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Oxidative dehydrogenation of n-butane over mesoporous VO x /SBA-15 catalysts

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Abstract

Mesoporous VO x /SBA-15 catalysts with different V contents were evaluated for the oxidative dehydrogenation of n-butane and characterized by N2 adsorption, XRD, HRTEM, H2-TPR, NH3-TPD, XPS, and EPR techniques. Compared to conventional V2O5/SiO2 catalysts, the VO x /SBA-15 catalysts showed better performance. The good performance can be attributed to the good dispersion of V species, presence of V4+ species and the pore structure.

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References

  1. M.A. Chaar, D. Patel, H.H. Kung, J. Catal. 109 (1988) 463

    Article  CAS  Google Scholar 

  2. D. Bhattacharyya, S.K. Bej, M.S. Rao, Appl. Catal. 87 (1992) 29

    Article  CAS  Google Scholar 

  3. L.M. Madeira, M.F. Portela, Catal. Rev.-Sci. Eng. 44 (2002) 247

    Article  CAS  Google Scholar 

  4. T. Blasco, J.M. López Nieto, Appl. Catal. A 157 (1997) 117

    Article  CAS  Google Scholar 

  5. E.A. Mamedov, V. Cortés Corberán, Appl. Catal. A 127 (1995) 1

    Article  CAS  Google Scholar 

  6. L. Owens, H.H. Kung, J. Catal. 144 (1993) 202

    Article  CAS  Google Scholar 

  7. S. Ted Oyama, G.A. Somorjai, J. Phys. Chem. 94 (1990) 5022

    Article  Google Scholar 

  8. A. Erdöhelyi, F. Solymosi, J. Catal. 123 (1990) 31

    Article  Google Scholar 

  9. A. Erdöhelyi, F. Solymosi, J. Catal. 129 (1991) 497

    Article  Google Scholar 

  10. T. Blasco, A. Galli, J.M. López Nietó, J. Catal. 169 (1997) 203

    Article  CAS  Google Scholar 

  11. H.X. Dai, A.T. Bell, E. Iglesia, J. Catal. 221 (2004) 491

    Article  CAS  Google Scholar 

  12. M.A. Chaar, D. Patel, M.C. Hung, H.H. Kung, J. Catal. 105 (1987) 483

    Article  CAS  Google Scholar 

  13. A.A. Lemonidou, G.J. Tjatjopoulos, I.A. Vasalos, Catal. Today 45 (1998) 65

    Article  CAS  Google Scholar 

  14. R. Vidal-Michel, K.L. Hohn, J. Catal. 221 (2004) 127

    Article  CAS  Google Scholar 

  15. Q.H. Zhang, Y. Wang, Y. Ohishi, T. Shishido, K. Takehira, J. Catal. 202 (2001) 308

    Article  CAS  Google Scholar 

  16. B. Solsona, T. Blasco, J.M. López Nieto, M.L. Peña, F. Rey, A. Vidal-Moya, J. Catal. 203 (2001) 443

    Article  CAS  Google Scholar 

  17. P. Selvam, S. E. Dapurkar, J. Catal. 229 (2005) 64

    Article  CAS  Google Scholar 

  18. K.J. Chao, C.N. Wu, and H. Chang, J. Phys. Chem. B 101 (1997) 6341

    Article  Google Scholar 

  19. D.Y. Zhao, J.L. Feng, Q.S. Huo, N. Melosh, G.H. Fredrickson, B.F. Chmelka, G.D. Stucky, Science 279 (1998) 548

    Article  CAS  Google Scholar 

  20. X.K. Li, W.J. Ji, J. Zhao, Z.B. Zhang, C.T. Au, J. Catal. 238 (2006) 232

    Article  CAS  Google Scholar 

  21. H.H. López, A. Martínez, Catal. Lett. 83 (2002) 37

    Article  Google Scholar 

  22. V. Fornés, C. López, H.H. López, A. Martínez, Appl. Catal. 249 (2003) 345

    Article  CAS  Google Scholar 

  23. C. Hess, J.D. Hoefelmeyer, T. Don Tilley, J. Phys. Chem. B 108 (2004) 9703

    Article  CAS  Google Scholar 

  24. Y.M. Liu, Y. Cao, S.R. Yan, W.L. Dai, K.N. Fan, Catal. Lett. 88 (2003) 61

