Skip to main content
SpringerLink
Log in

A Coupled Experimental Study and Thermodynamic Modeling of the SiO2-P2O5 System

  • Published:
Metallurgical and Materials Transactions B Aims and scope Submit manuscript

Abstract

A coupled key phase diagram experimental study and thermodynamic modeling of the SiO2-P2O5 system was conducted. Equilibration and quenching experiments using sealed Pt crucibles were performed in the SiO2-rich region to resolve inconsistencies found in the literature data about the SiO2 liquidus. Based on new experimental data and all available and reliable phase diagram and thermodynamic data, the thermodynamic optimization of the SiO2-P2O5 system was carried out to obtain a set of thermodynamic equations for liquid and solid phases in the system. The liquidus slope of SiO2 indicates that P2O5 in the SiO2-rich liquid exists mainly in the form of P2O7 4− instead of PO4 3−. Thermodynamic properties of the liquid solution can be predicted from the Gibbs energy of the liquid phase.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. E.T. Turkdogan: Fundamentals of Steelmaking, 1st ed., pp. 217–39, Institute of Materials, London, 1996.

  2. E.M. Dianov, I.A. Bufetov, M.M. Bubnov, and M.V. Grekov, S.A. Vasilev, O.I. Medvedlov: Opt. Lett., 2000, vol. 25, no.6, pp. 402-04.

    Article  CAS  Google Scholar 

  3. E.M. Dianov, M.V. Grekov, I.A. Bufetov, S.A. Vasilev, O.I. Medvedlov, V.G. Plotnichenko, V.V. Koltashev, A.V. Belov, M.M. Bubnov, S.L. Semjonov, and A.M. Prokhorov: Electron. Lett., 1997, vol. 33, no. 18, pp. 1542-44.

    Article  CAS  Google Scholar 

  4. D.C. Douglass, T.M. Duncan, K.L. Walker, and R. Csencsits: J. Appl. Phys., 1985, vol. 58, no.1, pp. 197-203.

    Article  CAS  Google Scholar 

  5. S.G. Kosinski, D.M. Krol, T.M. Duncan, D.C. Douglass, J.B. MacChesney, and J.R. Simpson: J. Non-Cryst. Solids, 1988, vol. 105, pp. 45–52

