Abstract
This paper investigates the effect of crystallographic texture on the corrosion product morphology and corrosion behavior of AZ31 magnesium alloy after immersion in simulated body fluid for 3 days. The microstructure and macrotexture analyses are performed through optical microscopy and x-ray diffraction methods, respectively. The polarization test evaluated the corrosion, and the FESEM electron microscope equipped with EDS was used to investigate the morphology of the corrosion products. According to the results, the morphology of calcium phosphate deposit as a corrosion product at the surface with basal texture was a porous cauliflower shape. In contrast, the calcium phosphate deposit at the surface of the nonbasal texture was uniform and nanoworm-like. The corrosion rate at the basal texture surface was higher than the nonbasal one, which is attributed to the difference in the morphology of calcium phosphate film.
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T. Hosaka, S. Yoshihara, I. Amanina, and B.J. MacDonald, Influence of Grain Refinement and Residual Stress on Corrosion Behavior of AZ31 Magnesium Alloy Processed by ECAP in RPMI-1640 Medium, Procedia Eng., 2017, 184, p 432–441
M. Moravej and D. Mantovani, Biodegradable Metals for Cardiovascular Stent Application: Interests and New Opportunities, Int. J. Mol. Sci., 2011, 12(7), p 4250–4270
M.P. Staiger, A.M. Pietak, J. Huadmai, and G. Dias, Magnesium and Its Alloys as Orthopedic Biomaterials: A Review, Biomaterials, 2006, 27(9), p 1728–1734
B.R. Sunil, T.S.S. Kumar, U. Chakkingal, V. Nandakumar, M. Doble, V.D. Prasad, and M. Raghunath, In Vitro and In Vivo Studies of Biodegradable Fine Grained AZ31 Magnesium Alloy Produced by Equal Channel Angular Pressing, Mater. Sci. Eng., C, 2016, 59, p 356–367
M. Alvarez-Lopez, M.D. Pereda, J.A. Del Valle, M. Fernandez-Lorenzo, M.C. Garcia-Alonso, O.A. Ruano, and M.L. Escudero, Corrosion Behaviour of AZ31 Magnesium Alloy with Different Grain Sizes in Simulated Biological Fluids, Acta Biomater., 2010, 6, p 51763–51771
C.L.P. Silva, A.C. Oliveira, C.G.F. Costa, R.B. Figueiredo, M. de Fátima Leite, M.M. Pereira, V.F.C. Lins, and T.G. Langdon, Effect of Severe Plastic Deformation on the Biocompatibility and Corrosion Rate of Pure Magnesium, J. Mater. Sci., 2017, 52(10), p 5992–6003
A. Atrens, G.L. Song, F. Cao, Z. Shi, and P.K. Bowen, Advances in Mg Corrosion and Research Suggestions, J. Magnes. Alloys, 2013, 1(3), p 177–200
F. Cao, G.L. Song, and A. Atrens, Corrosion and Passivation of Magnesium Alloys, Corros. Sci., 2016, 111, p 835–845
H. Li, D. Liu, Y. Zhao, F. Jin, and M. Chen, The Influence of Zn Content on the Corrosion and Wear Performance of Mg-Zn-Ca Alloy in Simulated Body Fluid, J. Mater. Eng. Perform., 2016, 25, p 3890–3895
Y. Ding, J. Lin, C. Wen, D. Zhang, and Y. Li, Mechanical Properties, In Vitro Corrosion and Biocompatibility of Newly Developed Biodegradable Mg-Zr-Sr-Ho Alloys for Biomedical Applications, Sci. Rep., 2016, 6, p 31990
Y. Ding, C. Wen, P. Hodgson, and Y. Li, Effects of Alloying Elements on the Corrosion Behavior and Biocompatibility of Biodegradable Magnesium Alloys: A Review, J. Mater. Chem. B, 2014, 2(14), p 1912–1933
M.E. Turan, Y. Sun, Y. Akgul, Y. Turen, and H. Ahlatci, The Effect of GNPs on Wear and Corrosion Behaviors of Pure Magnesium, J. Alloy. Compd., 2017, 724, p 14–23
A.M. Kumar, S. Fida Hassan, A.A. Sorour, M. Paramsothy, and M. Gupta, Electrochemical Corrosion and In vitro Biocompatibility Performance of AZ31Mg/Al2O3 Nanocomposite in Simulated Body Fluid, J. Mater. Eng. Perform., 2018, 27, p 3419–3428
L.Y. Cui, S.D. Gao, P.P. Li, R.C. Zeng, F. Zhang, S.-Q. Li, and E.H. Han, Corrosion Resistance of a Self-Healing Micro-arc Oxidation/Polymethyltrimethoxysilane Composite Coating on Magnesium Alloy AZ31, Corros. Sci., 2017, 118, p 84–95
X.J. Cui, X.Z. Lin, C.H. Liu, R.S. Yang, X.W. Zheng, and M. Gong, Fabrication and Corrosion Resistance of a Hydrophobic Micro-arc Oxidation Coating on AZ31 Mg Alloy, Corros. Sci., 2015, 90, p 402–412
H.R. Bakhsheshi-Rad, E. Hamzah, M.R. Abdul-Kadir, S.N. Saud, M. Kasiri-Asgarani, and R. Ebrahimi-Kahrizsangi, The Mechanical Properties and Corrosion Behavior of Double-Layered Nano Hydroxyapatite-Polymer Coating on Mg-Ca Alloy, J. Mater. Eng. Perform., 2015, 24, p 4010–4021
