Abstract
Large amount of drilling wastewater was generated during the exploitation of oil and gas field, which contains high concentration of suspended solids and organic matter. The reuse of drilling wastewater was an important way to solve the problem of water shortage during the development of oil and gas field. Therefore, hybrid ozonation-coagulation (HOC) as an integrated water treatment process was applied for the treatment of secondary effluent of drilling wastewater, which combines ozonation and coagulation in one reactor. During the HOC reaction, lots of ozone microbubble flocs were generated. Under the optimal conditions of pH 7, polyaluminum chloride (PAC) dosage 40 mg Al/L, ozone dosage 0.8 mg/L and reaction duration for 15 min, the removal efficiency of UV254, UV280 and DOC reached 20.07%, 37.97% and 14.51%, respectively. Benzene ring, proteins and humic acids were greatly reduced according to fluorescence analysis. The Fourier transform infrared spectrometer (FT-IR) analysis results showed that adsorption and interphase transfer to ozone microbubble flocs were the major mechanism for C-O functional groups removal. Enhanced decreased proportion of oxygen-containing groups can be observed in the effluent of drilling wastewater treated by ozone microbubble flocs compared with conventional microbubble flocs based on X-ray photoelectron spectroscopy (XPS) analysis. However, the ratio of oxygen-containing groups increased after the treatment of microbubble ozone, which implied that the synergistic effect during the treatment using ozone microbubble flocs, which involved oxidation, adsorption and flotation.
Similar content being viewed by others
Data Availability
Data will be made available on request.
References
Adams, M., Campbell, I., & Robertson, P. (2008). Novel photocatalytic reactor development for removal of hydrocarbons from water. International Journal of Photoenergy, 2008, 1–7.
Chiang, P.-C., Chang, E. E., Chang, P.-C., et al. (2009). Effects of pre-ozonation on the removal of THM precursors by coagulation. Science of the Total Environment, 407(21), 5735–5742.
Deng, S., Bai, R., Chen, J. P., et al. (2002). Produced water from polymer flooding process in crude oil extraction: Characterization and treatment by a novel crossflow oil–water separator. Separation and Purification Technology, 29(3), 207–216.
Estrada, J. M., & Bhamidimarri, R. (2016). A review of the issues and treatment options for wastewater from shale gas extraction by hydraulic fracturing. Fuel, 182, 292–303.
Farvardin, M. R., & Collins, A. G. (1989). Preozonation as an aid in the coagulation of humic substances—Optimum preozonation dose. Water Research, 23(3), 307–316.
Fujishima, A., & Honda, K. (1972). Electrochemical photolysis of water at a semiconductor electrode. Nature, 238(5358), 37–38.
Georgantas, D. A., & Grigoropoulou, H. P. (2007). Orthophosphate and metaphosphate ion removal from aqueous solution using alum and aluminum hydroxide. Journal of Colloid and Interface Science, 315(1), 70–79.
He, Y., Wang, X., Xu, J., et al. (2013). Application of integrated ozone biological aerated filters and membrane filtration in water reuse of textile effluents. Bioresource Technology, 133, 150–157.
Hu, E., Shang, S., Tao, X. M., et al. (2016). Regeneration and reuse of highly polluting textile dyeing effluents through catalytic ozonation with carbon aerogel catalysts. Journal of Cleaner Production, 137(20), 1055–1065.
Huang, G., Xiao, Z., Zhen, W., et al. (2020). Hydrogen production from natural organic matter via cascading oxic-anoxic photocatalytic processes: An energy recovering water purification technology. Water Research, 175, 115684.
Igwe, C. O., Saadi, A. A. (2013). Optimal options for treatment of produced water in offshore petroleum platforms. Journal of Pollution Effects & Control, 1(01), 127–132.
Janks, J. S., & Cadena, F. (1992). Investigations into the Use of Modified Zeolites for Removing Benzene, Toluene, and Xylene from Saline Produced Water. Springer.
