Abstract
Hot deformation behavior of a Ni-free, Fe-17Cr-12Mn-0.28N-0.06C (wt.%) austenitic stainless steel, hereinafter coded as FeCrMnN, was investigated using hot compression tests conducted under different deformation conditions comprising temperature and strain rate ranges of 800-1200 °C and 0.01-10 s−1, respectively. While the hot deformation at high strain rate and low temperatures (e.g., 10 s−1 and 800 or 900 °C) showed essentially dynamic recovery, resulting in a pancake-shaped microstructure, most of the other conditions exhibited occurrence of dynamic recrystallization (DRX). Increasing deformation temperature and decreasing strain rate showed a decrease in the critical stress and strain for initiating DRX. In general, DRX resulted in extensive microstructural reconstitution and grain refinement. For instance, hot deformation at 1000 °C/0.01 s−1 resulted in a fully recrystallized fine-grained microstructure with an average grain size of about 15 μm in comparison with the initial grain size of 60 µm. Increasing the temperature enhanced grain growth, but an increase in strain rate resulted in a finer grain structure. The amount of delta ferrite in the present steel varied under different conditions of deformation such that the lowest amount of delta ferrite (about 4.5%) was observed at 1000 °C. The activation energy of deformation (Qdef) for the present FeCrMnN steel with the initial grain size of 60 µm was estimated to be about 502 kJ/mol, which is higher than that of the conventional austenitic stainless steels.
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K.H. Lo, C.H. Shek, and J.K.L. Lai, Recent Developments in Stainless Steels, Mater. Sci. Eng. R Rep., 2009, 65, p 39–104
D.W. Kim, Influence of Nitrogen-Induced Grain Refinement on Mechanical Properties of Nitrogen Alloyed Type 316LN Stainless Steel, J. Nucl. Mater., 2012, 420, p 473–478
J.W. Simmons, Overview: High-Nitrogen Alloying of Stainless Steels, Mater. Sci. Eng. A, 1996, 207, p 159–169
H. Hänninen, J. Romu, R. Ilola, J. Tervo, and A. Laitinen, Effects of Processing and Manufacturing of High Nitrogen-Containing Stainless Steels on Their Mechanical, Corrosion and Wear Properties, J. Mater. Process. Technol., 2001, 117(3), p 424–430
H. Ha, T. Lee, C. Oh, and S. Kim, Effects of Combined Addition of Carbon and Nitrogen on Pitting Corrosion Behavior of Fe-18Cr-10Mn Alloys, Scripta Mater., 2009, 61, p 121–124
Z. Jiang, Z. Zhang, H. Li, Z. Li, and Q. Ma, Microstructural Evolution and Mechanical Properties of Aging High Nitrogen Austenitic Stainless Steels, Int. J. Miner. Metall. Mater., 2010, 17(6), p 729–736
M. Saucedo-Muñoz, Y. Watanabe, T. Shoji, and H. Takahashi, Effect of Microstructure Evolution on Fracture Toughness in Isothermally Aged Austenitic Stainless Steels for Cryogenic Applications, Cryogenics, 2000, 40(11), p 693–700
K. Yang and Y. Ren, Nickel-Free Austenitic Stainless Steels for Medical Applications, Sci. Technol. Adv. Mater., 2010, 11(1), p 014105
Y. Han, G. Qiao, J. Sun, and D. Zou, A Comparative Study on Constitutive Relationship of As-Cast 904L Austenitic Stainless Steel During Hot Deformation Based on Arrhenius-Type and Artificial Neural Network Models, Comput. Mater. Sci., 2013, 67, p 93–103
