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Combined Oxidative and Non-oxidative Dehydrogenation of n-Butane Over VOX Species Supported on HMS

Abstract

The combination of oxidative and non-oxidative dehydrogenation of n-butane as an attractive possibility for production of C4 olefins was studied over VOX based catalyst. Long-term activity and selectivity to desired products could be achieved over the catalysts with well dispersed monomeric vanadium oxide species supported on mesoporous silica support.

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Acknowledgments

A financial support of the Czech Science Foundation under the project No. P106/10/0196 is highly acknowledged. We also thank to Peter Priecel for proofreading.

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Correspondence to M. Setnička.

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Setnička, M., Čičmanec, P., Tvarůžková, E. et al. Combined Oxidative and Non-oxidative Dehydrogenation of n-Butane Over VOX Species Supported on HMS. Top Catal 56, 662–671 (2013). https://doi.org/10.1007/s11244-013-0018-1

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Keywords

  • Vanadium oxide
  • Oxidative dehydrogenation
  • Lean-oxygen conditions
  • n-Butane
  • Hexagonal mesoporous silica