Jin, P., Jin, X., Bjerkelund, V. A., et al. (2016). A study on the reactivity characteristics of dissolved effluent organic matter (EfOM) from municipal wastewater treatment plant during ozonation. Water Research, 88, 643–652.
Jin, X., Jin, P., Hou, R., et al. (2017). Enhanced WWTP effluent organic matter removal in hybrid ozonation-coagulation (HOC) process catalyzed by Al-based coagulant. Journal of Hazardous Materials, 327, 216–224.
Jin, X., Wang, Y., Zhang, W., et al. (2019). Mechanism of the hybrid ozonation-coagulation (HOC) process: Comparison of preformed Al13 polymer and in situ formed Al species. Chemosphere, 229, 262–272.
Jin, X., Liu, Y., Wang, Y., et al. (2020). Towards a comparison between the hybrid ozonation-coagulation (HOC) process using Al- and Fe-based coagulants: Performance and mechanism. Chemosphere, 253, 126625.
Jin, X., Zhang, S., Yang, S., et al. (2021a). Behaviour of ozone in the hybrid ozonation-coagulation (HOC) process for ibuprofen removal: Reaction selectivity and effects on coagulant hydrolysis. Science of the Total Environment, 794, 148685.
Jin, X., Xie, X., Zhang, S., et al. (2021b). Insights into the electro-hybrid ozonation-coagulation process-Significance of connection configurations and electrode types. Water Research, 204, 117600.
Jin, X., Zhang, L., Liu, M., et al. (2022). Characteristics of dissolved ozone flotation for the enhanced treatment of bio-treated drilling wastewater from a gas field. Chemosphere, 298, 134290.
Leenheer, J. A. (1981). Comprehensive approach to preparative isolation and fractionation of dissolved organic carbon from natural waters and wastewaters. Environmental Science & Technology, 15(5), 578–587.
Li, M., Chen, Z., Wang, Z., et al. (2019). Investigation on degradation behavior of dissolved effluent organic matter, organic micro-pollutants and bio-toxicity reduction from secondary effluent treated by ozonation. Chemosphere, 217, 223–231.
Liu, B., Gao, Y., Pan, J., et al. (2022). Coagulation behavior of polyaluminum-titanium chloride composite coagulant with humic acid: A mechanism analysis. Water Research, 220, 118633.
Machado, W., Franchini, J. C., de Fatima, G. M., et al. (2020). Spectroscopic characterization of humic and fulvic acids in soil aggregates, Brazil. Heliyon, 6(6), e04078.
Marhaba, T. F., Van, D., & Lippincott, R. L. (2000). Changes in NOM fractionation through treatment: A comparison of ozonation and chlorination. Ozone Science & Engineering, 22(3), 249–266.
Naceradska, J., Pivokonsky, M., Pivokonska, L., et al. (2017). The impact of pre-oxidation with potassium permanganate on cyanobacterial organic matter removal by coagulation. Water Research, 114, 42–49.
Oliveira, C., & Rubio, J. (2012). A short overview of the formation of aerated flocs and their applications in solid/liquid separation by flotation. Minerals Engineering, 39, 124–132.
Tekle-Roettering, A., Von Sonntag, C., Reisz, E., et al. (2016). Ozonation of anilines: Kinetics, stoichiometry, product identification and elucidation of pathways. Water Research, 98, 147–159.
Zhou, F. S., Dang, Y. S., & Lu, F. J. (2000). Inorganic polymeric flocculant FMA for purifying oilfield produced water: Preparation and uses. Oilfield Chemistry, 17(3), 256–259.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of Interest
The authors declare that they have no conflict of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.
About this article
Cite this article
Li, Y., Tong, X., Xi, J. et al. Application of Dissolved Ozone Flotation in the Advanced Treatment of Drilling Wastewater in Gas Field: Significance of Ozone Microbubble Flocs. Water Air Soil Pollut 235, 327 (2024). https://doi.org/10.1007/s11270-024-07147-9
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11270-024-07147-9