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Microstructure and Thermal Behavior of Thermal Barrier Coatings

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Abstract

Yttria stabilized zirconia thick coatings were thermally sprayed from two different feedstock powders. Coating characteristics such as density, crystalline phase composition, and microstructure were evaluated. The thermal expansion coefficient and thermal diffusivity were measured as a function of temperature up to 800 °C and analyzed in terms of the microstructural features. The ability of available models to relate the measured thermal properties to the microstructural features as characterized by readily available methods was assessed. The importance of pore shape and orientation on the thermal conductivity was evidenced. The thermal contact resistance between the substrate and the coating in these samples was estimated from the thermal diffusivity data, and found to change during cooling from 800 °C.

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References

  1. N.P. Padture, M. Gell, E.H. Jordan, Thermal Barrier Coatings for Gas-Turbine Engine Applications, Science, 2002, 296, p 280-284

    Article  CAS  Google Scholar 

  2. D.W. Parker, Thermal Barrier Coatings for Gas Turbines, Automotive Engines and Diesel Engines, Mater. Des., 1992, 13(6), p 345-351

    CAS  Google Scholar 

  3. A.G. Evans, D.R. Mumm, J.W. Hutchinson, G.H. Meier, F.S. Petit, Mechanisms Controlling the Durability of Thermal Barrier Coatings. Prog. Mater. Sci., 2001, 46, p 505-553

    Article  Google Scholar 

  4. P. Ramaswamy, S. Seetharamu, K.B.R. Varma, N. Raman, K.J. Rao, Thermomechanical Fatigue Characterization of Zirconia (8% Y2O3-Zro2) and Mullite Thermal Barrier Coatings on Diesel Engine Components: Effect of Coatings on Engine Performance, Proc. Inst. Mech. Eng., 2000, 214, p 729-742

    Google Scholar 

  5. M.F. Winkler and D. W. Parker, Thermal Barrier Coatings for Diesel Engines-Ten Years of Experience, SAE Technical Paper Series, No. 922438, 1992

  6. H. Herman, Plasma Sprayed Coatings, Sci. Am., 1998, 259(3), p 112-117

    Article  Google Scholar 

  7. A. Kulkarni, Z. Wang, T. Nakamura, S. Sampath, A. Goland, H. Herman, J. Allen, J. Ilavsky, G. Long, J. Frahm, R.W. Steinbrech, Comprehensive Microstructural Characterization and Predictive Property Modeling of Plasma-Sprayed Zirconia Coatings, Acta Mater., 2003, 51, p 2457-2475

    Article  CAS  Google Scholar 

  8. Z. Wang, A. Kulkarni, S. Deshpande, T. Nakamura, H. Herman, Effects of Pores and Interfaces on the Effective Properties of Plasma Sprayed Zirconia Coatings, Acta Mater., 2003, 51, p 5319-5334

    Article  CAS  Google Scholar 

  9. J.C. Maxwell, A Treatise on Electricity and Magnetism. Oxford: Clarendon Press; 1904

    Google Scholar 

  10. G. Grimvall, Thermophysical Properties of Materials. Selected Topics in Solid State Physics, Vol XVIII, North-Holland Physics Publishing, 1986

  11. B. Schulzt, Thermal Conductivity of Porous and Highly Porous Materials, High Temp. High Press., 1981, 13, p 649-660

    Google Scholar 

  12. D.P.H. Hasselman, Effect of Cracks on Thermal Conductivity, J. Appl. Phys., 1978, 12(19), p 403-407

    Google Scholar 

  13. B. Shafiro, M. Kachanov, Anisotropic Effective Conductivity of Materials with Nonrandomly Oriented Inclusions of Diverse Ellipsoidal Shapes, J. Appl. Phys., 2000, 87, p 8561-8569

    Article  CAS  Google Scholar 

  14. I. Seviostanov, M. Kachanov, Plasma-Sprayed Ceramic Coatings: Anisotropic Elastic and Conductive Properties in Relation to the Microstructure; Cross-Property Correlations, Mater. Sci. Eng. A, 2001, 297, p 235-243

    Article  Google Scholar 

  15. K.W. Schlichting, N.P. Padture, P.G. Klemens, Thermal Conductivity of Dense and Porous Y2O3 Stabilized ZrO2, J. Mater. Sci., 2001, 36, p 3003-3010

    Article  CAS  Google Scholar 

  16. I.O. Golosnoy, S.A. Tsipas, T.W. Clyne, An Analytical Model for Simulation of Heat Flow in Plasma Sprayed Thermal Barrier Coatings, J. Therm. Spray Technol., 2005, 14, p 205-214

    Article  CAS  Google Scholar 

  17. A.D. Jadhav, N.P. Padture, E.H. Jordan, M. Gell, P. Miranzo, E.R. Fuller, Low-Thermal-Conductivity Plasma-Sprayed Thermal Barrier Coatings with Engineered Microstructures, Acta Mater., 2006, 54, p 3343-3349