    Article  CAS  Google Scholar 

  6. H.L. Tuller, D.P. Button, and D.R. Uhlmann: J. Non-Cryst. Solids, 1980, vol. 40, pp. 93-118.

    Article  CAS  Google Scholar 

  7. S.-P. Tung and B.-J. Hwang: J. Membr. Sci., 2004, vol. 241, pp. 315–23.

  8. T. Uma and M. Nogami: J. Membr. Sci., 2006, vol. 280, pp. 744-51.

    Article  CAS  Google Scholar 

  9. R.A. Bowling and G.B. Larrabee: J. Electrochem. Soc., 1985, vol. 132, no. 1, pp. 141-45.

    Article  CAS  Google Scholar 

  10. M. Delfino: IEEE Electron Device Lett., 1983, vol. 4, no. 3, pp. 54-56.

    Article  Google Scholar 

  11. K. Nassau, R.A. Levy, and D.L. Chadwick: J. Electrochem. Soc., 1985, vol. 132, no. 2, pp. 409-15.

    Article  CAS  Google Scholar 

  12. L.L. Hench: J. Am. Ceram. Soc., 1991, vol. 74, pp. 1487-1510.

    Article  CAS  Google Scholar 

  13. G. Baret, R. Madar, and C. Bernard: J. Electrochem. Soc., 1991, vol. 138, no. 9, pp. 2830-35.

    Article  CAS  Google Scholar 

  14. T-Y. Tien and F. Hummel: J. Am. Ceram. Soc., 1962, vol. 49 (9), pp. 422–24.

  15. E. Kooi: J. Electrochem. Soc., 1964, vol. 111, no. 12, pp. 1383-87.

    Article  CAS  Google Scholar 

  16. E.H. Snow and B.E: Deal. J. Electrochem. Soc., 1966, vol. 113 (3), pp. 263–69.

  17. J.M. Eldridge and P Balk: Trans. TMS-AIME, 1967, vol. 242, pp. 539–45.

  18. C.R. Hammond: Phys. Chem. Glasses, 1978, vol. 19, no. 3, pp. 41-42.

    CAS  Google Scholar 

  19. A. Mal’shikov and I. Bondar: Russ J. Inorg. Chem., 1988, vol. 33, no. 1, pp. 109-12.

    Google Scholar 

  20. I. Bondar and A. Mal’shikov: Dokl. Phys. Chem., 1989, vol. 306, no. 1, pp. 361-64.

    Google Scholar 

  21. W. Jacoby: Ph.D. Thesis, Rutgers University, New Brunswick, 1956, p. 110.

  22. H. Völlenkle, A. Wittmann, and H. Nowotny: Monatsh. Chem., 1963, vol. 94, no. 5, pp. 819-21.

    Article  Google Scholar 

  23. H. Makart: Helv. Chim. Acta., 1967, vol. 50, no. 2, pp. 399-405.

    Article  CAS  Google Scholar 

  24. H. Mayer: Monatsh. Chem., 1974, vol. 105, no. 1, pp. 46-54.

    Article  CAS  Google Scholar 

  25. D.M. Poojary, R.B. Borade, and A. Clearfield: Inorg. Chim. Acta., 1993, vol. 208, pp. 23-29.

    Article  CAS  Google Scholar 

  26. G. Levi and G. Peyronel: Z. Krist., 1935, vol. 92, pp. 190-209.

    CAS  Google Scholar 

  27. H. Völlenkle, A. Wittmann, and H. Nowotny: Monatsh. Chem., 1963, vol. 94, no. 5, pp. 956-63.

    Article  Google Scholar 

  28. F. Liebau, G. Bissert, and N. Köppen: Z. Anorg. Allg. Chem., 1968, vol. 359, no. 3-4, pp. 113-134.

    Article  CAS  Google Scholar 

  29. F. Liebau and G. Bissert: Bull. Soc. Chim. France, 1968, pp. 1742–44.

  30. E. Tillmanns, W. Gebert, and W. Baur: J. Solid State Chem., 1973, vol. 7, pp. 69-84.

    Article  CAS  Google Scholar 

  31. E. Tillmanns, W. Gebert, and W. Baur; Fortschr. Mineral., 1972, vol. 50, no. 1, pp. 97-99.

    Google Scholar 

  32. F. Liebau and K-F. Hesse : Z. Kryst., 1971, vol. 133, pp. 213–24.

  33. G. Bissert and F. Liebau: Acta. Cryst. B, 1970, vol. 26, pp. 233-40.

    Article  CAS  Google Scholar 

  34. D.M. Poojary, R.B. Borade, F.L. Campbell III, and A. Clearfield: J. Solid State Chem., 1994, vol. 112, pp. 106-12.

    Article  CAS  Google Scholar 

  35. G.B. Seifer. Russ J. Inorg. Chem., 1962, vol. 7, no. 12, pp. 1462-63.

    Google Scholar 

  36. B. Lelong: Ann. Chim. (Paris), 1964, vol. 9, pp. 229-60.

    CAS  Google Scholar 

  37. A. Murashkevich, V. Pechkovskii, R. Mel’nikova, T. Barannikova, and A. Chubarov: Russ. J. Inorg. Chem., 1984, vol. 29 (12), pp. 1722–25.

  38. O. Nielsen; Ferrum, 1913, vol. 10, no. 4, pp. 97-112.

    CAS  Google Scholar 

  39. A. Murashkevich, V. Pechkovskii, A. Chubarov, and N. Ivkovich: Russ J. Inorg. Chem., 1983, vol. 28, no. 9, pp. 1243-46.

    Google Scholar 

  40. A. Boullé and R. Jary: Compt. Rend. Acad. Sci. Paris, 1958, vol. 237, pp. 161-3.

    Google Scholar 

  41. A. Boullé and R. Jary: Compt. Rend. Acad. Sci. Paris, 1958, vol. 237, pp. 328-30.

    Google Scholar 

  42. R. Jary: Ann. Chim. (Paris), 1957, vol. 13, no. 2, pp. 58-104.

    Google Scholar 

  43. W. Gerrard and G.J. Jeacocke: Chem. Ind. (London), 1959, p. 704.

  44. J. Lecompte, A. Boullé, C. Dorémieux-Morin, and B. Lelong: Compt. Rend. Acad. Sci. Paris, 1962, vol. 255, pp. 621-24.

    Google Scholar 

  45. [45] J. Lecompte, A. Boullé, C. Dorémieux-Morin, and B. Lelong: Compt. Rend. Acad. Sci. Paris, 1964, vol. 258, pp. 131-34.

    Google Scholar 

  46. B. Lelong and A. Boullé; Compt. Rend. Acad. Sci. Paris, 1963, vol. 257, pp. 3437-39.

    CAS  Google Scholar 

  47. P. Robinson and E. McCartney: J. Am. Ceram. Soc., 1964, vol. 47, no. 11, pp. 587-92.

    Article  CAS  Google Scholar 

  48. P.H. Hautefeuille and P. Margottet: Compt. Rend. Acad. Sci. Paris, 1883, vol. 96, pp. 1053-54.

    Google Scholar 

  49. P.H. Hautefeuille and P. Margottet: Compt. Rend. Acad. Sci. Paris, 1884, vol. 99, pp. 789-92.

    Google Scholar 

  50. P.H. Hautefeuille and P. Margottet: Compt. Rend. Acad. Sci. Paris, 1886, vol. 102, pp. 1017-19.

    Google Scholar 

  51. G. Bissert and F. Liebau: Fortschr. Mineral., 1966, vol. 42, no. 2, pp. 222-23.

    CAS  Google Scholar 

  52. R. Dupree, D. Holland, M.G. Mortuza, J.A. Collins, and M.W.G. Lockyer: J. Non-Cryst. Solids, 1989, vol. 112, pp. 111-119.