G. Dieter, H. Kuhn, and S. Semiatin, Handbook of Workability and Process Design, ASM International, Almere, 2003
D. Banabic, H.J. Bunge, K. Pöhlandt, and A.E. Tekkaya, Formability of Metallic Materials : Plastic Anisotropy, Formability Testing, Forming Limits, Springer, New York, 2000
N.D. Ryan, H.J. McQueen, and E. Evangelista, Dynamic Recovery and Strain Hardening in the Hot Deformation of Type 317 Stainless Steel, Mater. Sci. Eng., 1986, 81, p 259–272
N.D. Ryan, H.J. McQueen, and J.J. Jonas, The Deformation Behavior of Types 304, 316, and 317 Austenitic Stainless Steels During Hot Torsion, Can. Metall. Q., 1983, 22(3), p 369–378
N.D. Ryan and H.J. McQueen, Flow Stress, Dynamic Restoration, Strain Hardening and Ductility in Hot Working of 316 Steel, J. Mater. Process. Technol., 1990, 21(2), p 177–199
A. Dehghan-Manshadi, M.R. Barnett, and P.D. Hodgson, Hot Deformation and Recrystallization of Austenitic Stainless Steel: Part I. Dynamic Recrystallization, Metall. Mater. Trans. A, 2008, 39, p 1359–1370
H.J. McQueen and J.J. Jonas, Recent Advances in Hot Working: Fundamental Dynamic Softening Mechanisms, J. Appl. Met. Work., 1984, 3(3), p 233–241
H.J. McQueen and C.A.C. Imbert, Dynamic Recrystallization: Plasticity Enhancing Structural Development, J. Alloys Compd., 2004, 378, p 35–43
F.J. Humphreys and M. Hatherly, Recrystallization and Related Annealing Phenomena, Elsevier, Amsterdam, 2004
T. Sakai, A. Belyakov, R. Kaibyshev, H. Miura, and J.J. Jonas, Dynamic and Post-dynamic Recrystallization Under Hot, Cold and Severe Plastic Deformation Conditions, Prog. Mater. Sci., 2014, 60, p 130–207
J. Moon, T. Lee, J. Shin, and J. Lee, Hot Working Behavior of a Nitrogen-Alloyed Fe-18Mn-18Cr-N Austenitic Stainless Steel, Mater. Sci. Eng. A, 2014, 594, p 302–308
M. Tendo, Y. Tadokoro, K. Suetsugu, and T. Nakazawa, Effects of Nitrogen, Niobium and Molybdenum on Strengthening of Austenitic Stainless Steel Produced by Thermo-Mechanical Control Process, ISIJ Int., 2001, 41, p 262–267
M. Guo, Z. Wang, Z. Zhou, S. Sun, and W. Fu, Effect of Nitrogen Content on Hot Deformation Behavior and Grain Growth in Nuclear Grade 316LN Stainless Steel, Adv. Mater. Sci. Eng., 2015, 2015, p 427945
S. Venugopal, S.L. Mannan, and Y.V.R.K. Prasad, Influence of Strain Rate and State of Stress on the Formation of Ferrite in Stainless Steel Type AISI, 304 During Hot Working, Mater. Lett., 1996, 26, p 161–165
R. Ebrahimi and A. Najafizadeh, A New Method for Evaluation of Friction in Bulk Metal Forming, J. Mater. Process. Technol., 2004, 152, p 136–143
D. Shahriari, M.H. Sadeghi, and K.T. Kim, Effects of Lubricant and Temperature on Friction Coefficient During Hot Forging of Nimonic 115 Superalloy, Kovove Mater., 2011, 49, p 375–383
H. Mirzadeh, A. Najafizadeh, and M. Moazeny, Flow Curve Analysis of 17-4 PH Stainless Steel Under Hot Compression Test, Metall. Mater. Trans. A, 2009, 40, p 2950–2958
H. Mirzadeh, J.M. Cabrera, J.M. Prado, and A. Najafizadeh, Hot Deformation Behavior of a Medium Carbon Microalloyed Steel, Mater. Sci. Eng. A, 2011, 528, p 3876–3882
