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Study on Changes in the Rheologic Properties of EHL Film Using Fluorescence Measurements

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Abstract

This article describes a fundamental study using the fluorescence measurement method to understand the rheologic properties (such as viscosity and solidification) of elasto-hydrodynamic lubrication (EHL) film. The measurement principle is based upon the excimer emission of a pyrene fluorescence agent, which depends on the viscosity. To investigate the relationship between the excimer emission and viscosity, the measurements were taken under low temperature, with the results showing that the excimer emission decreased with decreasing temperature because of increasing of viscosity. No remarkable peak was observed below the temperature at which the state changed from liquid into a viscoelastic or elastic–plastic solid. The fluorescence was clearly observed in EHL film, and its spectrum revealed that the intensity of excimer emission decreases along the flow direction, with a contact area having the same behavior as that of the elastic–plastic solid at 243 K. These results suggest that the viscosity increased at the inlet of contact because of increasing hydrodynamic pressure under the wedge action and that the state in the contact region changes to solid because of high contact pressure. This study also proposes that this measurement method can be used to understand the viscosity change and solidification in the lubrication film.

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References

  1. Dowson, D., Higginson, G.R.: Elasto-hydrodynamic Lubrication, The Fundamentals of Roller and Gear Lubrication. Pergamon Press, London (1966)

    Google Scholar 

  2. Cameron, A., Gohar, R.: Theoretical and experimental studies of the oil film in lubricated point contact. Proc. R. Soc. Lond. A 291, 520–536 (1966)

    Article  Google Scholar 

  3. Foord, C.A., Wedeven, L.D., Westlake, F.J., Cameron, A.: Optical elastohydrodynamics. Proc. IMechE 184(1), 487–505 (1969–1970)

  4. Johnston, G.J., Wayte, R., Spikes, H.A.: The measurement and study of very thin lubricant films in concentrated contacts. Tribol. Trans. 34(2), 187–194 (1991)

    Article  Google Scholar 

  5. Gustafsson, L., Höglund, E., Marklund, O.: Measuring lubricant film thickness with image analysis. Proc. IMechE Part J J. Eng. Tribol. 208, 199–205 (1994)

    Article  Google Scholar 

  6. Cann, P.M., Spikes, H.A., Hutchinson, J.: The development of a spacer layer imaging method (SLIM) for mapping elastohydrodynamic contacts. Tribol. Trans. 39(4), 915–921 (1996)

    Article  Google Scholar 

  7. Hamrock, B.J., Dowson, D.: Ball Bearing Lubrication. Wiley, New York (1981)

    Google Scholar 

  8. Venner, C.H., Lubrecht, A.A.: Multilevel Methods in Lubrication, Tribology Series 37. Elsevier, Amsterdam (2000)

    Google Scholar 

  9. Spikes, H.A.: The behavior of lubricants in contacts: current understanding and future possibilities. Proc. IMechE Part J J. Eng. Tribol. 208, 3–15 (1994)

    Article  Google Scholar 

  10. Alsaad, M., Bair, S., Sanborn, D.M., Winer, W.O.: Glass transitions in lubricants: its relation to elastohydrodynamic lubrication (EHD). Trans. ASME J. Lubr. Technol. 100, 404–417 (1978)

    Article  Google Scholar 

  11. Ponjavic, A., di Mare, L., Wong, J.S.S.: The effect of pressure on the flow behavior of polybutene. J. Polym. Sci. Part B Polym. Phys. 52, 708–715 (2014)

    Article  Google Scholar 

  12. ASME: A Report of the ASME Research Committee on Lubrication, Pressure Viscosity Report, vols. 1&2. ASME, New York (1953)

  13. Alsaad, M.A., Winer, W.O., Medina, F.D., O’Shea, D.C.: Light scattering study of the glass transition in lubricants. Trans. ASME J. Lubr. Technol. 100, 418–422 (1978)