I.A. Shahar, T. Hosaka, S. Yoshihara, and B.J. Macdonald, Mechanical and Corrosion Properties of AZ31 Mg Alloy Processed by Equal-Channel Angular Pressing and Aging, Procedia Eng., 2017, 184, p 423–431
S. Pawar, X. Zhou, G.E. Thompson, G. Scamans, and Z. Fan, The role of intermetallics on the corrosion initiation of twin roll cast AZ31 Mg alloy, J. Electrochem. Soc., 2015, 162(9), p 442–448
Z. Zou, J. Chen, H. Yan, B. Su, and X. Gong, Microstructure, Bio-corrosion Behavior, and Corrosion Residual Strength of High Strain Rate Rolled Mg-4Zn Alloy Sheet, J. Mater. Eng. Perform., 2016, 25, p 1974–1985
S. Pawar, T.J.A. Slater, T.L. Burnett, X. Zhou, G.M. Scamans, Z. Fan, G.E. Thompson, and P.J. Withers, Crystallographic Effects on the Corrosion of Twin Roll Cast AZ31 Mg Alloy Sheet, Acta Mater., 2017, 133, p 90–99
B. Jiang, Q. Xiang, A. Atrens, J. Song, and F. Pan, Influence of Crystallographic Texture and Grain Size on the Corrosion Behaviour of As-Extruded Mg Alloy AZ31 Sheets, Corros. Sci., 2017, 126, p 374–380
D. Orlov, K.D. Ralston, N. Birbilis, and Y. Estrin, Enhanced Corrosion Resistance of Mg Alloy ZK60 After Processing by Integrated Extrusion and Equal Channel Angular Pressing, Acta Mater., 2011, 59(15), p 6176–6186
D. Song, A. Ma, J. Jiang, P. Lin, D. Yang, and J. Fan, Corrosion Behavior of Equal-Channel-Angular-Pressed Pure Magnesium in NaCl Aqueous Solution, Corros. Sci., 2010, 52(2), p 481–490
M.-C. Zhao, M. Liu, G. Song, and A. Atrens, Influence of the β-Phase Morphology on the Corrosion of the Mg Alloy AZ91, Corros. Sci., 2008, 50(7), p 1939–1953
N.N. Aung and W. Zhou, Effect of Grain Size and Twins on Corrosion Behaviour of AZ31B Magnesium Alloy, Corros. Sci., 2010, 52(2), p 589–594
T. Zhang, Y. Shao, G. Meng, Z. Cui, and F. Wang, Corrosion of Hot Extrusion AZ91 Magnesium Alloy: I-Relation Between the Microstructure and Corrosion Behavior, Corros. Sci., 2011, 53(5), p 1960–1968
R. Xin, B. Li, L. Li, and Q. Liu, Influence of Texture on Corrosion Rate of AZ31 Mg Alloy in 3.5 wt.% NaCl, Mater. Des., 2011, 32(8–9), p 4548–4552
R. Xin, Y. Luo, A. Zuo, J. Gao, and Q. Liu, Texture Effect on Corrosion Behavior of AZ31 Mg Alloy in Simulated Physiological Environment, Mater. Lett., 2012, 72, p 1–4
G.-L. Song, R. Mishra, and Z. Xu, Crystallographic Orientation and Electrochemical Activity of AZ31 Mg Alloy, Electrochem. Commun., 2010, 12(8), p 1009–1012
C. Wang, H. Ding, B.-S. Wang, K. Wang, J.-J. Shi, and J.-F. Chen, Effects of Deformation Texture and Twins on the Corrosion Resistance of Rolled AZ31 Mg Alloy Under 5% Uniaxial Compression, Acta Metallurgica Sinica (English Lett.), 2017, 30(10), p 921–930
Z. Pu, G.L. Song, S. Yang, J.C. Outeiro, O.W. Dillon, Jr., D.A. Puleo, and I.S. Jawahir, Grain Refined and Basal Textured Surface Produced by Burnishing for Improved Corrosion Performance of AZ31B Mg Alloy, Corros. Sci., 2012, 57, p 192–201
M. Esmaily, J.E. Svensson, S. Fajardo, N. Birbilis, G.S. Frankel, S. Virtanen, R. Arrabal, S. Thomas, and L.G. Johansson, Fundamentals and Advances in Magnesium Alloy Corrosion, Prog. Mater Sci., 2017, 89, p 92–193
ASTM G1-03, Standard Practice for Preparing, Cleaning, and Evaluating Corrosion Test Specimens, ASTM International, West Conshohocken, 2011
R.C. Zeng, J. Zhang, W.J. Huang, W. Dietzel, K.U. Kainer, C. Blawert, and K.E. Wei, Review of Studies on Corrosion of Magnesium Alloys, Trans. Nonferrous Met. Soc. China, 2006, 16, p 763–771
Y.F. Zhang, B. Hinton, G. Wallace, X. Liu, and M. Forsyth, On Corrosion Behavior of Magnesium Alloy AZ31 in Simulated Body Fluids and Influence of Ionic Liquid Pretreatments, Corros. Eng., Sci. Technol., 2012, 47(5), p 374–382
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Aghamohammadi, H., Hosseinipour, S.J., Rabiee, S.M. et al. Influence of Crystallographic Texture on the Corrosion Product Morphology and Corrosion Rate of AZ31 Plate in Simulated Body Fluid. J. of Materi Eng and Perform 29, 3824–3830 (2020). https://doi.org/10.1007/s11665-020-04902-x
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DOI: https://doi.org/10.1007/s11665-020-04902-x