A. Najafizadeh and J.J. Jonas, Predicting the Critical Stress for Initiation of Dynamic Recrystallization, ISIJ Int., 2006, 46, p 1679–1684
H. Fu-xiang, W. Xin-hua, Z. Jiong-ming, J. Chen-xi, F. Yuan, and Y. Yan, Situ Observation of Solidification Process of AISI, 304 Austenitic Stainless Steel, J. Alloys Compd., 2008, 15, p 78–82
A. Dehghan-Manshadi and P.D. Hodgson, Effect of δ-Ferrite Co-existence on Hot Deformation and Recrystallization of Austenite, J. Mater. Sci., 2008, 43, p 6272–6277
J.J. Jonas, C.M. Sellars, and W. Tegart, Strength and Structure Under Hot-Working Conditions, Metall. Rev., 1969, 14(1), p 1–24
R. Nkhoma, C. Siyasiya, and W. Stumpf, Hot Workability of AISI, 321 and AISI, 304 Austenitic Stainless Steels, J. Alloys Compd., 2014, 595, p 103–112
Z. Wang, W. Fu, S. Sun, H. Li, Z. Lv, and D. Zhao, Mechanical Behavior and Microstructural Change of a High Nitrogen CrMn Austenitic Stainless Steel During Hot Deformation, Metall. Mater. Trans. A, 2010, 41, p 1025–1032
B. Gan, M. Zhang, H. Li, Y. Yao, and L. Li, A Modified Constitutive Model and Dynamic Recrystallization Behavior of High-N Mn18Cr18 Alloy, Steel Res. Int., 2017, 87, p 1–14
H. Li, W. Jiao, H. Feng, X. Li, Z. Jiang, G. Li, L. Wang, G. Fan, and P. Han, Deformation Characteristic and Constitutive Modeling of 2707 Hyper Duplex Stainless Steel Under Hot Compression, Metals, 2016, 6, p 223
T. Xi, C. Yang, M. Babar Shahzad, and K. Yang, Study on the Processing Map and Hot Deformation Behavior of a Cu-Bearing 317LN Austenitic Stainless Steel, Mater. Des., 2015, 87, p 303–312
H. Feng, Z. Jiang, H. Li, W. Jiao, X. Li, H. Zhu, S. Zhang, B. Zhang, and M. Cai, Hot Deformation Behavior and Microstructural Evolution of High Nitrogen Martensitic Stainless Steel 30Cr15Mo1N, Steel Res. Int., 2017, 87, p 1700149
V. Gavriljuk, Y. Petrov, and B. Shanina, Effect of Nitrogen on the Electron Structure and Stacking Fault Energy in Austenitic Steels, Scripta Mater., 2006, 55, p 537–540
I.A. Yakubtsov, A. Ariapour, and D.D. Perovic, Effect of Nitrogen on Stacking Fault Energy, Acta Mater., 1999, 47, p 1271–1279
L. Yu-Ping, Z. Yong, R. Fan, C. Hai-Tao, W. Yu-Qing, and S. Jie, Hot Working of High Nitrogen Austenitic Stainless Steel, J. Iron Steel Res., 2010, 17(10), p 45–49
A. Sarkar and J.K. Chakravartty, Investigation of Progress in Dynamic Recrystallization in Two Austenitic Stainless Steels Exhibiting Flow Softening, J. Metall. Eng., 2013, 2, p 130–136
M. Jafari and A. Najafizadeh, Comparison Between the Methods of Determining the Critical Stress for Initiation of Dynamic Recrystallization in 316 Stainless Steel, J. Mater. Sci. Technol., 2008, 24, p 840–844
S. Kim and Y. Yoo, Dynamic Recrystallization Behavior of AISI, 304 Stainless Steel, Mater. Sci. Eng. A, 2001, 311, p 108–113
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Khorshidi, H., Kermanpur, A., Somani, M.C. et al. On the Hot Deformation Behavior of a Ni-Free Austenitic Stainless Steel Interstitially Alloyed with Low Nitrogen Content. J. of Materi Eng and Perform 27, 6765–6779 (2018). https://doi.org/10.1007/s11665-018-3766-z
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DOI: https://doi.org/10.1007/s11665-018-3766-z