    Article  CAS  Google Scholar 

  18. F. Cernuschi, S. Ahmaniemi, P. Vuoristo, T.J. Mantyla, Modeling of Thermal Conductivity of Porous Materials: Application to Thick Thermal Barrier Coatings, J. Eur. Ceram. Soc., 2004, 24, p 2657-2667

    Article  CAS  Google Scholar 

  19. H.J. Lee, “Thermal Diffusivity in Layered and Dispersed Composites,” Ph.D. Thesis, Purdue University, University Microfilm International, 1975

  20. R. Soltani, E. Garcia, T.W. Coyle, J. Mostaghimi, R.S. Lima, B.R. Marple, C. Moreau. Thermomechanical Behavior of Nanostructured Plasma Sprayed Zirconia Coatings, J. Therm. Spray Technol., 2006, 15, p 657-662

    Article  CAS  Google Scholar 

  21. R.E. Taylor, K.D. Maglic, Pulse Method for Thermal Diffusivity Measurement, Compendium of Thermophysical Properties Measurement Methods. Vol 1, Survey of Measurement Techniques, K.D. Maglic, A. Cezairliyan, V.E. Peletsky Eds., Plenum Press, (New York), 1992, p 305-336

    Google Scholar 

  22. W. Chi, S. Sampath, H. Wang, Comparison of the Thermal Transport Property Measurements of Thermally Sprayed Coatings by the Laser and Xenon Flash Techniques, J. Therm. Spray Technol., 2007, 16, p 444-448

    Article  CAS  Google Scholar 

  23. R.E. Taylor, X. Wang, X. Xu, Thermophysical Properties of Thermal Barrier Coatings, Surf. Coat. Tech., 1999, 120-121, p 89-95

    Article  CAS  Google Scholar 

  24. F. Cernuschi, L. Lorenzoni, S. Ahmaniemi, P. Vuoristo, T. Mäntylä, Studies of the Sintering Kinetics of Thick Thermal Barrier Coatings by Thermal Diffusivity Measurements, J. Eur. Ceram. Soc., 2005, 25, p 393-400

    Article  CAS  Google Scholar 

  25. J. Wu, X. Wei, N.P. Padture, P.G. Klemens, M. Gell, E. Garcia, P. Miranzo, M.I. Osendi, Low Thermal Conductivity Rare Earth Zironates for Potential Thermal Barrier Coating Applications, J. Am. Ceram. Soc., 2002, 85, p 3031-3035

    CAS  Google Scholar 

  26. S. Ahmaniemi, P. Vuoristo, T. Mantyla, F. Cernuschi, L. Lorenzoni, Modified Thick Barrier Coatings: Thermophysical Characterization, J. Eur. Ceram. Soc., 2004, 24, p 2669-2679

    Article  CAS  Google Scholar 

  27. P. Morrel, R. Taylor, Thermal Diffusivity of Thermal Barrier Coatings of ZrO2 Stabilized with Y2O3, High Temp. High Press., 1985, 17, p 79-88

    Google Scholar 

  28. H.E. Eaton, J.R. Linsey, R.B. Diwinddie, The Effect Of Thermal Aging on the Thermal Conductivity of Plasma Sprayed Fully Stabilized Zirconia, Thermal Conductivity 22, T.W. Tong Ed., Technomic Pub. Co. Inc., (Lancaster, PA), 1994, p 289-300

    Google Scholar 

  29. W. Chi, S. Sampath, H. Wang, Ambient and High-Temperature Thermal Conductivity of Thermal Sprayed Coatings, J. Therm. Spray Technol., 2006, 15, p 773-778

    Article  CAS  Google Scholar 

  30. R. McPherson, A Model for the Thermal Conductivity of Plasma Sprayed Ceramic Coatings. Thin Solid Films, 1984, 112, p 89-95

    Article  CAS  Google Scholar 

  31. A.S. Wagh, Porosity Dependence of the Thermal Conductivity of Ceramics and Sedimentary Rocks, J. Mater. Sci., 1993, 28, p 3715-3721

    Article  CAS  Google Scholar 

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Acknowledgments

The authors would like to acknowledge the Auto 21 National Centre of Networks of Excellence and Materials and Manufacturing, Ontario, for financial support, and the Industrial Materials Institute of the National Research Council, Canada, for technical support. Financial support from the MEC-MAT2006-07118 is gratefully acknowledged. E. Garcia acknowledges financial support from the I3P-PC2005L program.

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Garcia, E., Miranzo, P., Soltani, R. et al. Microstructure and Thermal Behavior of Thermal Barrier Coatings. J Therm Spray Tech 17, 478–485 (2008). https://doi.org/10.1007/s11666-008-9200-6

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  • DOI: https://doi.org/10.1007/s11666-008-9200-6

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