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Combined Oxidative and Non-oxidative Dehydrogenation of n-Butane Over VOX Species Supported on HMS

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Abstract

The combination of oxidative and non-oxidative dehydrogenation of n-butane as an attractive possibility for production of C4 olefins was studied over VOX based catalyst. Long-term activity and selectivity to desired products could be achieved over the catalysts with well dispersed monomeric vanadium oxide species supported on mesoporous silica support.

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References

  1. Cavani F, Ballarini N, Cericola A (2007) Catal Today 127:113

    Article  CAS  Google Scholar 

  2. Ovsitser O, Schomaecker R, Kondratenko EV, Wolfram T, Trunschke A (2012) Catal Today 192:16

    Article  CAS  Google Scholar 

  3. Jackson SD, Rugmini S (2007) J Catal 251:59

    Article  CAS  Google Scholar 

  4. Bhasin MM, McCain JH, Vora BV, Imai T, Pujado PR (2001) Appl Catal A 221:397

    Article  CAS  Google Scholar 

  5. Tsikoyiannis JG, Stern DL, Grasselli RK (1999) J Catal 184:77

    Article  CAS  Google Scholar 

  6. Rase HF (2000) Handbook of commercial catalysts. CRC Press, New York

    Google Scholar 

  7. Dean JA (1999) Lange’s handbook of chemistry. McGraw-Hill Inc., New York

    Google Scholar 

  8. Chaar MA, Patel D, Kung MC, Kung HH (1987) J Catal 105:483

    Article  CAS  Google Scholar 

  9. Madeira LM, Portela MF (2002) Catal Rev 44:247

    Article  CAS  Google Scholar 

  10. Ovsitser O, Kondratenko EV (2010) Chem Commun 46:4974

    Article  CAS  Google Scholar 

  11. Grasselli RK, Stern DL, Tsikoyiannis JG (2000) In: Corma A, Melo FV, Mendioroz S, Fierro JLG (eds) Studies in surface science and catalysis, vol 130. Elsevier, Amsterdam, p 773

    Google Scholar 

  12. Waku T, Biscardi JA, Iglesia E (2004) J Catal 222:481

    Article  CAS  Google Scholar 

  13. Setnička M, Bulánek R, Čapek L, Čičmanec P (2011) J Mol Catal A 344:1

    Article  Google Scholar 

  14. Bulánek R, Kalužova A, Setnička M, Zukal A, Čičmanec P, Mayerová J (2012) Catal Today 179:149

    Article  Google Scholar 

  15. Čapek L, Adam J, Grygar T, Bulánek R, Vradman L, Kosova-Kucerová G, Čičmanec P, Knotek P (2008) Appl Catal A 342:99

    Article  Google Scholar 

  16. Blasco T, Nieto JML (1997) Appl Catal A 157:117

    Article  CAS  Google Scholar 

  17. Weckhuysen BM, Keller DE (2003) Catal Today 78:25

    Article  CAS  Google Scholar 

  18. Tian HJ, Ross EI, Wachs IE (2006) J Phys Chem B 110:9593

    Article  CAS  Google Scholar 

  19. McGregor J, Huang Z, Shiko G, Gladden LF, Stein RS, Duer MJ, Wu Z, Stair PC, Rugmini S, Jackson SD (2009) Catal Today 142:143

    Article  CAS  Google Scholar 

  20. Harlin ME, Niemi VM, Krause AOI, Weckhuysen BM (2001) J Catal 203:242

    Article  CAS  Google Scholar 

  21. Xu YB, Lu JY, Zhong M, Wang JD (2009) J Nat Gas Chem 18:88

    Article  CAS  Google Scholar 

  22. Bulánek R, Čičmanec P, Sheng-Yang H, Knotek P, Čapek L, Setnička M (2012) Appl Catal A 415–416(1):29–39

    Google Scholar 

  23. Kung HH (1994) Advances in Catalysis, vol 40. Academic Press Inc, San Diego, p 1

    Google Scholar 

  24. Tanev PT, Pinnavaia TJ (1995) Science 267:865

    Article  CAS  Google Scholar 

  25. Bulánek R, Čapek L, Setnička M, Čičmanec P (2011) J Phys Chem C 115:12430

    Article  Google Scholar 

  26. Kubelka P, Munk FZ (1931) Tech Phys 12:593

    Google Scholar 

  27. Sachtler WMH, Boer NHD (1964) In: Proceedings of 3rd international congress on catalysis, North-Holland Publishing Company, Amsterdam p 8

  28. Owens L, Kung HH (1993) J Catal 144:202

    Article  CAS  Google Scholar 

  29. Karakoulia SA, Triantafyllidis KS, Lemonidou AA (2008) Microporous Mesoporous Mater 110:157

    Article  CAS  Google Scholar 

  30. Chen C, Zhang QH, Gao J, Zhang W, Xu J (2009) J Nanosci Nanotechnol 9:1589

    Article  CAS  Google Scholar 

  31. Liu W, Lai SY, Dai HX, Wang SJ, Sun HZ, Au CT (2007) Catal Lett 113:147

    Article  CAS  Google Scholar 

  32. Wang WJ, Lin HY, Chen YW (2007) J Porous Mater 14:137

    Article  CAS  Google Scholar 

  33. Kondratenko EV, Cherian M, Baerns M, Su DS, Schloegl R, Wang X, Wachs IE (2005) J Catal 234:131

    Article  CAS  Google Scholar 

  34. Niemantsverdriet JW (2007) Spectroscopy in catalysis. Wiley-VCH, Weinheim

    Book  Google Scholar 

  35. Sarsfield BA, Davidovich M, Desikan S, Fakes M, Futernik S, Hilden JL, Tan JS, Yin S, Young G, Vakkalagadda B, Volk B (2006) Denver X-ray Conference (Advances in X-ray Analysis), vol 49. JCPDS, Denver p 322

