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Photochemical reactions of M(CO)5THF (M = Cr, Mo, W) with thio Schiff bases

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Abstract

The hitherto unknown complexes, [M2(CO)6(μ-CO)(μ-L)], [M = Cr; 1, Mo; 2, W; 3] and [M2(CO)6(μ-CO)(μ-L′)], [M = Cr; 4, Mo; 5, W; 6] have been synthesized by the photochemical reactions of photogenerated intermediate, M(CO)5THF (M = Cr, Mo, W) with thio Schiff base ligands, N,N′-bis(2-aminothiophenol)-1,4-bis(2-carboxaldehydephenoxy)butane (H 2 L) and N,N′-bis(2-aminothiophenol)-1,7-bis(2-formylphenyl)-1,4,7-trioxaheptane (H 2 L′). The complexes have been characterized by elemental analysis, LC-mass spectrometry, magnetic studies, FT-IR and 1H NMR spectroscopy. The spectroscopic studies show that H 2 L and H 2 L′ ligands are converted to benzothiazole derivatives, L and L′ after UV irradiation and coordinated to the central metal as bridging ligands via the central azomethine nitrogen and sulphur atoms in 1–6.

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Acknowledgements

We thank the Research Foundation of Dokuz Eylul and Dicle University for funds. We thank TUBITAK for allocation of time at the Mass Spectra and Elemental Analyses. We thank Ege University for obtaining 1H NMR spectra. This work was supported by Dokuz Eylul University, Project: 05.KB.FEN.019.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science and Arts, Dokuz Eylul University, Buca-Tinaztepe, 35160, Izmir, Turkey

    Senem Karahan, Pelin Kose & Elif Subasi

  2. Department of Chemistry, Faculty of Education, Dicle University, 21280, Diyarbakir, Turkey

    Huseyin Alp & Hamdi Temel

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  1. Senem Karahan
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  2. Pelin Kose
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  3. Elif Subasi
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  4. Huseyin Alp
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Correspondence to Elif Subasi.

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Karahan, S., Kose, P., Subasi, E. et al. Photochemical reactions of M(CO)5THF (M = Cr, Mo, W) with thio Schiff bases. Transition Met Chem 33, 849–854 (2008). https://doi.org/10.1007/s11243-008-9121-8

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  • DOI: https://doi.org/10.1007/s11243-008-9121-8

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