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The Differentiation between Point and Diffuse Industrial Pollution of the Floodplain of the Ploučnice River, Czech Republic

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Abstract

Pollution by heavy metals (Co, Cu, Ni, Pb, Sb and Zn), 226Ra and U was studied in eight profiles (1.0–1.8 m deep) in the floodplain sediments of the Ploučnice River, the Czech Republic. The element concentrations were processed by establishing local geochemical background functions from non-polluted overbank fines yet not affected by reductimorphic processes and a subsequent calculation of enrichment factors in the polluted strata. In the case of Cu and Ni, the geogenic variability of the watershed (Cretaceous marine sediments and Cenozoic volcanics and their weathering products) was successfully handled using different background functions in two parts of the studied area, which allowed us to decipher the anthropogenic and natural portions of the heavy metals and hence evaluate the history of pollution. The upper course of the river drains an extensive area of so-called chemical mining (underground acid leaching of low-grade U-bearing sediments) and hydrometallurgical processing in Stráž pod Ralskem that started in the late 1960s and operated without waste-processing plants up to 1989. The river system has consequently been impacted by U and gamma-emitting 226Ra and obviously also by divalent heavy metals (Co, Ni, Zn). In the entire study area, that pollution was preceded by increasing levels of Cu, Pb and Sb and by the 206Pb/207Pb ratio decreasing from 1.20 towards 1.17, which had started earlier in the twentieth century before the U mining. That pre-mining pollution can be attributed to diffuse anthropogenic activities of regional or continental importance. The most recent 206Pb/207Pb ratio in the Ploučnice alluvium coincides with that of peatbog profiles on the borders of the Czech Republic, showing the usefulness of floodplains as pollution archives of widespread regional to continental pollution signals.

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Acknowledgment

Laboratory sample processing and analyses were mostly performed by P. Vorm, R. Barochová and Z. Hájková (IIC Řež). T. Nováková (IIC Řež) helped with data processing and graphical presentation. Institutional funding in IIC (RVO 61388980) was essential for this work. The geoinformatic work, ICP and radiochemical analyses were funded by OPVK project ENVIMOD (CZ.1.07/2.2.00/28.0205).

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Authors and Affiliations

  1. Faculty of Environment, J. E. Purkyně University in Ústí nad Labem, Ústí nad Labem, Czech Republic

    L. Majerová, T. Matys Grygar & J. Elznicová

  2. Institute of Inorganic Chemistry AS CR, v.v.i, Řež, Czech Republic

    T. Matys Grygar

  3. Faculty of Science, Charles University, Prague, Czech Republic

    L. Strnad

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  1. L. Majerová
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  2. T. Matys Grygar
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  3. J. Elznicová
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Correspondence to T. Matys Grygar.

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Majerová, L., Matys Grygar, T., Elznicová, J. et al. The Differentiation between Point and Diffuse Industrial Pollution of the Floodplain of the Ploučnice River, Czech Republic. Water Air Soil Pollut 224, 1688 (2013). https://doi.org/10.1007/s11270-013-1688-9

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