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Metallic Conductivity of Mechanochemically Doped Polyaniline

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Theoretical and Experimental Chemistry Aims and scope

It was shown that the conductivity of polyaniline can be increased significantly as a result of mechanochemical doping with camphorsulfonic acid and secondary doping with m-cresol in comparison with the conductivity of the polymer synthesized by the traditional method. The obtained polymer has a nanofibrillar structure and is characterized by a metallic type of temperature dependence of the conductivity over a wide range of temperatures.

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Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, Kyiv, 03028, Ukraine

    O. Yu. Posudievsky, O. A. Kozarenko, I. E. Kotenko, V. G. Koshechko & V. D. Pokhodenko

  2. Institute of Physics, National Academy of Sciences of Ukraine, Prospekt Nauky, 46, Kyiv, 03028, Ukraine

    O. P. Boiko

  3. Taras Shevchenko National University of Kyiv, Institute of High Technologies, Prospekt Akademika Glushkova, 4g, Kyiv, 03022, Ukraine

    A. G. Shkavro

Authors
  1. O. Yu. Posudievsky
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  2. O. A. Kozarenko
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  3. I. E. Kotenko
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  4. O. P. Boiko
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  5. A. G. Shkavro
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  6. V. G. Koshechko
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  7. V. D. Pokhodenko
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Corresponding author

Correspondence to O. Yu. Posudievsky.

Additional information

Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 50, No. 4, pp. 199-205, July-August, 2014.

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Posudievsky, O.Y., Kozarenko, O.A., Kotenko, I.E. et al. Metallic Conductivity of Mechanochemically Doped Polyaniline. Theor Exp Chem 50, 197–203 (2014). https://doi.org/10.1007/s11237-014-9373-7

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  • DOI: https://doi.org/10.1007/s11237-014-9373-7

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