Abstract
ZrO2 was brazed to Ti-6Al-4V using a Zr55Cu30Al10Ni5 (at.%) amorphous filler in a high vacuum at 1173-1273 K. The influences of brazing temperature, holding time, and cooling rate on the microstructure and shear strength of the joints were investigated. The interfacial microstructures can be characterized as ZrO2/ZrO2−x + TiO/(Zr,Ti)2(Cu,Ni)/(Zr,Ti)2(Cu,Ni,Al)/acicular Widmanstäten structure/Ti-6Al-4V. With the increase in the brazing temperature, both the thickness of the ZrO2−x + TiO layer and the content of the (Zr,Ti)2(Cu,Ni) phase decreased. However, the acicular Widmanstäten structure gradually increased. With the increase in the holding time, the (Zr,Ti)2(Cu,Ni) phase decreased, and the thickness of the (Zr,Ti)2(Cu,Ni) + (Zr,Ti)2(Cu,Ni,Al) layer decreased. In addition, cracks formed adjacent to the ZrO2 side under rapid cooling. The microstructures produced under various fabrication parameters directly influence the shear strength of the joints. When ZrO2 and Ti-6Al-4V couples were brazed at 1173 K for 10 min and then cooled at a rate of 5 K/min, the maximum shear strength of 95 MPa was obtained.
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W.B. Hanson, K.I. Ironside, and J.A. Fernie, Active Metal Brazing of Zirconia, Acta Mater., 2000, 48, p 4673–4676
V. Fiorentini and G. Gulleri, Theoretical Evaluation of Zirconia and Hafnia as Gate Oxides for Si Microelectronics, Phys. Rev. Lett., 2002, 89, p 266101
R. Roger, E.W. Collings, and G. Welsch, Materials Properties Handbook: Titanium Alloys, ASM International, Materials Park, OH, 1994
A.N. Alhazaa and T.I. Khan, Diffusion Bonding of Al7075 to Ti-6Al-4V Using Cu Coatings and Sn-3.6Ag-1Cu, J. Alloys Compd., 2010, 494, p 351–358
M.L. Muolo, E. Ferrera, L. Morbelli, and A. Passerone, Wetting, Spreading and Joining in the Alumina-Zirconia-Inconel 738 System, Scripta Mater., 2004, 50, p 325–330
O. Smorygo, J.S. Kim, M.D. Kim, and T.G. Eom, Evolution of the Interlayer Microstructure and the Fracture Modes of the Zirconia/Cu-Ag-Ti Filler/Ti Active Brazing Joints, Mater. Lett., 2007, 61, p 613–616
A.V. Durov, B.D. Kostjuk, A.V. Shevchenko, and Y.V. Naidich, Joining of Zirconia to Metal with Cu-Ga-Ti and Cu-Sn-Pb-Ti Fillers, Mater. Sci. Eng. A, 2000, 290, p 186–189
A.V. Durov, Y.V. Naidich, and B.D. Kostyuk, Investigation of Interaction of Metal Melts and Zirconia, J. Mater. Sci., 2005, 40, p 2173–2178
A. Guedes and A. Pinto, Active Metal Brazing of Machinable Aluminum Nitride-Based Ceramic to Stainless Steel, J. Mater. Eng. Perform., 2012, 5, p 671–677
B.A. Kalin, V.T. Fedotov, and A.E. Grigoriew, Tritium Barrier Development for Austenitic Stainless Steel by its Aluminizing in a Lithium Melt, Fusion Eng. Design., 1995, 28, p 119
D. Szewieczek and J. Tyrlik, Designing the Brazed Joint Properties with Application of Amorphous Tapes as a Filler Metal, J. Mater. Process. Technol., 1995, 53, p 405–412
A. Rabinkin, Optimization of Brazing Technology. Structural Integrity, and Performance, Sci. Technol. Weld. Join., 2004, 9, p 181–199
M. Naka and I. Okamoto, Amorphous Alloy and its Application to Joining, Trans. JWRI, 1985, 14, p 185–195
M. Singh, R. Asthana, and T.P. Shpargel, Brazing of Ceramic-Matrix Composites to Ti and Hastealloy Using Ni-base Metallic Glass Interlayers, Mater. Sci. Eng. A, 2008, 498, p 19–30
M. Singh and R. Asthana, Joining of Zirconium Diboride-Based Ultra High-Temperature Ceramic Composites Using Metallic Glass Interlayers, Mater. Sci. Eng. A, 2007, 460, p 153–162
Y. Yokoyama, K. Yamano, K. Fukaura, H. Sunada, and A. Inoue, Ductility Improvement of Zr55Cu30Al10Ni5 Bulk Amorphous Alloy, Scripta Mater., 2001, 44, p 1529–1533
Y.H. Liu, J.D. Hu, Y.P. Zhang, Z.X. Guo, and Y. Yang, Joining of Zirconia and Ti-6Al-4V Using a Ti-based Amorphous Filler, J. Mater. Sci. Technol., 2011, 27(7), p 653–658
D. Sciti, A. Bellosi, and L. Esposito, Bonding of Zirconia to Superalloy with the Active Brazing Technique, J. Eur. Ceram. Soc., 2001, 21, p 45–52
Y.H. Liu, J.D. Hu, Y.P. Zhang, Z.X. Guo, and Y. Yang, Effect of Parameters on Interface of the Brazed ZrO2 Ceramic and Ti-6Al-4V Joint Using Ti-based Amorphous Filler, Acta Metall. Sin. (Engl. Lett.)., 2012, 25(2), p 89–94
C.T. Chang, T.Y. Yeh, R.K. Shiue, and C.S. Chang, Microstructural Evolution of Infrared Brazed CP-Ti Using Ti-Cu-Ni Brazes, J. Mater. Sci. Technol., 2011, 27(2), p 131–138
M.X. Yang, T.S. Lin, P. He, and Y.D. Huang, In Situ Synthesis of TiB Whisker Reinforcements in the Joints of Al2O3/TC4 during Brazing, Mater. Sci. Eng. A, 2011, 528, p 3520–3525
Acknowledgments
This study was supported by 2012 Open Foundation of the Key Lab of Automobile Materials, Jilin University; from the Natural Scientific Basic Research Fund for Platform and Base Construction (Grant No. 12-450060481229); the State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology (No. AWPT-Z03); and by the Department of Science & Technology of Jilin Province (Grant No. 20100545).
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Liu, Y., Hu, J., Shen, P. et al. Effects of Fabrication Parameters on Interface of Zirconia and Ti-6Al-4V Joints Using Zr55Cu30Al10Ni5 Amorphous Filler. J. of Materi Eng and Perform 22, 2602–2609 (2013). https://doi.org/10.1007/s11665-013-0534-y
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DOI: https://doi.org/10.1007/s11665-013-0534-y