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Intergranular Corrosion of Σ9 Copper Bicrystal with Gradually Changed Misorientation in Young’s Dislocation Etchant

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Abstract

The allowable deviation to preserve the “specialness” of a coincident site lattice (CSL) boundary was shown using a pure copper bicrystal which was designed to have gradually changed deviation around 〈110〉 axis from near-ideal Σ9{221} to a random relation. The grain boundary preserved immunity to grain boundary corrosion in Young’s dislocation etchant until the deviation reached the angle where the misfit dislocation spacing is supposed to decrease to CSL dimension. This underlies the common principle of the Brandon-type criteria of CSL.

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Authors and Affiliations

  1. Department of Mechanical Engineering, Faculty of Science and Engineering, Doshisha University, Kyotanabe, Kyoto, 610-0321, Japan

    Yuhei Takehara (Graduate Student) & Hiroshi Fujiwara (Associate Professor)

  2. Department of Mechanical Engineering, Faculty of Science and Engineering, Doshisha University, 1-3 Miyakodani Tatara, Kyotanabe, Kyoto, 610-0394, Japan

    Hiroyuki Miyamoto (Professor)

Authors
  1. Yuhei Takehara
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  2. Hiroshi Fujiwara
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  3. Hiroyuki Miyamoto
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Corresponding author

Correspondence to Hiroyuki Miyamoto.

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Manuscript submitted February 25, 2013.

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Takehara, Y., Fujiwara, H. & Miyamoto, H. Intergranular Corrosion of Σ9 Copper Bicrystal with Gradually Changed Misorientation in Young’s Dislocation Etchant. Metall Mater Trans A 44, 3685–3689 (2013). https://doi.org/10.1007/s11661-013-1748-1

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  • DOI: https://doi.org/10.1007/s11661-013-1748-1

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