Abstract
Aiming to develop high-strength Al-based alloys with high material index (strength/density) for structural application, this article reports a new class of multiphase Al alloys in the Al-Ni-Cr system that possess impressive room temperature and elevated temperature (≥ 200 °C) mechanical properties. The ternary eutectic and near eutectic alloys display a complex microstructure containing intermetallic phases displaying hierarchically arranged plate and rod morphologies that exhibit extraordinary mechanical properties. The yield strengths achieved at room temperatures are in excess of 350 MPa with compressive plastic strains of more than 30 pct (without fracturing) for these alloys. The stability of the complex microstructure also leads to a yield stress of 191 ± 8 to 232 ± 5 MPa at 250 °C. It is argued that the alloys derive their high strength and impressive plasticity through synergic effects of refined nanoeutectics of two different morphologies forming a core shell type of architecture.
Similar content being viewed by others
Notes
JEOL is a trademark of Japan Electron Optics Ltd., Tokyo.
References
J.R. Davis: Aluminum and Aluminum Alloys, 1993.
T.E. George and S.D. Mackenzie: Handbook of Aluminum: Volume 2: Alloy Production and Materials Manufacturing, CRC Press, Boca Raton, FL, 2003.
W.C. Hagel: Corrosion, 1965, vol. 21, pp. 316–26.
G.C. Wood: Oxid. Met., 1970, vol. 2, pp. 11–57.
R. Prescott and M.J. Graham: Oxid. Met., 1992, vol. 38, pp. 233–54.
W.R. Osório, L.C. Peixoto, M.V. Canté, and A. Garcia: Electrochimica Acta, 2010, vol. 55, pp. 4078–85.
W.R. Osório, J.E. Spinelli, C.R.M. Afonso, L.C. Peixoto, and A. Garcia: Electrochimica Acta, 2012, vol. 69, pp. 371–78.
H.E. Hu, L. Zhen, L. Yang, W.Z. Shao, and B.Y. Zhang: Mater. Sci. Eng. A, 2008, vol. 488, pp. 64–71.
E.R. Wang, X.D. Hui, and G.L. Chen: Mater. Des., 2011, vol. 32, pp. 4333–40.
H.E. Hu, X. Wang, and L. Deng: Mater. Sci. Eng. A, 2013, vol. 576, pp. 45–51.
I.R. Hughes and H. Jones: J. Mater. Sci., 1976, vol. 11, pp. 1781–93.
J.D. Cotton and M.J. Kaufman: Metall. Trans. A, 1991, vol. 22A, pp. 927–34.
P. Gilgien, A. Zryd, and W. Kurz: Acta Metall. Mater., 1995, vol. 43, pp. 3477–87.
G.A. Chadwick: Progr. Mater. Sci., 1963, vol. 12, pp. 99–182.
B. Cantor and G.A. Chadwick: J. Cryst. Growth, 1974, vol. 23, pp. 12–20.
B. Cantor and G.A. Chadwick: J. Cryst. Growth, 1975, vol. 30, pp. 101–08.
C.S. Tiwary, D.R. Mahapatra, and K. Chattopadhyay: Appl. Phys. Lett., 2012, vol. 101, p. 171901.
B. Cantor, G.J. May, and G.A. Chadwick: J. Mater. Sci., 1973, vol. 8, pp. 830–38.
B. Cantor and G.A. Chadwick: J. Mater. Sci., 1975, vol. 10, pp. 578–88.
J.H. Tregilgas and T.Z. Kattamis: J. Mater. Sci., 1976, vol. 11, pp. 1239–45.
A. Misra, Z.L. Wu, M.T. Kush, and R. Gibala: Mater. Sci. Eng. A, 1997, vol. 239–240, pp. 75–87.
A. Misra, Z.L. Wu, M.T. Kush, and R. Gibala: Philos. Mag. A, 1998, vol. 78, pp. 533–50.
J.M. Park, N. Mattern, U. Kühn, J. Eckert, K.B. Kim, W.T. Kim, K. Chattopadhyay, and D.H. Kim: J. Mater. Res., 2009, vol. 24, pp. 2605–09.
J.M. Park, K.B. Kim, D.H. Kim, N. Mattern, R. Li, G. Liu, and J. Eckert: Intermetallics, 2010, vol. 18, pp. 1829–33.
S.W. Sohn, J.M. Park, W.T. Kim, and D.H. Kim: J. Alloys Compd., 2012, vol. 541, pp. 14–17.
G.J. Fan, H. Choo, P.K. Liaw, and E.J. Lavernia: Acta Mater., 2006, vol. 54, pp. 1759–66.
C.S. Tiwary, S. Kashyap, and K. Chattopadhyay: Scripta Mater., 2014, vol. 93, pp. 20–23.
C.S. Tiwary, S. Kashyap, D.H. Kim, and K. Chattopadhyay: Mater. Sci. Eng. A, 2015, vol. 639, pp. 359–69.
J. Das, K.B. Kim, F. Baier, W. Löser, and J. Eckert: Appl. Phys. Lett., 2005, vol. 87, p. 161907.
L.C. Zhang, J. Das, H.B. Lu, C. Duhamel, M. Calin, and J. Eckert: Scripta Mater., 2007, vol. 57, pp. 101–04.
J.H. Han, K.B. Kim, S. Yi, J.M. Park, S.W. Sohn, T.E. Kim, D.H. Kim, J. Das, and J. Eckert: Appl. Phys. Lett., 2008, vol. 93, p. 141901.
D.N. Compton, L.A. Cornish, and M.J. Witcomb: J. Alloys Compd., 2001, vols. 317–318, pp. 372–78.
J.D. Hunt and K.A. Jackson: Trans. TMS-AIME, 1966, vol. 236, pp. 843–52.
K.A. Jackson and J.D. Hunt: Trans. TMS-AIME, 1966, vol. 236, pp. 1129–42.
L. Liu, J.F. Li, and Y.H. Zhou: Acta Mater., 2009, vol. 57, pp. 1536–45.
P. Pandey, C.S. Tiwary, and K. Chattopadhyay: J. Electron. Mater., 2016, vol. 45, pp. 5468–77.
K.B. Kim, J. Das, W. Xu, Z.F. Zhang, and J. Eckert: Acta Mater., 2006, vol. 54, pp. 3701–11.
J.M. Park, D.H. Kim, K.B. Kim, and J. Eckert: Appl. Phys. Lett., 2010, vol. 97, p. 251915.
J.T. Kim, S.H. Hong, H.J. Park, Y.S. Kim, G.H. Park, J.-Y. Park, N. Lee, Y. Seo, J.M. Park, and K.B. Kim: Mater. Des., 2015, vol. 76, pp. 190–95.
Acknowledgments
The authors acknowledge the Department of Science and Technology, India, for providing the financial support, and the Advanced Facility for Microscopy and Microanalysis at IISc, Bangalore, for making available the microscopy facility.
Author information
Authors and Affiliations
Corresponding author
Additional information
Manuscript submitted May 3, 2017.
Electronic Supplementary Material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Pandey, P., Kashyap, S., Tiwary, C.S. et al. Development of High-Strength High-Temperature Cast Al-Ni-Cr Alloys Through Evolution of a Novel Composite Eutectic Structure. Metall Mater Trans A 48, 5940–5950 (2017). https://doi.org/10.1007/s11661-017-4369-2
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11661-017-4369-2