    Article  Google Scholar 

  14. Ohno, N.: High-pressure behavior of toroidal CVT fluid for automobile. Tribol. Int. 40, 233–238 (2007)

    Article  Google Scholar 

  15. Yasutomi, S., Bair, S., Winer, W.O.: An application of a free volume model to lubricant rheology I—dependence of viscosity on temperature and pressure. Trans. ASME J. Tribol. 106, 291–303 (1984)

    Article  Google Scholar 

  16. Yasutomi, S., Bair, S., Winer, W.O.: An application of a free volume model to lubricant rheology 2—variation in viscosity of binary blended lubricants. Trans. ASME J. Tribol. 106, 304–312 (1984)

    Article  Google Scholar 

  17. Ohno, N., Hattori, N., Kuwano, N., Hirano, F.: Some observations on the relationship between rheological properties of lubricants at high pressure and regimes of traction (part 1) –The rheological properties of lubricants at high pressure. J. Jpn. Soc. Lubr. Eng. 33(12), 922–928 (1988). (in Japanese)

    Google Scholar 

  18. Ohno, N., Sunahara, K., Kumamoto, T., Hirano, F.: Predictions of liquid lubricant viscosity at high pressure from the density measurements. J. Jpn. Soc. Tribol. 44(7), 560–566 (1999). (in Japanese)

    Google Scholar 

  19. Ausherman, V.K., Nagaraj, N.S., Sanborn, D.M., Winer, W.O.: Infrared temperature mapping in elastohydrodynamic lubrication. Trans. ASME J. Lubr. Technol. 98, 236–243 (1976)

    Article  Google Scholar 

  20. Lauer, J.L., Peterkin, M.E.: Infrared emission spectra of elastohydrodynamic contacts. Trans. ASME J. Lubr. Technol. 98, 230–235 (1976)

    Article  Google Scholar 

  21. Nagaraj, H.S., Sanborn, D.M., Winer, W.O.: Effects of load, speed, and surface roughness on sliding EHD contact temperatures. Trans. ASME J. Lubr. Technol. 99, 254–263 (1977)

    Article  Google Scholar 

  22. Imado, K., Kido, Y., Miyagawa, H., Hirano, F.: A study of temperature rise in oil due to compression. Proc. IMechE Part J J. Eng. Tribol. 212(4), 291–299 (1998)

    Article  Google Scholar 

  23. Yagi, K., Kyogoku, K., Nakahara, T.: Relationship between temperature distribution in EHL film and dimple formation. Trans. ASME J. Tribol. 127, 658–665 (2005)

    Article  Google Scholar 

  24. Reddyhoff, T., Spikes, H.A., Olver, A.V.: Compression heating and cooling in elastohydrodynamic contacts. Tribol. Lett. 36, 69–80 (2009)

    Article  Google Scholar 

  25. Cann, P.M., Spikes, H.A.: In lubro studies of lubricants in EHD contacts using FTIR absorption spectroscopy. Tribol. Trans. 34(2), 248–256 (1991)

    Article  Google Scholar 

  26. Hoshi, Y., Shimotomai, N., Sato, M., Mori, S.: Change of concentration of additives under EHL condition—observation by micro-FTIR. J. Jpn. Soc. Tribol. 44(9), 736–743 (1999). (in Japanese)

    Google Scholar 

  27. Yagi, K., Vergne, P., Nakahara, T.: In situ pressure measurements in dimpled elastohydrodynamic sliding contacts by Raman microspectroscopy. Tribol. Int. 42, 724–730 (2009)

    Article  Google Scholar 

  28. Kaneta, M., Nishikawa, H., Kanda, T., Matsuda, K.: Abnormal phenomena appearing in EHL contacts. Trans. ASME J. Tribol. 118, 886–892 (1996)

    Article  Google Scholar 

  29. Cann, P.M., Spikes, H.A.: Determination of the shear stresses of lubricants in elastohydrodynamic contacts. Tribol. Trans. 32(3), 414–422 (1989)

