Abstract
Wide use of dyes in production of fabric becomes the most problematic and generates high amount of liquid effluent pollutants to the surface water. The potential of waste materials, pineapple (Ananas comosus) leaf powder and lime (Citrus aurantifolia) peel powder, to remove Remazol Brilliant Blue R (RBBR) from aqueous solution through adsorption process was investigated. Batch experiments were conducted at initial dye concentration of 500 mg/L. Data analysis showed a removal percentage more than 90 %. The Langmuir, Freundlich, and Temkin isotherm models were also investigated to study the mechanism of dye molecules onto adsorption process. The optimum equilibrium was obtained by the Langmuir isotherm (R 2 = 0.9945) for pineapple leaves and (R 2 = 0.9994) for lime peel. The maximum monolayer adsorption capacity adsorbents onto RBBR (9.58 mg/g) were achieved. The pseudo-second-order kinetic indicates that the rate constant was 1.00. The specific area of both adsorbents was identified as homogenous structure and was characterized by field emission scanning electron microscopy (FESEM) analysis. The surface functional groups responsible for dye uptake by adsorbents indicate that both adsorbents were defined as carboxyl group which consists of carbonyl and hydroxyl groups and were analyzed by Fourier transform infrared spectrometry (FTIR) analysis. The overall study indicates that adsorbents prepared from pineapple leaves and lime peels are alternative low-cost product in dye removal from aqueous solution.
Similar content being viewed by others
References
Ahmad, M. A. (2011). Optimization of rambutan peel based activated carbon preparation conditions for Remazol Brilliant Blue R removal. Chemical Engineering Journal, 168, 280–285.
Demiral, H., Demiral, I., Tumsek, F., & Karabacakoglu, B. (2008). Adsorption of chromium (VI) from aqueous solution by activated carbon derived from olive bagasse and applicability of different adsorption models. Chemical Engineering Journal, 144, 188–196.
Dogan, M., Abak, H., & Alkan, M. (2008). Biosorption of methylene blue from aqueous solutions by hazelnut shells: equilibrium, parameters and isotherms. Water, Air, and Soil Pollution, 192, 141–153.
Doulati Ardejani, F., Badii, K., Yousefi Limaee, N., Shafaei, S. Z., & Mirhabibi, A. R. (2008). Adsorption of Direct Red 80 dyes from aqueous solution on to almond shells: effect of pH, initial concentration and shell type. Journal of Hazardous Materials, 151, 730–737.
Eichlerova, I., Homolka, L., Benada, O., Kofronova, O., Hubalek, T., & Nerud, F. (2007). Decolorization of Orange G and Remazol Brilliant Blue R by the white rot fungus Dichomittus squalens: toxicological evaluation and morphological study. Chemosphere, 69, 795–802.
Ergene, A., Ada, K., Tan, S., & Katircioglu, H. (2009). Removal of Remazol Brilliant Blue R dye from aqueous solution by adsorption onto immobilized Scenedesmus quadricauda: equilibrium and kinetic modeling studies. Desalination, 249, 1308–1314.
Gupta, S. K. S., Mishra, S., Rani, V. R., & Arvind, U. (2012). General acid catalysts in benzoic acid-crystal violet carbinol base reactions in toluene. International Journal of Chemical Kinetics, 44, 570–576.
Hadibarata, T., Adnan, L. A., Yusoff, A. R. M., Yuniarto, A., Rubiyatno, Zubir, M. M. F. A., Khudhair, A. B., & Abu Naser, M. (2013). Microbial decolorization of an azo dye Reactive Black 5 using white-rot fungus Pleurotus eryngii F032. Water Air Soil Pollut, 224, 1595–1604.
Hadibarata, T., & Kristanti, R. A. (2013). Biodegradation and metabolite transformation of pyrene by basidiomycetes fungal isolate Armillaria sp. F022. Bioprocess and Biosystems Engineering, 36, 461–468.
Hameed, B. H., Mahmood, D. K., & Ahmad, A. L. (2008). Sorption of basic dye from aqueous solution by pomelo (Citrus grandis) peel in a batch system. Colloid Surface A, 316, 78–84.
Han, X., Wang, W., & Ma, X. (2011). Adsorption characteristics of methylene blue onto low cost biomass material lotus leaf. Chemical Engineering Journal, 171, 1–8.
