Fe2O3.
The XRD of the corroded coatings (Fig. 11a-d) shows that coating 1 is covered with two oxides, namely Fe2O3 and Al2O3. The results obtained from the EDS analysis (Fig. 6) confirm the depletion of Al in the Fe-Al phase. The rapid growth of iron oxide was not observed in the rest of the coatings, yet alumina was identified; the alumina-identified pattern phase is mainly α-Al2O3 corundum; actually, it has been reported that the predominant surface product that forms between 600 and 800 °C is α-Al2O3(rhombohedral), together with γ-Al2O3(cubic) and θ-Al2O3(monoclinic) (Ref 84). The latter two phases are fast growing, more voluminous, more porous and less protective than α-Al2O3; the heterogeneous growing of α-Al2O3, also with some traces of γ and θ phases, could also explain why the other coatings showed significant damage. According to the literature, the sequence is believed to be as follows: γ-Al2O3 → δ-Al2O3 (750 °C); δ-Al2O3 → θ-Al2O3 (900 °C); θ-Al2O3 → α-Al2O3 (1000 °C), and the precise temperature transformation from θ to α is influenced by the presence of reactive elements (Ref 85).
The formation of alumina consumes a certain quantity of Al, reducing its activity and partial pressure of the oxygen. This caused a relative increase in the activities of the Fe and S and serves as a catalyst for the reaction with the molten mixture to obtain a compound such as FeS.
Sulfur attack and penetration appear to be more visible in the edges of coating 4 (not presented here). Under the molten salt corrosion conditions, the dissolution of the component below can be produced by local dissolution or selective dissolution of different components of the oxide (Ref 86). Selective oxidation and dissolution of iron in coating 4 resulted in a loss of the coating integrity, leading to a high corrosion rate. In this case, sulfur may have moved from the oxide/molten salt interface toward the coating/substrate interface by diffusion or infiltration of the melt through the structural defects of the oxide scale. It proceeded through particle boundaries as well as microcrack networks until the moment it reached the steel substrate in some parts of the coating. It can be suspected that this local corrosion mechanism may have triggered the damage, causing metal dissolution in hot points. The decomposition of Na2SO4 would result in SO3 formation, which might have been the aggressive agent for the rapid preferential attack at coating defects (Ref 87). Sodium presence within the coating might follow the basic dissolution reaction at the oxide/molten salt interface: Al2O3 + Na2O → 2NaAlO2 (Ref 19).
Corrosion in the rest of the coatings appears to have been produced by uniform oxidation at the coating/molten salt/air interface. The formation of the fast growing oxides indicates that the coating might be diluted upon longer exposure times, apparently without preference for any of the coating components. At 900 °C, the Fe40Al composition for bulk materials was found to be more resistant than Fe40Al-0.1B-10Al2O3 (at.%) (Ref 88). Apparently, a similar phenomenon applies to coating 2, but the scale is much more complex, especially in contrast to coating 3. Under the oxide scale, Al depletion was observed in the intermetallic phase. Less defective structure of the as-sprayed coatings and the favorable presence of other stoichiometric intermetallic phases may be the reason why their corrosion rates were lower than the ones observed in the as-sprayed SHS powder.
The results of experiments and subsequent analyses allowed an evaluation of hot corrosion performance of HVOF-sprayed coatings with Fe-Al intermetallic matrix in molten Na2SO4 at 850 °C in an isothermal process in the span of 45 h under static conditions.
It was determined that under applied HVOF spraying conditions, Fe-Al powder particles form a stratified/laminar/pseudo-composite structure of the coating, in which the thickness varies in dependence of the Fe-Al powder composition after nine passes of the HVOF gun. At the same time, high plastic deformation of FeAl grains in the volume of the coating, obtained from the powder particles of different chemical composition with the involvement of alloying elements, proves the plastic deformability of a highly brittle Fe-Al phase upon impact with the substrate material. However, significant changes to the percentage shares of iron and aluminum in the structure of the as-sprayed coatings, involving the oxide phases formed in situ during the HVOF process, indicate melting or pre-melting of the powder particles, coupled with intensive oxidation due to reaction with the highly reactive hydroxyl radicals (OH). Rapid plastic transformation of intermetallic powder particles, combined with their “freezing” in contact with the “cold” substrate, leads to the amorphization of oxide ceramics. The oxides are shaped in the form of flattened, nanometric thin films at the boundaries of the splats, within a fine-dispersed, heterogenous structure of the Fe-Al coating. Selective depletion of aluminum, diffusing into oxide phases, has no influence on the behavior of the FeAl (B2) superstructure, obtained from the pre-milled powder FeCr25 + FeAl-TiAl-Al2O3 sprayed under applied HVOF conditions. Hard oxide phases, in the form of thin films at the grain boundaries and dispersions in the grain volume, influence the strengthening of the structure, mainly by limiting the dislocation motion and migration of grain boundaries. Consequently, this reduces the susceptibility to plastic deformation of FeAl grains and recrystallization of the intermetallic alloy. Participation of the phases rich in aluminum, namely Fe2Al5 and FeAl2, as well as oxide phases, leads to the formation of microcracks. As a result, this is conducive to the diffusion of toxic ingredients in aggressive environment of Na2SO4 molten salt under the conditions of high-temperature oxidation at 850 °C in the span of 45 h.
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The research leading to these results has received funding from the People Programme (Accions Marie Curie) of the 7 Framework Programme of the European Union (FP7/2007-2013) under REA Grant Agreement No. 600388 (TECNIO spring programme), and from the Agency for Business Competitiveness of the Government of Catalonia, ACCIÓ. The authors wish to thank Dr. D. Zasada and M.Sc. Eng. D. Marczak from the Department of Advanced Materials and Technologies, Military University of Technology, for his help in the experimental work as well as Prof. L. Swadźba for enabling the study of hot corrosion.
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Senderowski, C., Cinca, N., Dosta, S. et al. The Effect of Hot Treatment on Composition and Microstructure of HVOF Iron Aluminide Coatings in Na2SO4 Molten Salts. J Therm Spray Tech 28, 1492–1510 (2019). https://doi.org/10.1007/s11666-019-00886-w
- FeAl intermetallic
- hot corrosion
- thermal spray coatings