    Article  Google Scholar 

  30. Glovnea, R.P., Spikes, H.A.: Mapping shear stress in elastohydrodynamic contacts. Tribol. Trans. 38(4), 932–940 (1995)

    Article  Google Scholar 

  31. Spikes, H.A., Anghel, V., Glovnea, R.: Measurement of the rheology of lubricant films within elastohydrodynamic contacts. Tribol. Lett. 17(3), 593–605 (2004)

    Article  Google Scholar 

  32. Smart, A.E., Ford, R.A.J.: Measurement of thin liquid films by a fluorescence technique. Wear 29, 41–47 (1974)

    Article  Google Scholar 

  33. Ford, R.A.J., Foord, C.A.: Laser based fluorescence techniques for measuring thin liquid films. Wear 51, 289–297 (1978)

    Article  Google Scholar 

  34. Ting, L.L.: Development of a laser fluorescence technique for measuring piston ring oil film thickness. Trans. ASME J. Lubr. Technol. 102, 165–171 (1980)

    Article  Google Scholar 

  35. Sato, Y., Toda, A., Nakamura, K., Yamamoto, Y.: Measurement of the lubricant film thickness of radial shaft seals using laser induced fluorescent method. In: Proceedings of International Tribology Conference Nagasaki 2000 (ITC Nagasaki 2000), pp. 1897–1902 (2000)

  36. Tokunaga, Y., Hosoe, T., Inoue, H., Okada, K., Yamamoto, Y.: Measurement of film distribution by two-dimensional dynamic measuring system for mechanical seals. In: Proceedings of 19th International Conference on Fluid Sealing, pp. 221–234 (2017)

  37. Sugimura, J., Hashimoto, M., Yamamoto, Y.: Study of elastohydrodynamic contacts with fluorescence microscope, thinning films and tribological interfaces. In: Proceedings of 26th Leeds-Lyon Symposium Tribology. Elsevier, Amsterdam, pp. 609–617 (2000)

  38. Necas, D., Sperka, P., Vrbka, M., Krupka, I., Hartl, M.: Film thickness mapping in lubricated contacts using fluorescence. MM Sci. J. 4, 1–16 (2015). https://doi.org/10.17973/MMSJ.2015_12_201524

    Google Scholar 

  39. Reddyhoff, T., Choo, J.H., Spikes, H.A., Glovnea, R.P.: Lubricant flow in an elastohydrodynamic contact using fluorescence. Tribol. Lett. 38, 207–215 (2010)

    Article  Google Scholar 

  40. Myant, C., Reddyhoff, T., Spikes, H.A.: Laser-induced fluorescence for film thickness mapping in pure sliding lubricated, compliant, contacts. Tribol. Int. 43, 1960–1969 (2010)

    Article  Google Scholar 

  41. Ponjavic, A., Dench, J., Morgan, N., Wong, J.S.S.: In situ viscosity measurements of confined liquids. RSC Adv. 5, 99585–99593 (2015)

    Article  Google Scholar 

  42. Dench, J., Morgan, N., Wong, J.S.S.: Quantitative viscosity mapping using fluorescence lifetime measurements. Tribol. Lett. 65, 25 (2017)

    Article  Google Scholar 

  43. Seidel, H.-P., Selinger, B.K.: The effect of pressure on excimer formation. Aust. J. Chem. 18, 977–984 (1965)

    Article  Google Scholar 

  44. Birks, J.B.: Photophysics of Aromatic Molecules, pp. 301–316. Wiley, London (1970)

    Google Scholar 

  45. Johnson, P.C., Offen, H.W.: Effect of pressure on pyrene excimer fluorescence in toluene. J. Chem. Phys. 56(4), 1638–1642 (1972)