Hirata, M., Kawasaki, N., Nakamura, T., Matsumoto, K., Kabayama, M., Tamura, T., & Tanada, S. (2002). Adsorption of dyes onto carbonaceous materials produced from coffee grounds by microwave treatment. Journal of Colloid and Interface Science, 254, 17–22.
Kant, R. (2012). Adsorption of dye eosin from an aqueous solution on two different samples of activated carbon by static batch method. Journal of Water Resource and Protection, 4, 93–98.
Keng, P. S., Lee, S. L., Ha, S. T., Hung, Y. T., & Ong, S. T. (2013). Removal of hazardous heavy metals from aqueous environment by low-cost adsorption materials. Environmental Chemistry Letters, 12, 15–25.
Kumar, P. S., Ramalingam, S., & Sathishkumar, K. (2011). Removal of methylene blue dye from aqueous solution by activated carbon prepared from cashew nut shell as a new low-cost adsorbent. Korean Journal of Chemical Engineering, 28, 149–155.
Lazim, Z. M., Hadibarata, T., Puteh, M.H., Yusop, Z., (2015a) Adsorption characteristics of Bisphenol A onto low cost modified phyto-waste material in aqueous solution. Water, Air, and Soil Pollution, 226(34), 1–11.
Lazim, Z. M., Mazuin, E., Hadibarata, T., & Yusop, Z. (2015b). The removal of methylene blue and Remazol Brilliant Blue R dyes by using orange peel and spent tea leaves. Journal Teknologi, 74, 129–135.
Mafra, M. R., Igarashi-Mafra, L., Zuim, D. R., Vasques, E. C., & Ferreira, M. A. (2013). Adsorption of Remazol Brilliant Blue on an orange peel adsorbent. Brazilian Journal of Chemical Engineering, 30, 657–665.
Nor, N. M., Hadibarata, T., Yusop, Z., & Lazim, Z. M. (2015). Removal of brilliant green and procion red dyes from aqueous solution by adsorption using selected agricultural wastes. Journal Teknologi., 74, 117–122.
Pelosi, B. T., Lima, L. K. S., & Vieira, M. G. A. (2014). Removal of the synthetic dye Remazol Brilliant Blue R from textile industry wastewaters by biosorption on the macrophyte Salvinia natans. Brazilian Journal of Chemical Engineering, 31, 1035–1045.
Ponnusami, V., Vikiram, S., & Srivastava, S. N. (2008). Guava (Psidium guajava) leaf powder: novel adsorbent for removal of methylene blue from aqueous solutions. Journal of Hazardous Materials, 152, 276–286.
Ramaraju, B., Reddy, P. M. K., & Subrahmanyam, C. (2013). Low cost adsorbents from agricultural waste for removal of dyes. Environmental Progress & Sustainable Energy, 33, 38–46.
Robinson, T., McMullan, G., Marchant, R., Nigam, P. (2001). Remidiation of dyes in textile effluent, a critical review on current treatment technologies with a proposed alternative. Bioresource Technology, 77, 247–255.
Tanyildizi, M. S. (2011). Modeling of adsorption isotherms and kinetics of reactive dye from aqueous solution by peanut hull. Chemical Engineering Journal, 168, 1234–1240.
Wirasnita, R., Hadibarata, T., Yusoff, A. R. M., & Yusop, Z. (2014). Removal of bisphenol A from aqueous solution by activated carbon derived from oil palm empty fruit bunch. Water, Air, and Soil Pollution, 225(2148), 1–12.
Wirasnita, R., Hadibarata, T., Yusoff, A. R. M., & Lazim, Z. M. (2015). Preparation and characterization of activated carbon from oil palm empty fruit bunch wastes using zinc chloride. Journal Teknologi, 74, 77–81.
Acknowledgments
The authors would like to acknowledge the Ministry of Education Malaysia (R.J130000.7809.4 F465) and Universiti Teknologi Malaysia (Q.J130000.2522.10H17) as financial support of this project.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Rahmat, N.A., Ali, A.A., Salmiati et al. Removal of Remazol Brilliant Blue R from Aqueous Solution by Adsorption Using Pineapple Leaf Powder and Lime Peel Powder. Water Air Soil Pollut 227, 105 (2016). https://doi.org/10.1007/s11270-016-2807-1
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11270-016-2807-1