Topics in Catalysis

, Volume 58, Issue 14–17, pp 961–970 | Cite as

The Effect of Phosphorus Exposure on Diesel Oxidation Catalysts—Part I: Activity Measurements, Elementary and Surface Analyses

  • Marja KärkkäinenEmail author
  • Tanja Kolli
  • Mari Honkanen
  • Olli Heikkinen
  • Mika Huuhtanen
  • Kauko Kallinen
  • Toivo Lepistö
  • Jouko Lahtinen
  • Minnamari Vippola
  • Riitta L. Keiski
Original Paper


The effects of phosphorus poisoning on the activity of PtPd and Pt diesel oxidation catalysts and on the activity of the support material were investigated using the gas phase laboratory-scale-aging procedure. The catalysts were treated using two different phosphorus concentrations (0.065 and 0.13 mol/L (NH4)2HPO). The deactivation was studied by inductively coupled plasma optical emission spectroscopy, electron microscopy, X-ray diffractometry, X-ray photoelectron spectrometry and Fourier-transform infrared reflectance, N2-physisorption, and activity measurements with CO, C3H6 and NO. The amount of accumulated phosphorus was higher on the Pt catalyst surface than on the PtPd catalyst and significantly higher on the surface of the bare support material. Phosphorus concentration was uniform throughout the support layer (down to the 10 μm), and phosphorus was found as phosphate, although it can also form compounds like AlPO4 with the support. The treatment with low phosphorus concentration was found to have a clear deactivation effect only for C3H6 oxidation activity on PtPd catalysts above 200 °C. The treatment with high phosphorus concentration significantly decreased the activity of both the PtPd and Pt catalysts. In particular, the C3H6 and NO oxidation activities of the fresh and P-treated Pt catalysts were higher than those of the PtPd catalysts for the entire temperature range.


Phosphorus Deactivation Poisoning Diesel oxidation catalyst Platinum Palladium 



Financial support from The Academy of Finland (ACABIO 139187) is gratefully acknowledged. F. Cumming is acknowledged for his contribution to the experimental work.