    Article  Google Scholar 

  46. Atkins, P., de Paula, J.: Atkins’ Physical Chemistry, 10th edn, pp. 890–891. Oxford University Press, Oxford (2014)

    Google Scholar 

  47. Cameron, A.: Principles of Lubrication, vol. 23. Wiley, New York, pp. 194 & 203–208 (1966)

  48. Nakamura, Y., Tsunoda, M., Matsui, T., Fujishiro, I.: Laser light scattering measurement of lubricants at high pressure and evaluation of mechanical properties (4th report, evaluation of high viscosity of solidified lubricants by Rayleigh scattering and photon correlation technique). Trans. Jpn. Soc. Mech. Eng. Ser. C 65(635), 2866–2891 (1997). (in Japanese)

    Google Scholar 

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Acknowledgements

The authors acknowledge the financial support provided by the Mitutoyo Association for Science and Technology (MAST). The authors are grateful to Atsuyoshi Miura and Ryo Ikeda for the technical support.

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Correspondence to Takefumi Otsu.

Appendix

Appendix

In this study, a one-dimensional Ertel-Grubin calculation is used as a simple simulation model. The calculation model is shown in Fig. 13. The calculated part is the region from the start of the lubricated zone x1 to the inlet position of the contact x2. A value of 5 mm is assumed for x1 based on the location of the outlet meniscus.

Fig. 13
figure 13

Model for the calculation of pressure distribution at the inlet of the contact

In Ertel-Grubin’s equation [47], a one-dimensional modified Reynolds equation is described by following Eq. (5), which uses a reduced pressure, p0, defined in Eq. (6). In Eq. (5), h m is an integration constant.

$$\frac{{{\text{d}}p_{0} }}{{{\text{d}}x}} = 12\eta_{0} U\frac{{h - h_{m} }}{{h^{3} }}$$
(5)

where

$$p_{0} = \frac{1 - \exp ( - \alpha p)}{\alpha }$$
(6)

where α and U are the pressure-viscosity coefficient and rolling speed, respectively.

The film shape, h(x), is assumed to be described by Eq. (7) [47].

$$h(x) = h_{0} + \frac{{a^{2} }}{{\pi R_{\text{B}} }}\left( { - \left( {2 - \frac{{x^{2} }}{{a^{2} }}} \right)\cos^{ - 1} \frac{a}{x} + \left( {\frac{{x^{2} }}{{a^{2} }} - 1} \right)^{0.5} } \right)$$
(7)

where RB is the equivalent radius of the ball and a is the radius of Hertzian contact under the test condition. The value measured using optical interferometry was used as h0.

The reduced pressure p0 distribution can be obtained by integrating Eq.(5), in which the boundary conditions p0 at x1 and x2 are assumed to be zero and 1/α, respectively.

$$p_{0} = 12\eta U\left( {\int_{{ - x_{1} }}^{{ - x_{2} }} {\frac{1}{{h^{2} }}{\text{d}}x - h_{m} \int_{{ - x_{1} }}^{{ - x_{2} }} {\frac{1}{{h^{3} }}{\text{d}}x} } } \right)$$
(8)

where

$$h_{m} = \frac{{\int_{{ - x_{1} }}^{{ - x_{2} }} {\frac{1}{{h^{2} }}{\text{d}}x} - \frac{1}{{12\eta_{0} U\alpha }}}}{{\int_{{ - x_{1} }}^{{ - x_{2} }} {\frac{1}{{h^{3} }}{\text{d}}x} }}$$
(9)

The value of the viscosity (2.5 Pa s at 295 K [48]) and pressure-viscosity coefficient (54 GPa−1 at 295.5 K [14]) are the same as those under experimental conditions.

Finally, the pressure p and viscosity ratio, η/η0, are given by Eqs. (10) and (11).

$$p = \frac{1}{\alpha }\left\{ { - \ln \left( {1 - \alpha p_{0} } \right)} \right\}$$
(10)
$$\frac{\eta }{{\eta_{0} }} = \exp (\alpha p)$$
(11)

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Otsu, T., Imado, K. Study on Changes in the Rheologic Properties of EHL Film Using Fluorescence Measurements. Tribol Lett 66, 40 (2018). https://doi.org/10.1007/s11249-018-0983-4

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