Abstract
In this work, static mass analysis method and electrochemical test experiment were used to study the corrosion resistance of Mg-12Gd-3Y-1Sm-0.8Al alloy in different heat treatment states. Optical microscope, scanning electron microscope and x-ray diffractometer were used to analyze microstructure. The result shows: The microstructure of different samples are composed of α-Mg, Mg5Gd, Mg24Y5, Mg41Sm5 and Al2RE phases. Heat treatment can change the morphology and distribution of the precipitates, and the precipitates can affect the corrosion behavior as a cathode, thereby improving the corrosion resistance of the alloy in 3.5% NaCl solution. The relative corrosion rates of the different samples can be ranked as T6>T6-18h>T4>As-cast. After aging treatment, the fine and continuous precipitates act as a barrier to prevent the propagation of corrosion. At this time, the alloy has the strongest corrosion resistance.
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X. Zhou, C. Liu, Y. Gao, S. Jiang and Z. Chen, Mechanical Properties of the Mg-Gd-Y-Zn-Zr Alloys with Different Morphologies of Long-period Stacking Ordered Phases, J. Mater. Eng. Perform., 2018, 27, p 6237–6245.
C.P. Tang, X.Z. Wang, W.H. Liu, D. Feng, G.L. Zuo, D. Li, X.Y. Li, X. Chen, Q. Li and X. Liu, Effect of Deformation Conditions on Dynamic Mechanical Behavior of a Mg-Gd-Based Alloy, J. Mater. Eng. Perform., 2020, 29, p 8414–8421.
B. Chen, W.M. Zhou, S. Li, X.L. Li and C. Lu, Hot Compression Deformation Behavior and Processing Maps of Mg-Gd-Y-Zr Alloy, J. Mater. Eng. Perform., 2013, 22, p 2458–2466.
M. Zhang, K. Peng, J. Chen and Y. Deng, Heat-resistant Magnesium Alloys and Their Development, Chin. J. Nonferrous., 2004, 14(9), p 1443–1450.
S.M. He, Q.Z. Xiao, M.P. Li et al., Microstructure, Mechanical Properties, Creep and Corrosion Resistance of Mg-Gd-Y-Zr(Ca) Alloys, Mater. Sci. Forum, 2007, 546, p 101–104.
C. Li, Q.A. Li, X.Y. Zhang and J.L. Bu, Effects of Sm on Microstructure and Mechanical Properties of Mg-5.5Al-0.5Y Alloy, Adv. Mater. Res., 2011, 146, p 267–271.
S. Liang, D. Guan, L. Chen, Z.H. Gao, H.X. Tang, X.T. Tong and R. Xiao, Precipitation and Its Effect on Age-hardening Behavior of As-cast Mg-Gd-Y Alloy, Mater. Des., 2011, 32(1), p 361–364.
M.E. Drits, Z.A. Sviderskaya, L.L. Rokhlin and N.I. Nikitina, Effect of Alloying on the Properties of Mg−Gd Alloys, Met. Sci. Heat Treat., 1979, 21(11), p 887–889.
I.A. Anyanwu, S. Kamado and Y. Kojima, Aging Characteristics and High Temperature Tensile Properties of Mg-Gd-Y-Zr Alloys, Mater. Trans., 2001, 42(7), p 1206–1211.
J. Liu, L.X. Yang, C.Y. Zhang, B. Zhang, T. Zhang, Y. Li, K.M. Wu and F.H. Wang, Significantly Improved Corrosion Resistance of Mg-15Gd-2Zn-0.39Zr Alloys: Effect of Heat-treatment, J. Mater. Sci. Technol., 2019, 35(08), p 132–142.
G. Song and A. Atrens, Corrosion Mechanisms of Magnesium Alloys, Adv. Eng. Mater., 2000, 1(1), p 11–33.
B.L. Mordike and T. Ebert, Magnesium-Properties-Applications-Potential, Mater. Sci. Eng: A., 2001, 302(1), p 37–45.
S.C. Maria del Rosario, B. Carsten, M.L. Chamini, M. Marta, Z. Tristan, P. Daniel, Z.L. Mikhail and K. Karl Ulrich, Effect of Heat Treatment on the Corrosion Behavior of Mg-10Gd Alloy in 0.5% NaCl Solution, Front. Mater. Sci., 2020, 7, p 1–16.
F.M. Lu, A.B. Ma, J.H. Jiang, Y. Guo, D.H. Yang, D. Song and J.Q. Chen, Significantly Improved Corrosion Resistance of Heat-treated Mg-Al-Gd Alloy Containing Profuse Needle-like Precipitates Within Grains, Corrs. Sci., 2015, 94(5), p 171–178.
S. Yu, R.L. Jia, T. Zhang, F.H. Wang, J. Hou and H.X. Zhang, Effect of Different Scale Precipitates on Corrosion Behavior of Mg–10Gd–3Y–0.4Zr Alloy, Acta Metall. Sin.-Engl. Lett., 2019, 32, p 433–442.
M. Yang, Y.H. Liu, J.A. Liu and Y.L. Song, Effect of T6 Heat Treatment on Corrosion Resistance and Mechanical Properties of AM50 Magnesium Alloy, Mater. Res. Innov., 2016, 19(10), p 259–264.
G.L. Makar and J. Kruger, Corrosion of Magnesium, Int. Mater. Rev., 1993, 38, p 138–153.
A.D. Sudholz, K. Gusieva, X.B. Chen, B.C. Muddle, M.A. Gibson and N. Birbilis, Electrochemical Behaviour and Corrosion of Mg-Y Alloys, Corrosion Sci., 2011, 53(6), p 2277–2282.
