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Insights into facile synthesized pomelo biochar adsorbing thallium: potential remediation in agricultural soils

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Abstract

Little information is available on thallium (Tl) adsorption onto fruit-derived biochar. In this study, pomelo peel and waste pomelo were thus chosen to prepare two kinds of biochars recorded as PPB and WPB. The two produced biochars subsequently evaluated their potential remediation of thallium (Tl) contamination in agricultural soils by their Tl adsorption capacity. Results showed that the two pomelo-derived biochars presented obvious microporous structure and rich oxygen-containing functional group, supported by the observant data of specific surface area, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and X-ray diffraction (XRD). Furthermore, Langmuir isothermal adsorption model can better fit the adsorption behavior of thallium onto PPB and WPB, and the subsequent maximum adsorption capacity was 4283.9 μg g−1 and 5286.0 μg g−1, respectively. In addition, the pseudo-second-order kinetic model could well fit the kinetic behavior of thallium adsorption onto PPB and WPB, indicating that the process is accompanied by chemical adsorption. Meanwhile, in agricultural soils, PPB and WPB can be used as environmentally friendly adsorbents to remediate Tl contamination due to their pH increase of the tested soils and their comparable adsorption ability of Tl. The obtained findings can provide insights into comprehensively developed fruit-derived biochar technology to remediate Tl contamination in agricultural soils.

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Acknowledgments

We would like to thank the anonymous reviewers for their helpful comments.

Funding

This study was supported by the Natural Science Foundation of Fujian Province of China (2018J01473) and the STS project of the Chinese Academy of Sciences in Fujian province (2018T3016).

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Authors and Affiliations

  1. College of Food and Biological Engineering, Jimei University, Xiamen, 361021, China

    Chunbai Gao, Yang Lin, Han Zhao & Yicheng Huang

  2. College of Port and Environmental Engineering, Jimei University, Xiamen, 361021, China

    Yinglan Cao, Jianqing Lin & Hongda Fang

  3. Key Laboratory of Urban Environment and Health, Institute of Urban Environment,, Chinese Academy of Sciences, Xiamen, 361021, China

    Zhuanxi Luo

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  1. Chunbai Gao
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  2. Yinglan Cao
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Correspondence to Yinglan Cao.

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Gao, C., Cao, Y., Lin, J. et al. Insights into facile synthesized pomelo biochar adsorbing thallium: potential remediation in agricultural soils. Environ Sci Pollut Res 27, 22698–22707 (2020). https://doi.org/10.1007/s11356-020-08595-6

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