    Article  Google Scholar 

  53. C. Bale, E. Belisle, P. Chartrand, S. Decterov, G. Eriksson, K. Hack, I.-H. Jung, Y.-B. Kang, J. Melancon, A. Pelton, C. Robelin, and S. Petersen: CALPHAD, 2009, vol. 33 (2), pp. 295–11.

  54. M.W. Chase Jr.: NIST-JANAF Thermochemical Tables, 4th ed. Part II, Monograph no. 9, The American Institute of Physics, Woodburry, 1998, pp. 1751–55.

  55. R. Berman and T. Brown: Contrib. Miner. Petrol., 1985, vol. 89, no. 2-3, pp. 168-83.

    Article  CAS  Google Scholar 

  56. S. Saxena, N. Chatterjee, Y. Fei, and G. Shen: Thermodynamic Data on Oxides and Silicates. Springer, New York, 1993, p. 168.

  57. I.-H. Jung and P. Hudon: J. Am. Ceram. Soc., 2012, vol. 95, no. 11, pp. 3665-72.

    Article  CAS  Google Scholar 

  58. E.T. Turkdogan and J. Pearson: J. Iron Steel Inst. London, 1953, vol. 175, pp. 398-401.

    CAS  Google Scholar 

  59. A. Pelton, S. Degterov, G. Eriksson, C. Robelin, and Y. Dessureault: Metall. Trans. B, 2000, vol. 31, pp. 651-59.

    CAS  Google Scholar 

  60. I.-H. Jung: CALPHAD, 2010, vol. 34 (3), pp. 332–62.

  61. J. Wong: J. Non-Cryst. Solids, 1976, vol. 20, pp. 83-100.

    Article  CAS  Google Scholar 

  62. I. N. Chakraborty and R. A. Condrate: Phys. Chem. Glasses, 1985, vol. 26, no. 3, pp. 68-73.

    CAS  Google Scholar 

  63. B. O. Mysen, F. J. Ryerson, and D. Virgo: Am. Mineral, 1981, vol. 66, pp. 106-117.

    CAS  Google Scholar 

  64. N. Shibata, M. Horigudhi and T. Edahiro: J. Non-Cryst. Solids, 1981, vol. 45, pp. 115-126.

    Article  CAS  Google Scholar 

  65. H. Chen, G. Huang, H. Mao, and F. Gan: J. Non-Cryst. Solids, 1986, vol. 80, pp. 152-159.

    Article  CAS  Google Scholar 

  66. D. Li, G.M. Bancroft, M. Kasrai, M.E. Fleet, X. H. Feng and K.H. Tan: Am. Mineral, 1994, vol. 79, pp. 785-788.

    CAS  Google Scholar 

  67. D. Li, M.E. Fleet, G.M. Bancroft, M. Kasrai, and Y. Pan: J. Non-Cryst. Solids, 1995, vol. 188, pp. 181-189.

    Article  CAS  Google Scholar 

  68. V.G. Plotnichenko, V.O. Sokolov, V.V. Koltashev, and E.M. Dianov: J. Non-Cryst. Solids, 2002, vol. 306, pp. 209-26.

    Article  CAS  Google Scholar 

  69. A. Pelton: Metall. Trans. A, 1988, vol. 19A, pp. 1819-25.

    CAS  Google Scholar 

Download references

Acknowledgments

Financial support from a collaborative research grant provided by the Natural Sciences and Engineering Research Council of Canada (NSERC) with Posco, RIST, and Tata Steel Europe (formerly Danieli-Corus) is greatly appreciated. M. Rahman thanks the financial support obtained from a McGill Engineering Doctoral Award (MEDA). We thank Manas Paliwal for help with the XRD.

Author information

Authors and Affiliations

  1. Department of Mining and Materials Engineering, McGill University, 3610 University Street, Montreal, QC, H3A 0C5, Canada

    Miftaur Rahman (Ph.D Student), Pierre Hudon (Research Associate) & In-Ho Jung (Assistant Professor)

Authors
  1. Miftaur Rahman
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Pierre Hudon
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. In-Ho Jung
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to In-Ho Jung.

Additional information

Manuscript submitted September 18, 2012.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rahman, M., Hudon, P. & Jung, IH. A Coupled Experimental Study and Thermodynamic Modeling of the SiO2-P2O5 System. Metall Mater Trans B 44, 837–852 (2013). https://doi.org/10.1007/s11663-013-9847-3

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11663-013-9847-3

Keywords

Search

Navigation