Skip to main content
SpringerLink
Log in

Die Kristallstruktur von Si5O[PO4]6

The crystal structure ofSi 5O[PO4]6

  • Anorganische, Struktur- und Physikalische Chemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

The crystal structure of Si5O[PO4]6 has been determined and refined by least-squares, using three-dimensional X-raydata fromWeissenberg photographs: space group R 3;a=7.869 andc=24.138 Å;Z=3; 418 independent reflections;R=6.0%.

The crystal structure consists of isolated [SiO6] octahedra and [Si2O7] groups which are linked by [PO4] tetrahedra forming a three-dimensional network. The average interatomic distances are: Si[6]−O=1.768, Si[4]−O=1.607 and P−O=1.52i Å. The compound is isotypic with Ge5O[PO4]6.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literatur

  1. H. Mayer undH. Völlenkle, Mh. Chem.103, 1560 (1972).

    Google Scholar 

  2. H. Völlenkle, Dissertation, Universität Wien, 1964.

  3. H. Völlenkle, A. Wittmann undH. Nowotny, Mh. Chem.94, 819 (1963).

    Google Scholar 

  4. T. Y. Tien undF. A. Hummel, J. Amer. Ceram. Soc.45, 422 (1962).

    Google Scholar 

  5. A. Boullé undR. Jary, C. r. hebdomad. Sé. acad. Sci. Paris237, 161 und 328 (1953).

    Google Scholar 

  6. W. Gerrard undG. Jeacocke, Chemistry and Ind. 1959, 704.

  7. G. B. Seifer, J. neorg. Khim.7, 2806 (1962); Chem. Abstr.58, 9855 (1963).

    Google Scholar 

  8. J. Lecomte, A. Boullé, C. Dorémieux-Morin undB. Lelong, C. r. hebdomad. Sé. Acad. Sci. Paris255, 621 (1962);257, 3437 (1963);258 131 (1964).

    Google Scholar 

  9. B. Lelong, Dissertation, Universität Paris, 1964.

  10. H. Makart, Helv. chim. Acta50, 399 (1967).

    Google Scholar 

  11. F. Liebau, G. Bissert undN. Köppen, Z. anorg. allgem. Chem.359, 113 (1968).

    Google Scholar 

  12. R. G. Levi undG. Peyronel, Z. Kristallogr.92, 190 (1935).

    Google Scholar 

  13. E. Tillmanns, W. Gebert undW. H. Baur, Fortschr. Miner.50 (Beiheft 1, 97 (1972).

    Google Scholar 

  14. G. Bissert undF. Liebau, Acta Crysta [Kopenhagen]B 26, 233 (1970).

    Google Scholar 

  15. F. Liebau undK.-F. Hesse, Z. Kristallogr.133, 213 (1971).

    Google Scholar 

  16. International tables for X-ray crystallography. Birmingham: The Kynoch Press. 1959.

  17. E. W. Hughes, J. Amer. Chem. Soc.63, 1737 (1941).

    Google Scholar 

  18. International tables for X-ray crystallography. Vol. 3. Birmingham: The Kynoch Press. 1959.

  19. F. Liebau, Fortschr. Miner.42, 266 (1966).

    Google Scholar 

  20. D. E. C. Corbridge, Bull. Soc. fr. Minéral. Cristallogr.94, 271 (1971).

    Google Scholar 

  21. H. Mayer undH. Völlenkle, Z. Kristallogr.136, 387 (1972).

    Google Scholar 

  22. F. Liebau, Bull. Soc. fr. Minéral. Cristallogr.94, 239 (1971).

    Google Scholar 

  23. J. J. Flynn undF. D. Boer, J. Amer. Chem. Soc.91, 5756 (1969).

    Google Scholar 

  24. S. M. Stishov undN. V. Belov, Dokl. Akad. Nauk SSSR.143, 951 (1962).

    Google Scholar 

  25. A. Preisinger, Naturwiss.49, 345 (1962).

    Google Scholar 

  26. F. Liebau, Acta Cryst. [Kopenhagen]14, 1103 (1961).

    Google Scholar 

  27. D. W. J. Cruickshank, H. Lynton undG. A. Barclay, Acta Cryst. [Kopenhagen]15, 491 (1962).

    Google Scholar 

  28. C. T. Prewitt (persönl. Mitteilung anS. J. Louisnathan undJ. V. Smith, Z. Kristallogr.132, 288 (1970).

    Google Scholar 

  29. R. D. Shannon undL. Katz, Acta Cryst. [Kopenhagen]B 26, 105 (1970).

    Google Scholar 

  30. T. Araki undT. Zoltai, Z. Kristallogr.129, 381 (1969).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut für Mineralogie, Kristallographie und Strukturchemie der Technischen Hochschule Wien, Getreidemarkt 9, A-1060, Wien, Österreich

    H. Mayer

Authors
  1. H. Mayer
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Mit 1 Abbildung

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mayer, H. Die Kristallstruktur von Si5O[PO4]6 . Monatshefte für Chemie 105, 46–54 (1974). https://doi.org/10.1007/BF00911286

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00911286

Search

Navigation