  1. 1.
    Twigg MV (2011) Catal Today 163:33CrossRefGoogle Scholar
  2. 2.
    Russell A, Epling WS (2011) Catal Rev 53:337CrossRefGoogle Scholar
  3. 3.
    Kröcher O, Widmer M, Elsener M, Rothe D (2009) Ind Eng Chem Res 48:9847CrossRefGoogle Scholar
  4. 4.
    Hauff K, Tuttlies U, Eigenberger G, Niekel U (2012) Appl Catal B 123–124:107CrossRefGoogle Scholar
  5. 5.
    Nejar N, Makkee M, Illan-Gomez MJ (2007) Appl Catal B 75:11CrossRefGoogle Scholar
  6. 6.
    Cavataio G, Jen H-W, Girard JW, Dobson D, Warner JR, Lambert CK (2007) SAE Paper 2009-01-0627 (2009)Google Scholar
  7. 7.
    Neyestanaki AK, Klingstedt F, Salmi T, Murzin DY (2004) Fuel 83:395CrossRefGoogle Scholar
  8. 8.
    Winkler A, Ferri D, Aguirre M (2009) Appl Catal B 93:177CrossRefGoogle Scholar
  9. 9.
    Matam SK, Kondratenko EV, Aguirre MH, Hug P, Rentsch D, Winkler A, Weidenkaff A, Ferri D (2013) Appl Catal B 129:214CrossRefGoogle Scholar
  10. 10.
    Watanabe T, Kawashima K, Tagawa Y, Tashiro K (2007) SAE Paper 2007-01-1920Google Scholar
  11. 11.
    Wiebenga MH, Kim CH, Schmieg SJ, Oh SH, Brown DB, Kim DH, Lee J-H, Peden CHF (2012) Catal Today 184:197CrossRefGoogle Scholar
  12. 12.
    Bourges P, Lunati S, Mabilon G (1998) Catal Automot Pollut Control IV 116:213Google Scholar
  13. 13.
    Kaneeda M, Iizuka H, Hiratsuka T, Shinotsuka N, Arai M (2009) Appl Catal B 90:564CrossRefGoogle Scholar
  14. 14.
    Morlang A, Neuhausen U, Klementiev KV, Schutze FW, Miehe G, Fuess H, Lox ES (2005) Appl Catal B 60:191CrossRefGoogle Scholar
  15. 15.
    Galisteo FC, Larese C, Mariscal R, Granados ML, Fierro JLG, Fernandez-Ruiz R, Furio M (2004) Top Catal 30–31:451CrossRefGoogle Scholar
  16. 16.
    Bartholomew CH (2001) Appl Catal A 212:17CrossRefGoogle Scholar
  17. 17.
    Rokosz MJ, Chenb AE, Lowe-Mac CK, Kucherov AV, Benson D, Paputa Peck MC, McCabee RW (2001) Appl Catal B 33:204CrossRefGoogle Scholar
  18. 18.
    Nehme G (2013) Wear 301:747CrossRefGoogle Scholar
  19. 19.
    Angove D, Cant NW (2000) Catal Today 63:371CrossRefGoogle Scholar
  20. 20.
    Lanzerath P, Guethenke A, Massner A, Gaertner U (2009) Catal Today 147:S265CrossRefGoogle Scholar
  21. 21.
    Kröger V (2007) Poisoning of automotive exhaust gas catalyst components: the role of phosphorus in the poisoning phenomena, Doctoral Thesis, University of Oulu, Oulu, FinlandGoogle Scholar
  22. 22.
    Ramis G, Rossi PF, Busca G, Lorenzelli V, La Ginestra A, Patrono P (1989) Langmuir 5:917CrossRefGoogle Scholar
  23. 23.
    Christou SY, Efstathiou AM (2007) Top Catal 42–43:415CrossRefGoogle Scholar
  24. 24.
    Andersson J, Antonsson M, Eurenius L, Olsson E, Skoglundh M (2007) Appl Catal B 72:71CrossRefGoogle Scholar
  25. 25.
    PDF-2 Powder Diffraction File Database International Centre of Diffraction Data, 12 Campus Boulevard Newton Square, PA 19073-3273, USA [PDF card: 70-4689 (AlPO4)]Google Scholar
  26. 26.
    Honkanen M, Kärkkäinen M, Heikkinen O, Kallinen K, Kolli T, Huuhtanen M, Lahtinen J, Keiski RL, Lepistö J, Vippola M (2015) Top Catal. doi: 10.1007/s11244-015-0465-y Google Scholar
  27. 27.
    Kärkkäinen M, Honkanen M, Viitanen V, Kolli T, Valtanen A, Huuhtanen M, Kalllinen K, Vippola M, Lepistö T, Lahtinen J, Keiski R-L (2013) Top Catal 56:672CrossRefGoogle Scholar
  28. 28.
    NIST X-ray Photoelectron Spectroscopy Database. Accessed 25 May 2014
  29. 29.
    Poojary MD, Clearfield A (1993) Mater Chem Phys 35:301CrossRefGoogle Scholar
  30. 30.
    Boonchom B, Kongtaweelert S (2010) J Therm Anal Calorim 99:531CrossRefGoogle Scholar
  31. 31.
    Youssif MI, Mohamed FSh, Aziz MS (2004) Mater Chem Phys 83:250CrossRefGoogle Scholar
  32. 32.
    Scaccia S, Carewska M, Bartolomeo AD, Prosini PP (2003) Thermochim Acta 397:135CrossRefGoogle Scholar
  33. 33.
    Nyquist RA, Kagel RO (1971) Infrared spectra of inorganic compounds (3800–45 cm−1). Academic press, New YorkGoogle Scholar
  34. 34.
    Khosravi M, Sola C, Abedi A, Hayes RE, Epling WS, Votsmeier M (2014) Appl Catal B 147:264CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2015

Authors and Affiliations

  • Marja Kärkkäinen
    • 1
    Email author
  • Tanja Kolli
    • 1
  • Mari Honkanen
    • 2
  • Olli Heikkinen
    • 3
  • Mika Huuhtanen
    • 1
  • Kauko Kallinen
    • 4
  • Toivo Lepistö
    • 2
  • Jouko Lahtinen
    • 3
  • Minnamari Vippola
    • 2
  • Riitta L. Keiski
    • 1
  1. 1.Environmental and Chemical Engineering, Faculty of TechnologyUniversity of OuluOuluFinland
  2. 2.Department of Materials ScienceTampere University of TechnologyTampereFinland
  3. 3.Department of Applied PhysicsAalto UniversityAaltoFinland
  4. 4.Catalyst ResearchDinex Ecocat OyOuluFinland

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