G. Ben-Hamua, D. Eliezer, S.K. Shin and S. Cohen, The Relation Between Microstructure and Corrosion Behavior of Mg–Y–RE–Zr Alloys, J. Alloy. Compd., 2007, 431(1), p 269–276.
S. Liang, D. Guan and X. Tan, The Relation Between Heat Treatment and Corrosion Behavior of Mg–Gd–Y–Zr Alloy, Mater. Des., 2011, 32(3), p 1194–1199.
G.L. Makar and J. Kruger, Corrosion Studies of Rapidly Solidified Magnesium Alloys, J. Electrochem. Soc., 1990, 137(2), p 414.
X. Liu, T. Zhang, Y.W. Shao and F. Wang, Effect of Alternating Voltage Treatment on the Corrosion Resistance of Pure Magnesium, Corros. Sci., 2009, 51(8), p 1772–1779.
T. Zhang, Y. Shao, G. Meng, Z. Cui and F. Wang, Corrosion of Hot Extrusion AZ91 Magnesium Alloy: I-relation Between the Microstructure and Corrosion Behavior, Corros. Sci., 2011, 53(5), p 1960–1968.
J. Li, Q. Jiang, H. Su and Y. Li, Effect of Heat Treatment on Corrosion Behavior of AZ63 Magnesium Alloy in 35 wt% Sodium Chloride Solution, Corros. Sci., 2016, 111, p 288–301.
G.A. Zhang, Y. Zeng, X.P. Guo, F. Jiang, D.Y. Shi and Z.Y. Chen, Electrochemical Corrosion Behaviour of Carbon Steel Under Dynamic High Pressure H2S/CO2 Enviroment, Corros. Sci., 2012, 65, p 37–47.
F. Cao, G. Song and A. Atrens, Corrosion and Passivation of Magnesium Alloys, Corrs. Sci., 2016, 111, p 835–845.
I.J. Skar, Corrosion and Corrosion Prevention of Magnesium Alloys, Mater. Corros., 1999, 50(1), p 2–6.
Z. Szklarz and Ł Rogal, Influence of Heat Treatment on the Microstructure and Corrosion Behavior of Thixo-Cast Mg-Y-Nd-Zr, J. Mater. Eng. Perform., 2020, 29, p 6181–6195.
Y. Gui and Q. Li, Effect of Heat Treatment on Corrosion Behaviors of Mg-5Y-2Nd-3Sm-0.5Zr Alloys, Int. J. Electrochem. Sci., 2019, 14(2), p 1342–1357.
Y.Y. Lv and L.F. Zhang, Corrosion and protection of magnesium alloys, Adv. Mater. Res., 2015, 1120, p 1078–1082.
A. Kania, R. Nowosielski, A. Gawlas-Mucha and R. Babilas, Mechanical and Corrosion Properties of Mg-based Alloys with Gd Addition, Mater., 2019, 12(11), p 1211.
F. Chong, M.Z. Li, Y. Hou, H.Y. Wang, X.Y. Li and L.Q. Fan, Effect of Ca on Corrosion Resistance Behavior of As-cast AZ91 Magnesium Alloys, Rare Metal Mat. Eng., 2015, 44(1), p 41–47.
G. Song, A.L. Bowles and D.H. Stjohn, Corrosion Resistance of Aged Die Cast Magnesium Alloy AZ91D, Adv. Eng. Mater., 2004, 366(1), p 74–86.
Y. Han, J. Pin, C. Xiao and Q. Zeng, Effects of Heat Treatments on Corrosion Behavior of Mg AT72 Alloy, Mater. Sci. Forum., 2013, 748, p 230–237.
X. Ma, Q. Tong, Y. Li and B. Hou, Effect of Heat Treatment on Corrosion Behaviors of Mg-5Y-1.5Nd Alloys, Int. J. Electrochem., 2016, 2016, p 1–9.
G. Song and A. Atrens, Corrosion Mechanisms of Magnesium Alloys, Adv. Eng. Mater., 2010, 1(1), p 11–33.
A. Atrens, G.L. Song, M. Liu, Z.M. Shi, F.Y. Cao and M.S. Dargusch, Review of Recent Developments in the Field of Magnesium Corrosion, Adv. Eng. Mater., 2015, 17(4), p 400–453.
A. Pardo, M.C. Merinoa, A.E. Coy and R. Arrabal, Corrosion Behaviour of Magnesium/Aluminium Alloys in 3.5 wt.% NaCl, Corros. Sci., 2008, 50(3), p 823–834.
G. Song, A. Atrens, X. Wu and B. Zhang, Corrosion Behaviour of AZ21, AZ501 and AZ91 in Sodium Chloride, Corros. Sci., 1998, 40(10), p 1769–1791.
G. Song, A. Atrens and M. Dargusch, Influence of Microstructure on the Corrosion of Diecast AZ91D, Corros. Sci., 1998, 41(2), p 249–273.
Z.L. Liu, X.C. Wu, X.Q. Wu, H.J. Xie and J. Xie, Effects of Al Content on the Corrosion Properties of Mg–4Y–xAl Alloys, Mater. Corros., 2020, 71(7), p 1216–1225.
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This project is sponsored by the National Natural Science Foundation of China (Nos. 51571084)
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Chen, Z., Li, Q., Chen, X. et al. Effect of Heat Treatment on Corrosion Performance of Mg-12Gd-3Y-1Sm-0.8Al Alloy. J. of Materi Eng and Perform 31, 2564–2574 (2022). https://doi.org/10.1007/s11665-021-06347-2
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DOI: https://doi.org/10.1007/s11665-021-06347-2