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Vertically Aligned Nanosheets of an Electrodeposited Lanthanum Oxide Electrode for Non-Enzymatic Glucose Sensing Application

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Abstract

A lanthanum oxide (La2O3) thin film electrode was synthesized by inexpensive electrodeposition using potentiostatic mode. The structural, morphological and electrochemical characterizations of La2O3 film was carried out by x-ray diffraction, x-ray photoelectron spectroscopy, energy dispersive x-ray spectroscopy, field emission scanning electron microscopy, the Brunauer–Emmett–Teller method, transmission electron microscopy and cyclic voltammetry. The La2O3 electrode displayed excellent electrocatalytic activity towards the oxidation of glucose in alkaline solution. Nearly linear i-t amperometric response was observed in the range from 1.25 mM to 11.25 mM glucose concentration with sensitivity 616 μA mM−1 cm−2. The electrode exhibited excellent response time of less than 1 s. The quick i-t amperometric current response towards glucose by La2O3 makes it a potential candidate for practical glucose detection application.

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Acknowledgments

The authors are thankful to D. Y. Patil Education Society (Deemed to be University), Kolhapur- 416006 (India), for financial support through internal research project sanction No. DYPES/DU/R&D/ 3099 dated 3rd Oct 2018. Also, this research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (2018R1A6A1A03023788). We are thankful to DSTFIST Analytical Instrumentation Laboratory, Jaysingpur College Jaysingpur for characterization facilities. In addition, S. B. Jadhav acknowledges the Chhatrapati Shahu Maharaj Research Training and Human Development (SARTHI), Government of Maharashtra, India, for awarded Junior Research Fellowship (JRF).

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Authors and Affiliations

  1. Centre for Interdisciplinary Research, D. Y. Patil Education Society, (Deemed to be University), Kolhapur, 416 006, India

    S. B. Jadhav, U. M. Patil, C. D. Lokhande & P. N. Pawaskar

  2. Department of Polymer Science and Engineering, Korea National University of Transportation, Chungju, 380-702, South Korea

    R. N. Bulakhe & Insik In

  3. Department of IT Convergence (Brain Korea PLUS 21), Korea National University of Transportation, Chungju, 380-702, South Korea

    Insik In

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  1. S. B. Jadhav
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  2. U. M. Patil
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  3. R. N. Bulakhe
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  5. C. D. Lokhande
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  6. P. N. Pawaskar
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Correspondence to P. N. Pawaskar.

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Jadhav, S.B., Patil, U.M., Bulakhe, R.N. et al. Vertically Aligned Nanosheets of an Electrodeposited Lanthanum Oxide Electrode for Non-Enzymatic Glucose Sensing Application. J. Electron. Mater. 50, 675–685 (2021). https://doi.org/10.1007/s11664-020-08605-w

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