  36. Knotek P, Čapek L, Bulánek R, Adam J (2007) Top Catal 45:51

    Article  CAS  Google Scholar 

  37. Čejka J, Corma A, Bekkum Hv, Schüth F (2007) Introduction to zeolite science and practice. Elsevier, Amsterdam

    Google Scholar 

  38. Lowell S, Shields JE, Thomas MA, Thommes M (2004) Characterization porous solids and powders: surface area, pore size and density. Kluwer Academic Publishers, Dordrecht

    Book  Google Scholar 

  39. Čapek L, Bulánek R, Adam J, Smoláková L, Sheng-Yang H, Čičmanec P (2009) Catal Today 141:282

    Article  Google Scholar 

  40. Zhou R, Cao Y, Yan SR, Deng JF, Liao YY, Hong BF (2001) Catal Lett 75:107

    Article  CAS  Google Scholar 

  41. Zukal A, Šiklová H, Čejka J (2008) Langmuir 24:9837

    Article  CAS  Google Scholar 

  42. Hess C, Hoefelmeyer JD, Tilley TD (2004) J Phys Chem B 108:9703

    Article  CAS  Google Scholar 

  43. Karakoulia SA, Triantafyllidis KS, Tsilomelekis G, Boghosian S, Lemonidou AA (2009) Catal Today 141:245

    Article  CAS  Google Scholar 

  44. Centi G (1996) Appl Catal A 147:267

    Article  CAS  Google Scholar 

  45. Wachs IE, Weckhuysen BM (1997) Appl Catal A 157:67

    Article  CAS  Google Scholar 

  46. Wachs IE (1996) Catal Today 27:437

    Article  CAS  Google Scholar 

  47. Keller DE, Visser T, Soulimani F, Koningsberger DC, Weckhuysen BM (2007) Vib Spectrosc 43:140

    Article  CAS  Google Scholar 

  48. Mathieu M, Van Der Voort P, Weckhuysen BM, Rao RR, Catana G, Schoonheydt RA, Vansant EF (2001) J Phys Chem B 105:3393

    Article  CAS  Google Scholar 

  49. Solsona B, Blasco T, Nieto JML, Pena ML, Rey F, Vidal-Moya A (2001) J Catal 203:443

    Article  CAS  Google Scholar 

  50. Gao F, Zhang YH, Wan HQ, Kong Y, Wu XC, Dong L, Li BQ, Chen Y (2008) Microporous Mesoporous Mater 110:508

    Article  CAS  Google Scholar 

  51. Schramlmarth M, Wokaun A, Pohl M, Krauss HL (1991) J Chem Soc 87:2635

    CAS  Google Scholar 

  52. Catana G, Rao RR, Weckhuysen BM, Van Der Voort P, Vansant E, Schoonheydt RA (1998) J Phys Chem B 102:8005

    Article  CAS  Google Scholar 

  53. Hurst NW, Gentry SJ, Jones A, McNicol BD (1982) Catal Rev 24:233

    Article  CAS  Google Scholar 

  54. Kissinger HE (1957) Anal Chem 29:1702

    Article  CAS  Google Scholar 

  55. Du G, Lim S, Pinault M, Wang C, Fang F, Pfefferle L, Haller GL (2008) J Catal 253:74

    Article  CAS  Google Scholar 

  56. Kanervo JM, Harlin ME, Krause AOI, Banares MA (2003) Catal Today 78:171

    Article  CAS  Google Scholar 

  57. Kustrowski P, Segura Y, Chmielarz L, Surman J, Dziembaj R, Cool P, Vansant EF (2006) Catal Today 114:307

    Article  CAS  Google Scholar 

  58. Cavani F, Trifiro F (1999) Catal Today 51:561

    Article  CAS  Google Scholar 

  59. Vrieland GE, Murchison CB (1996) Appl Catal A 134:101

    Article  CAS  Google Scholar 

  60. Harlin ME, Backman LB, Krause AOI, Jylha OJT (1999) J Catal 183:300

    Article  CAS  Google Scholar 

Download references

Acknowledgments

A financial support of the Czech Science Foundation under the project No. P106/10/0196 is highly acknowledged. We also thank to Peter Priecel for proofreading.

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Correspondence to M. Setnička.

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Setnička, M., Čičmanec, P., Tvarůžková, E. et al. Combined Oxidative and Non-oxidative Dehydrogenation of n-Butane Over VOX Species Supported on HMS. Top Catal 56, 662–671 (2013). https://doi.org/10.1007/s11244-013-0018-1

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