    Article  CAS  Google Scholar 

  25. Y.M. Liu, Y. Cao, N. Yi, W.L. Feng, W.L. Dai, S.R. Yan, H. Y. He, K.N. Fan, J. Catal. 224 (2004) 417

    Article  CAS  Google Scholar 

  26. C. Hess, M.H. Looi, S.B. Abd Hamid, R. Schlögl, Chem. Commun. 4 (2006) 451

    Article  CAS  Google Scholar 

  27. S. Jun, S.H. Joo, R. Ryoo, M. Kruk, M. Jaroniec, Z. Liu, T. Ohsuna, O. Terasaki, J. Am. Chem. Soc. 122 (2000) 10712

    Article  CAS  Google Scholar 

  28. R. Ryoo, C.H. Ko, M. Kruk, V. Antochshuk, M. Jaroniec, J. Phys. Chem. B 104 (2000) 11465

    Article  CAS  Google Scholar 

  29. W.E. Slinkard, P.B. Degroot, J. Catal. 68 (1981) 423

    Article  CAS  Google Scholar 

  30. F. Arena, F. Frusteri, G. Martra, S. Coluccia, A. Parmaliana, J. Chem. Soc., Faraday Trans. 93 (1997) 3849

    Article  CAS  Google Scholar 

  31. J. Santamaría-González, J. Luque-Zambrana, J. Mérida-Robles, P. Maireles-Torres, E. Rodríguez-Casllón, A. Jiménez-López, Catal. Lett. 68 (2000) 67

    Article  Google Scholar 

  32. M.L. Peña, A. Dejoz, V. Fornés, E. Rey, M.I. Vázquez, J.M. López Nieto, Appl. Catal. A 209 (2001) 155

    Article  Google Scholar 

  33. H. Berndt, A. Martin, A. Brückner, E. Schreier, D. Müller, H. Kosslick, G.U. Wolf, B. Lücke, J. Catal. 191 (2000) 384

    Article  CAS  Google Scholar 

  34. M. Baltes, K. Cassiers, P. Van der Voort, B.M. Weckhuysen, R.A. Schoonheydt, E.F. Vansant, J. Catal. 197 (2001) 160

    Article  CAS  Google Scholar 

  35. A. Brückner, P. Rybarczyk, H. Kosslick, G.U. Wolf, M. Baerns, Stud. Surf. Sci. Catal. 142 (2002) 1141

    Article  Google Scholar 

  36. T. Blasco, J.M. López Nieto, A. Dejoz, M.I. Vázquez, J. Catal. 157 (1995) 271

    Article  CAS  Google Scholar 

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Acknowledgments

The work was supported by the Research Grants Council of the Hong Kong Special Administration Region (Grant No. HKBU 200103); the research activities conducted in BJUT was financed by the National Natural Science Foundation of China (Grant No. 20473006).

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Authors and Affiliations

  1. Department of Chemistry, Centre for Surface Analysis and Research, Hong Kong Baptist University, Kowloon Tong, Hong Kong, China

    Wei Liu, Suk Yin Lai, Hongxing Dai & Chak Tong Au

  2. Department of Chemistry and Chemical Engineering, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing, 100022, China

    Hongxing Dai

  3. Chemistry and Chemical Engineering College, Xiamen University, Xiamen, 361005, China

    Shuiju Wang & Haizhen Sun

Authors
  1. Wei Liu
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  2. Suk Yin Lai
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  3. Hongxing Dai
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  6. Chak Tong Au
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Correspondence to Chak Tong Au.

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Liu, W., Lai, S.Y., Dai, H. et al. Oxidative dehydrogenation of n-butane over mesoporous VO x /SBA-15 catalysts. Catal Lett 113, 147–154 (2007). https://doi.org/10.1007/s10562-007-9023-y

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